Beruflich Dokumente
Kultur Dokumente
A. DATA DIRI
B. Riwayat Pekerjaan
1.Dosen Tetap Jurusan Fisika FMIPA Universitas Negeri Makassar, 1990 - sekarang.
2.Ketua Program Studi Fisika FMIPA Universitas Negeri Makassar, 2003 - 2004.
3.Pembantu Dekan Bidang Akademik FMIPA Universitas Negeri Makassar, 2004 - sekarang.
4.Dosen Program Pascasarjana UNM Makassar, 2006 - sekarang
Statistical Physics
Main Refereneces:
1. Introdution to Statistical Physics for Students
by Pointon Longman, England
2. Problem and Solution on Thermodynamics and Statistical
Mechanics, Yung Kuo Lim, World Scientific Singapore
Additional References :
Solid States Physics Textbook, Quantum Physics and Modern
Physics Texbooks Related with Statistical Physics.
Some e-books dowloanded from internet
Main Topics
Microstate Macrostate
Statistical
Physics
Basic Ideas/Terminology
Example:
What is the probability of
rolling two sixes?
Classical probabilities:
p6 1
6
Two sixes:
p6,6 16 16 1
36
xi
Mean: x
nx
i
,
i i
where N i ni
N
Statistical distributions
16
ni N
xi
ni
Mean: x i pi xi , where pi lim
N N
Statistical distributions
16
ni
xi
Standard x p x x
2 2
i i i
deviation
Statistical distributions
Gaussian distribution
(Bell curve)
x x
2
1
p( x ) exp
2
2
2
Probabality Theory
Mean
Mode
Median
Varians
Mean
3 4 4 3 6 3 5 28
X 4
7 7
x1 x2 x3 x4 x5 x6 x7
X
7
x i
X i
N
Mean
continuous
We can expand the formula for mean
f .( x ).x
f (x ) 1
i i
f ( x ). x
discrete
X i
i
i i
f ( x ) i i
i
If it’s function is continue : X x. f ( x)dx
Euclid Space
dV dxdydz
dV
z
y dz
x dx
dy
Euclid Space and Phase Space
p x2 p y2 p z2
2m
d dxdydzdpx dp y dp z
Space Space Momentum Space
p(N)
x(N)
Averaging of Assembly Properties
X
Px( N ), p( N )d
6 N
6N
Property Average of Assembly
pX i i
X i
p i
i
X pi X i
i
Classical and Quantum Assembly
a. Classical Assembly
- Distinguishble
- Continum energies
- Obey the Pauli exclusion principle
Distribusi Energi
…………………….
Sistem N dengan energi εN
Statistik Maxwell Boltzmann
Distribusi Energi
…………………….
Sistem N dengan energi εN
Statistik Maxwell Boltzmann
Prinsip Kekekalan
Statistik Maxwell Boltzmann
Empat partikel dengan notasi a,b,c dan d didistribusi pada dua pita energi, 2 pada pita 1 dan 2
pada sistim 2. Bobot masing-masing adalah 3 dan 4.
Jadi : N1 = N2 = 2 g1 = 3 , g2 = 4
N!
W g12 .g 22
N 1!.N 2 !
4!
W 3 2.4 2 864
2 !.2!
Contoh Pemakaian
Rumus Stirling
Distribusi Maxwell Boltzmann
2N
n( )d e / kT 1 / 2 d
kT 3 / 2
g() P()
exp g C
B
k T
=
0 0 0
Aplikasi Statistik Maxwell Boltzmann
Apabila energi sistem dalam suatu assembly berbentuk kuadratik terhadap posisi
dan koordinat momentum, maka kontribusi energi rata-rata akan menjadi ½ kT,
dimana T adalah temperatur assembly.
p d
2 e / KT
x / 2me
e / kT
e dT
dimana ε adalah energi total. Dengan mengambil energi dalam dua bentuk yaitu
2 Px 2
. Kedua bentuk ini independent terhadap Px,
Px dan
2m
2m
sehingga persamaan di atas dapat ditulis :
Aplikasi Statistik Maxwell Boltzmann
ky Untuk partikel kuantum dalam kotak 2D (e.g., electron pd FET):
2D nx n y
k kx ky k kx k y
2 2
Lx Ly
kx 1 k2 k 2 area k2 1 2m
N k G k G
4 4 4 4 2
Lx Ly
# states within ¼ of g 2 D
2s 1 m - Tak
2 2 bergantung pd
a circle of radius k
Lx
g 3D 2s 1 2m
2 2 1/ 2
3/ 2
2D
kx 4
ky 1D
3/ 2
1 2m
g 3D 2 2 1/ 2
Thus, for 3D electrons
(2s+1=2): 2
Distribusi Kecepatan Maxwell
" volume" v v dv
3/ 2
m mv2 vy
f v fv exp 4v 2 dv
2 k BT 2 k BT 4v 2 dv
Nampak bahwa persamaan ini merupakan perkalian v
antara faktor Boltzmann dengan sebuah tetapan.
Tetapan tersebut dapat diperoleh dari normalisasi vx
3/ 2
m
f v dv 1
vz
C
0 2 k B
T P(v)
dN NP d N exp d
k BT
Distribusi energi, N – the total # of particles
3/ 2
m mv 2
dN v NPv dv N 4v exp
2
dv
2 k B
T 2 k B
T
v
speed distribution (distribusi kecepatan) P(vx)
1/ 2
m mv 2
dN v x NPv x dv N exp dv
2 k B
T 2 k B
T
Distrbusi kecepatan dalam arah x, vx vx
Karakteristik Nilai Kecepatan
3/ 2
m mv 2 Lihat bahwa distribusi ini tidak simetrik, sehingga
Pv 4v exp
2
2 k BT
perlu dicari perata-rataan sebagai berikut
2 k BT
P(v)
Root-mean-square speed ( Pangkat dua rata
rata akar kecepatan ) is sebanding dengan akar
pangkat dua energi rata-rata.
mvrms
1 2E 3k BT
E vrms
2
2 m m
vmax v vrms v
dPv 2 k BT
Harga kec.maksimum :
dv 0 v max
v vmax m
m mv2
v v Pv dv
8k BT
Kelajuan rata-rata : 4v exp
3
dv
0 2 k BT 0 2k BT m
3/ 2
m mv2
Pv, T , m 4v exp
2
2 k B
T 2 k B
T
3/ 2 3/ 2
m1 m1v 2 m2 m2 v 2
4v exp
2
4v exp
2
2 k BT 2k BT 2 k BT 2 k BT
3 m1v 2 3 m2v 2
ln m1 ln m2
2 2k BT 2 2k BT
m1
3k BT ln
v2 3 1.38 10 23 300 ln 2
3 m1
ln m1 m2 v
m2
1.6 km/s
2 m2 2k BT m1 m2 2 1.7 10 27
Soal (Maxwell distr.)
Find the temperature at which the number of molecules in an ideal Boltzmann gas
with the values of speed within the range v - v+dv is a maximum.
Pv, T
3/ 2
m mv2
Pv, T , m 4v exp
2
maximum: 0
2 k B
T 2 k B
T T
1/ 2 3/ 2
3 m m mv2 m mv2 mv2
exp
2
exp 0
2
2 2 k BT 2 k BT 2k BT 2 k BT 2k BT 2k BT
3 mv2 mv2
0 T
2 2k BT 3k B
At home:
Find the temperature T at which the rms speed of Hydrogen molecules exceeds their
most probable speed by 400 m/s.
Answer: 380K
Pelebaran Garis Spektrum Doppler
Bagian ini adalah salah satu contoh penerapan distribusi laju dari
statistik Maxwell Boltzmann, yakni pelebaran spektrum akibat efek
Doppler.
Misalkan molekul gas melakukan radiasi dengan panjang
gelombang λ dalam arah x dengan kecepatan vx menuju kepada
seorang pengamat. Pengamat akan menerima radiasi dengan
panjang gelombang.
o
vx
o 1
c
co
v
o
c
dv x d
o
o
mc2 o 2 c
3/ 2
m
f d exp d
2 k BT 2k BT o o
2
o
Intensitas radiasi :
mc 2 o 2
I d Cf ( )d I o exp d
2 k BT o
2
o
Prinsip Ekipartisi Energi
Jika energi sistem dinyatakan dalam bentuk kuadrat posisi dan momentum maka tiap
bentuk kuadrat tersebut akan memberikan energi rata-rata ½ kT
Contoh molekul gas dengan massa m, energinya dapat dinyatakan dengan
p x2
x
2m
x d
2 e / KT
p / 2 m e
e / kT
e dT
Prinsip Ekipartisi Energi
p x2
Nyatakan energi sebagai 2m dan
x
p x2 px2
exp ( ) / kT dxdydzdp y dp z exp( p 2
x / 2mkT)dp x
2m 2m
x
exp ( p x2
2 m ) / kT dxdydzdp y dp x x
exp( p 2
x / 2mkT)dp x
2
Misalkan
p x= u2 maka
2mkT
u 2
2
kT e u du
x
e
u 2
du
Prinsip Ekipartisi Energi
Hasilnya memberikan : e
u 2
u du e du
u2
2 1
2
px2
1 u
Maka : x kT 2mkT
2
p x2 1 2
x x
2m 2
Prinsip Ekipartisi Energi
Maka :
2
p / 2m x e
1 2 e / kT
x 2
d
x
e d
e / kT
p x2 1 2
2 1 2
px 2 x exp 2m 2 x / kT dxdpx
x
p x2 1 2
exp 2m 2 x kT dxdpx
p x2 1 2
x r 2 cos 2
r 2 sin 2 , 2
2m
dp x dp y 2(m / ) rdrd
1
2
Prinsip Ekipartisi Energi
Maka :
2x
2
r / kT
d e r 3 dr
0
2x
0
kT
r 2
/ kT
d e rdr
0 0
p x2 1 p 2
1 p x2 1
2
1 x 2 y 3 z
2 y 2
2m 2 2m 2 2m 2
1
6. kT
2
3kT
E
3R 5,94 kal/ o
K/gr.atom
T v
Panas jenis gas
E
3R 5,94 kal/ o
K/gr.atom
T v
STATISTIK BOSE-EINSTEIN
g s g s 1 ns !
g s g s 1 ns !
ws
g s 1!ns !
g s 1 ns !
g s 1!ns !
w ws
s
STATISTIK BOSE-EINSTEIN
g s 1 ns !
s g s 1!ns !
w ws
s
STATISTIK BOSE-EINSTEIN
log w
s n
x
s dn s 0
s
log w
x s 0
n s
log w log ws
s
log w
log g s 1 n s log n s
n s
log w g ns
log s
ns ns
g ns
log s x s 0
ns
gs
e x s 1
ns
STATISTIK BOSE-EINSTEIN
gs
ns
e x s 1
gs
ns
1 s / kT 1
e
A
gs!
ws
ns !g s ns !
STATISTIK BOSE-EINSTEIN
gs
ns
e x s 1
gs
ns
1 s / kT 1
e
A
gs!
ws
ns !g s ns !
STATISTIK BOSE-EINSTEIN
STATISTIK FERMI-DIRAC
W ws
s
gs!
ws
ns !g s ns !
Jumlah untuk semua kemungkinan susunan
yang berbeda untuk satu tingkatan energi
gs!
W Jumlah untuk semua kemungkinan susunan
s n s ! g s n s ! yang berbeda
STATISTIK FERMI-DIRAC
gs!
log W log
s ns !g s ns !
g s log g s ns log ns g s ns log g s ns
s
log W
s n s dns 0 Gunakan rumus Stirling
s
log W
s 0
n s
STATISTIK FERMI-DIRAC
log W g s ns
log
ns ns
g s ns
log s 0
ns
gs s
e 1
ns
STATISTIK FERMI-DIRAC
~ kBT
f
1
e F kT 1
gs
ns Distribusi jumlah partikel partikel
e s 1
W
3 1 4 !
15 cara
3 1!4!
Radiasi Benda Hitam
This fact leads to the concept of photons as quanta of the electromagnetic field. The
state of the el.-mag. field is specified by the number n for each of the modes, or, in other
words, by enumerating the number of photons with each frequency.
However, we cannot use the usual expression for the chemical potential, because one
cannot increase N (i.e., add photons to the system) at constant volume and at the same
time keep the temperature constant: F
- does not exist for the photon gas
N T ,V
G N F F T ,V
Instead, we can use G F PV P
V T V
- by increasing the volume at T=const, we proportionally scale F
n ph f ph , T
1 1 Planck’s distribution provides the average
h
exp 1 exp 1 number of photons in a single mode of
B
k T k BT frequency = /h.
h
n h
The average energy in the mode: h
exp 1
In the classical (high temperature) limit: k BT B
k T
In order to calculate the average number of photons per small energy interval d, the
average energy of photons per small energy interval d, etc., as well as the total
average number of photons in a photon gas and its total energy, we need to know the
density of states for photons as a function of photon energy.
1 4 / 3 k 3 k 3 volume k3
N k G k
8 6 2 6 2
kx
Lx Ly Lz
ky dG 3 2
g cp ck G g 3D
d 6 2 c 2 2 c
3 ph 3
extra factor of 2:
g g
3D 3D d
h 2
h 8 2
2
3
3D 8 2
g 3
two polarizations d c
ph ph 3 ph
c c
Spektrum Radiasi Benda Hitam
Rata-rata jumlah foton per satuan volume denga frekwensi dan +d:
8 h 3
g f d uS , T d us , T h g f 3
c exp h 1
d
u adalah fungsi energi: u , T d u , T d u , T u , T u h , T h
d
8 3
Radiasi spektrum u , T
benda hitam hc 3 exp
1
B
k T
8 h 3 8 2
us , T 3
- Hasil secara klasik (no h), dapat
3 k BT
c exp h 1 c diperoleh langsung dari ekipartisi
Hukum Rayleigh-Jeans
8 k BT
u , T large 1
4
4
frekwensi tinggi , Hukum Pergeseran Wien’s
h 3
du d k BT 3x 2 x 3e x
const const x 2
0
max 2.8
k BT d h
d
h
exp 1 e 1 x
e 1
h k BT k BT
3 x e x 3 x 2.8
h max Hukum
2 .8 Pergeseran
k BT
u(,T)
Wien
- the “most likely” frequency of a photon in a
blackbody radiation with temperature T
Numerous applications
(e.g., non-contact radiation thermometry)
max max
h max
u , T u , T 2.8 - does this mean that
k BT
hc
2.8 ? Wrong!
max max k BT max
3
c
h
d hc 8 hc 8 hc
u , T d u , T d 1
d u , T
2 hc 3 exp hc 1 2 5 exp hc 1
k T k T
B B
du d
const 5
1
const 6
5
5
x 2 exp 1 / x
0
2
df dx x exp 1 / x 1 x exp 1 / x 1 x exp 1 / x 1
T = 300 K max 10 m
2 5 k B
4
Tetapan Stefan-Boltzmann 4 4 Hukum Stefan-
u T T Boltzmann
15h 3c 2 c
uT 8 5 k BT hc 4
4 3
k BT 2.7 k BT
15hc 8 k BT 2.4
3 3
N 15 2.4
energy density u
1m2
c 1s
Integrasi ke semua sudut kalikan fktor ¼:
1
power emitted by unit area cu
4
(ukuran lubang >> panjang gelombang)
Consider a human body at 310K. The power emitted by the body: T 4 500 W / m2
While the emissivity of skin is considerably less than 1, it emits sufficient infrared
radiation to be easily detectable by modern techniques (night vision).
Radiative transfer:
Liquid nitrogen is stored in a vacuum or Dewar flask, a container surrounded by a thin
evacuated jacket. While the thermal conductivity of gas at very low pressure is small, energy
can still be transferred by radiation. Both surfaces, cold and warm, radiate at a rate:
J rad 1 r Ti
4 i=a for the outer (hot) wall, i=b for the inner (cold) wall,
W / m2
r – the coefficient of reflection, (1-r) – the coefficient of emission
Let the total ingoing flux be J, and the total outgoing flux be J’:
Dewar
J 1 r Ta4 rJ J 1 r Tb4 rJ
1 r
The net ingoing flux: J J
1 r
Ta4 Tb4
If r=0.98 (walls are covered with silver mirror), the net flux is reduced to
1% of the value it would have if the surfaces were black bodies (r=0).
Efek Rumah Kaca
Absorption:
2
4 R
Power in RE TSun Sun
2
Rorbit
the flux of the solar radiation energy
received by the Earth ~ 1370 W/m2
Power out 4 RE TE
2 4
Emission:
1/ 4
R 2
TE Sun TSun
4 Rorbit
Rorbit = 1.5·1011 m
Transmittance of the Earth atmosphere RSun = 7·108 m
2 5 k B
4
15h 3c 2 m2K 4
This result is consistent with the flux of the solar radiation energy received by the Earth
(1370 W/m2) being multiplied by the area of a sphere with radius 1.5·1011 m (Sun-Earth
distance).
4
P 4 RSun
2 hc
2
4 7 108 m 5.7 10 8 2 4 5,740K 4 3.8 10 26 W
W
2.8 k B max mK
dm P 3.8 1026 W
the mass loss per one second 2 4.2 10 9
kg/s
dt c
3 10 m
8 2
1% of Sun’s mass will be lost in 0.01M 2 1028 kg
t 4.7 1018 s 1.5 1011 yr
dm / dt 4.2 10 kg/s
9
Fungsi Distribusi untuk gas Fermi Ideal
The probability of the i-state with energy i to be occupied n ni
P i , ni
1
by ni particles (the total energy of this state ni i) :
exp i i
Z k BT
The grand partition function for all particles in the ith single- n
particle state (the sum is taken over all possible values of ni) : Z i exp i i
ni k BT
If the particles are fermions, n can only be 0 or 1:
Z i 1 exp
The mean number of particles in this state: k B T
exp
ni ni Pni 0 P0 1 P1 k BT 1
1 exp 1 exp
ni
k B T B
k T
n
1
- the Fermi-Dirac ~ kBT
distribution
exp 1
k BT
ni
1
1 Z x 1 e x
1 e
1
ni
Distribusi Bose
Z x x 1 e x 1 e x e x 1 exp 1 Einstein
k BT
The mean number of particles in a given state for the BEG can exceed unity, it diverges as
, and is nonexistent for > .
Probabilitas, Fungsi Distribusi, Rapat Keadaan ….
f E n E
While f(E) is often less than unity (much less in the case of an ideal gas), it is not a
probability. (e.g., it can exceed unity in a Bose gas).
f E n
i
where n=N/V – the density of particles
where g() is the
If we can neglect the
spectrum discreteness:
n g f d density of states
0
Kaitan Termodinamika, Potensial Kimia
Consider the grand potential kBT ln Z which is a generalization of F=-kBT lnZ
- the appearance of μ as a variable, while computationally very convenient for the grand
canonical ensemble, is not natural. Thermodynamic properties of systems are
eventually measured with a given density of particles. However, in the grand canonical
ensemble, quantities like pressure or N are given as functions of the “natural” variables
T,V and μ. Thus, we need to use / T ,V N to eliminate μ in terms of T and
n=N/V.
S U F
n, T T
N U ,V N S ,V N T ,V
MB < 0: - the occupancy nB exp cannot be negative for any
B
k T
Potensial Kimia untuk Gas Fermi
g
nF f F
1
Fermi
n g f d d
Gas exp 1 T , n
0 0
exp 1
B
k T
k B T
T ,V , N n N / V T , n
When the average number of fermions in a system (their density) is known, this equation
can be considered as an implicit integral equation for (T,n). It also shows that
determines the mean number of particles in the system just as T determines the mean
energy. However, solving the eq. is a non-trivial task.
/EF
2 2
k BT depending on n and T, for 1
1 .... fermions may be either
EF 12 EF positive or negative. 1 kBT/EF
The limit T0: adding one fermion to the system at T=0 increases its energy U by EF. In
this situation F = U-TS = U (S is also 0: all the fermions are packed into the lowest-energy
states), so that the chemical potential, which is the change in F produced by the addition
of one particle, is EF: T 0 E F
g
n g f d
Bose 1
nBE d
Gas
exp 1 0 0
exp 1
k BT B
k T
The occupancy cannot be negative for any , thus, for bosons,
0 ( varies from 0 to ). Also, as T0, 0 T
0, 0
nBE T 0 1
nBE T 0
exp 0 / 0 1 1, 0
For bosons, the chemical potential is a non-trivial function of the density and temperature
(for details, see the lecture on BE condensation).
Pendekatan Klasik
The Fermi-Dirac and Bose-Einstein distributions must reduce to the Maxwell-
Boltzmann distribution in the classical limit, ni 1 for all i. Hence,
1 the Maxwell-
ni exp
exp 1 and k BT Boltzmann
B
k T exp distribution
B
k T
The same result, of course, we would get if we start from the equation for the
average nk in Boltzmann statistics:
Z
ni NPs
N Z
exp k BT ln 1 1 exp exp exp exp
Z1 k BT N N k BT k BT k BT k BT
=
Pendekatan Klasik (cont.)
3/ 2
2 mkBT
In terms of the density, the classical limit n nQ 2
corresponds to n << the quantum density: h
We can also rewrite this condition as T>>TC where TC is the so-called degeneracy
temperature of the gas, which corresponds to the condition n~ nQ. More accurately:
2/3
h2 n
TC
2 mkB 2 .6
For the FD gas, TC ~ EF/kB where EF is the Fermi energy (Lect. 24) , for the BE gas
TC is the temperature of BE condensation (Lect. 26).
g
3/ 2
2 s 1 2m
3/ 2
x1/ 2
d g
2 s 1 2 mk T
n 2 2
1/ 2
2
B
dx
0
exp 1 4 4 2
0 exp x 1
Since 0, the maximum possible value of x1/ 2
n is obtained when = 0, and 0 exp x 1 dx 1.3
2 s 1 2mkBT
3/ 2
where nQ is the quantum concentration,
ncr 1.3 2.6nQ
4 2 2 which varies as T 3/2
Pendekatan Ketiga Distribusi
S
Fermi-Dirac Nk B
Maxwell-Boltzmann
3
Bose-Einstein
U
k BTC 2
2
T
1 2 3 TC
zero-point 1
energy,
Pauli 2/3
h2 n
principle TC
T 2 mkB 2 .6
1 2 3 TC
Comparison between Distributions
CV /NkB
Fermi-Dirac
Maxwell-Boltzmann
Bose-Einstein
2
1.5
0 1 T/TC
Comparison between Distributions
Maxwell Bose Fermi
Boltzmann Einstein Dirac
1 1 1
nk nk nk
exp exp 1 exp 1
k BT k BT k BT
distinguishable indistinguishable indistinguishable
Z=(Z1)N/N! integer spin 0,1,2 … half-integer spin 1/2,3/2,5/2 …
nK<<1
Paramagnetism
Fungsi Partisi
Aplikasi Statistik Termodinamika
Fungsi Partisi
Aplikasi Statistik Termodinamika