Beruflich Dokumente
Kultur Dokumente
Reservoirs
Stephen A. Sonnenberg
Colorado School of Mines
Unconventional Reservoirs
• Outline
• General comments
• Conventional and Continuous Accumulations
• Basin center concept
• Tight gas
• Shale gas
• CBM
• Tight Oil
• Bituminous Sands
• Oil Shale
• Halo Oil
• Gas hydrates
Unconventional Characteristics
• Recoverable reserves are huge
Tight
Oil & Gas
Pore Sizes
Nelson, 2009
Hartman and Beaumont, 1999
Viscosity (cp) Permeability md
Tight Gas 0.01
Reservoirs Poor
<0.1
0.1
Poor
< 0.1
Tight Oil
Reservoirs
Poor – Fair
0.1-15
10
Good - Very Good
15 – 1,000
100
Good - Very Good
Heavy Oil
50 – 1,000
&
1,000
Tar Sand
Reservoirs Good
10,000 50 – 250+
1 microdarcy
1E-06 1E-05
1 nanodarcy
Cander, 2012
Sorption
• Adsorption is a process when a
gas or liquid solute accumulates
on the surface of a solid forming
a molecular or atomic film (the
adsorbate)
• Absorption is a physical or
chemical phenomenon or a
process in which atoms,
molecules, or ions enter some
bulk phase – gas, liquid, or solid
material. The molecules are
taken up by the volume, not the
surface.
Three Principal Types of
Unconventional Reservoir Systems
Primarily a
Sorbed Gas Reservoir
AAPG wiki
Migration
Capillary Entry Pressure Controls on
Hydrocarbon Emplacement
Interfacial tension
Reservoir Pore throat radius r (seal)
Buoyancy Pressure
Pb= h(w-o)g
Petroleum density hc
Water density w
Buoyancy Pressure Petroleum column height h
g = 0.433 = slope or static fluid pressure
X 0.433 (slope or static fluid pressure
gradient)
Schowalter, 1979
Controls on Hydrocarbon Emplacement
Non buoyancy
related?
UNCONVENTIONAL/
CONTINUOUS CONVENTIONAL
RESERVOIRS RESERVOIRS
Reservoir Trap
Microbial
Rock (oil fields)
Gas Zone
Conventional
Structural
Oil Shale Stratigraphic
Combination
Tar / Bituminous
Source
Rock Sand Unconventional
Coalbed Methane
Oil Window
Ro 0.6 – 1.3 Shale Gas
Gas Window Tight
Ro 1.3 – 3.+ Sand/Carbonate
Overpressured (‘continuous’) Gas
Cell
Tight Gas SS Shallow Basin
Methane (biogenic)
Hi-rate HC Generation 8000 ft Tight Oil
4000 ft Oil Shale
Base HC Generation
Tar Sands
0
Over-Pressured Cell 0 100 200 300 miles
Primary migration is an inefficient process and does not act equally on all of the
chemical components of oils, so composition changes have been observed between
source rock extracts and expelled oils.
Petrographic Test for Onset of Oil
Generation
kerogen-bitumen
300oC/72h
Hydrous Pyrolysis of
Woodford Shale Cores 125 μm
bitumen-oil 352oC/72h
Lewan (1987)
https://www.youtube.com/watch?v=lISNwF5tMXM
Conceptual Burial History of
Unit – Volume of Oil - Source
High
Low
Province
Resource Size
SAS, 04
Resource Plays
The Resource Pyramid
Conventional Reservoirs:
Small Volumes,
Easy to Develop
Oil Gas
Improving Technology
Unconventional Reservoirs:
Large Volumes, Tight
Tight
Hard to Develop Oil; Shale Oil
“Resource Plays”
Gas Sands;
Heavy Oil;
CBM;
Bituminous
Gas Shales
Sands;
Halo Plays
Huge
Volumes,
Difficult Oil Shale Gas Hydrates
to Develop
Theloy, 2013
Why not just
Shale Drilling a horizontal well?
and Completions
Heavy-Oil Deposits
Demaison, 1977
http://woodshole.er.usgs.gov/project-pages/hydrates/primer.html
Petroleum and
other Liquid Production
http://www.eia.gov/forecasts/aeo/er/executive_summary.cfm
Gas Production
http://www.eia.gov/energy_in_brief/article/about_shale_gas.cfm
Hubbert’s Prediction for US crude oil production (1956) and
actual lower-48 states production through 2014
https://www.oil-price.net/
Petroleum Systems
The Petroleum System
Keys:
• Source
• Seal
• Maturity
• Expulsion
• Migration
• Reservoir
• Trap
• Preservation
PETROLEUM SYSTEM
Trap
Reservoir (oil fields)
Surface Rock
Microbial
Gas zone Source
Rock
Oil and Wet Gas
Zone
Dry Gas
Zone
4000 ft
Onset of dry gas generation
0
0 100 200 300 miles
Zero edge
of
reservoir
rock
Migration pathways
0
Over-Pressured Cell 0 100 200 300 miles
• Humic:
• Mainly carbohydrates and lignins
• Tends to produce coal and gas
• Land plant material, plant cell, and wall material made up of
lignin, cellulose, and aromatic tannins
Kerogen Types
• Well-laminated or relatively
unburrowed sediments
• Elevated total organic
carbon contents
• Preserved local (aquatic)
organisms
• Black color
• Elevated trace element
values (Mo, Ni, Cu, V, U)
• Syngenetic pyrite
Tribovillard et al., 2006
Jarvie et al., 2007
Source Rock
Maturity
Critical Ro Values
Gas
• With increasing temperature and pressure, organic matter (OM) is converted to oil and gas,
and eventually oil is cracked to gas as well
Demaison, 1993
Concentration of oil reserves
• Two major cycles of source beds
• Paleozoic cycle: ~13% of reserves of conventional
oil
• Jurassic to Tertiary cycle 85% of worlds reserves
• Prolific source rocks during Jurassic and Cretaceous
periods are responsible for ~70% of world’s conventional
crude (180 to 85 m.y.)
• Heavy oils mainly in cycle 2
Tissot and Welte, 1984
Tissot and Welte, 1984
Tissot and Welte, 1984
Tissot and Welte, 1984
Tissot and Welte, 1984
Overpressuring by
Hydrocarbon
Generation
Overpressures Generated by
Hydrocarbon Generation
Overpressuring in Rockies Basins
“MATURE”
VOLUME OF GENERATED
FLUID HYDROCARBONS
VOLUME OF ORIGINAL
UNMETAMORPHOSED VOLUME OF METAMORPHOSED
“IMMATURE ORGANIC ORGANIC MATERIAL
MATERIAL (KEROGEN)
“Sweet
Spot”
Diagenesis Fractures
Pyrolysis
Rock-Eval & SRA Pyrolysis
• Pyrolysis is defined as the heating of OM in the
absence of oxygen
• In Rock-Eval & SRA pyrolysis, pulverized samples
are gradually heated under an inert atmosphere
• Heating distills the free organic compounds (bitumen),
then cracks pyrolytic products from the insoluble OM
(Kerogen)
Operating Conditions
• Samples of whole rock up to about 100 mg are
pyrolyzed at 300oC, followed by programmed
pyrolysis at 25oC/min to 550oC, both in a helium
atmosphere
• Each analysis takes about 20 minutes (allowing
time to cool the oven)
Schematic diagram of a Rock-Eval pyrolyzer (Waples, 1985)
Pyrolysis
132
Rock-Eval Parameters
• S1 peak is produced by free hydrocarbons
thermally distilled from the rock
• S2 peak is produced by hydrocarbons pyrolyzed
from the kerogen
• S3 peak is produced by carbon dioxide pyrolyzed
from the kerogen
• Tmax is the temperature at which maximum
evolution of S2 hydrocarbons occurs
• Production index = S1/(S1+S2)
Pyrolysis = Thermal Cracking
• Source-rock potential is measured by pyrolyzing
rock samples in an inert atmosphere
• The kerogen cracks to form volatile hydrocarbons
which are quantitatively measured as S2
• S2 = residual source-rock potential
0.5
Peters, 1986
HI = (S2 / TOC) X 100
OI = (S3 / TOC) X 100
Peters, 1986
Peters And Cassa, 1994
Peters and Cassa, 1994
HI = S2 / TOC
OI = S3 / TOC
Peters, 1986
Waples, 1985
Oil-Generating Ability of Macerals is
Variable
HI = 667(H/C) – 570(O/C) - 333
Waples, 1985
Changes in pyrograms, production index and Tmax with depth or thermal
maturity for core samples from the Tertiary of West Africa (from Waples,
1987)
Van Krevelen HI/OI
1000
Type I
900
800
700 0-4000
Type II
HI (mg HC/gm OC)
4001-6000
600 6001-8000
8001-10000
500
10001-12000
400 TYPE I
TYPE II
300 TYPE III
200
Type III
100
0
0 20 40 60 80 100
OI (mg CO2/gm OC)
HI versus Tmax
1000
900
Type I
800
700
Elm Coulee V
600
Hydrogen Index
Elm Coulee W
0-4000
Type II
500 4001-6000
6001-8000
8001-10000
400
10001-12000
Tmax/HI 300
100
437\300 peak Type III
0
400 410 420 430 440 450 460
Tmax
Kerogen Quality Plot
160
140
Type II: Oil Prone
Usually Marine
120
Type I: Oil Prone
Usually Lacustrine
100 Increasing Maturity 0-4000
4001-6000
S2
80 6001-8000
Type II/III:
Oil/Gas Prone 8001-10000
60 10001-12000
40
Type III:
Gas Prone
20
0
0 5 10 15 20 25 30
TOC (wt%)
TOC
0 5 10 15 20 25
400
410
420 0-4000
4001-6000
TMax
430 6001-8000
8001-10000
440 10001-12000
450
460
0.5
0.45
0.4
0.35
Production Index
0-4000
0.3
4001-6000
0.25 6001-8000
0.2 8001-10000
10001-12000
0.15
Oil Zone
0.1
Immature
0.05
0
380 400 420 440 460 480 500
Tmax
S1/TOC
0.00 20.00 40.00 60.00 80.00 100.00 120.00 140.00
0
2000
Webster, 1984
4000
Elm Coulee V
Elm Coulee W
Depth
Price, 1984
6000
Koch
Peterson
Pullam & Fleckton Mertz
Waswick
Braaflat (S-P)
8000
Slater Foghorn (EC)
High Geothermal Gradient
Dobrinski
7650 ft
10000 Kennedy
The Source Rock Analyser (SRA) quantitatively determines the amount of free hydrocarbons (S1), the residual generative
potential of the rock (S2), the amount of oxygen compounds decomposed during pyrolysis (S3) and the organic carbon remaining
after the S2 peak (S4). The SRA also determines tTemp, the temperature recorded at the time of the maximum S2 peak. By
summing the S1, S2 and S4 peaks, the SRA determines TOC
Summary of Method
• HI = (S2/TOC) X 100
• OI = (S3/TOC) X 100
• PI = S1/(S1+S2)
• TOC=[S4+(0.83(S1+S2))]/10
Mudrocks
Mudrocks
• fine-grained
Facies E
U. Bakken (10,077 – 10,084 ft)
M. Bakken Facies C
(10,102 – 10,119 ft)
Facies D
(10,084 – 10,102 ft)
L. Bakken
Facies A
(10,142 – 10,146 ft)
mudstone claystone
siltstone
mudshale clayshale
Claystone 0 m 4 m
Mudstone 0 m 64 m
Shale 0 m 64 m
Siltstone 4 m 64 m
Adapted from Lazar et al., 2015
Average “shale” compositions
Average “shale” compositions
Radiolaria
Diatoms
Distribution of main types of marine sediments (after Davies & Gorsline, 1976)
Mudrock microfossils Scholle, 2016
Distribution and Accumulation
• Three factors
• Rates of production of biogenic particles in surface
waters
• Nutrient supply and temperature
• Dissolution rates of those particles in the water column
after they reach the bottom
• Chemistry of deep ocean, bottom and interstitial waters
• Rates of dilution by terrigenous sediments
Carbonate Oozes
• Tiny (< 10 microns) calcareous plates produced by
phytoplankton of the marine algal group
• Foraminiferal ooze is dominated by the tests of
planktic protists
• Most foraminiferal tests are sand sized (> 61 microns in
diameter)
• Oozes are bimodal in particle-size distribution
because they are made of sand size foraminiferal
tests and mud-sized coccolith plates
Siliceous Oozes
• Two major contributors
• Golden-brown algae known as diatoms construct a shell
called a frustule out of opalline silica
• Radiolaria – large group of marine protists also construct
opalline silica skeletons
• Silica is undersaturated throughout most of the
world's oceans
• Siliceous sediments are most common beneath
upwelling zones
• Accumulation rates of siliceous oozes can reach 4-5
cm/1,000 years in these areas
Mudrock Deposition
Shales in Ancient Basins
Shelf-to-basin transition
Deltas prograde onto oceanic crust
• Most shales associated with prodelta muds
and medial and distal turbidites
A’
El Trapial Area, Vaca Muerta
URTeC 2154603
Crousse et al., 2015
Pore Sizes
Loucks et al., Picopore Nanopore Micropore Mesopore
2012 (pore dia.,)
Hartman et al., Micro- Meso- Macro-
1999 Nanopore Megapore
pore pore pore
(pore throat rd.)
Tight
Oil & Gas
Pore Sizes
Nelson, 2009
Hartman and Beaumont, 1999
Loucks et al., 2012
Mechanical
Stratigraphy
Corbett and Friedman, 1987
An example of multi-scale tectonic fracture development
from Gross (2009).
Sibson, 1996
From Michael Gross, 2017
Courtesy of M. Gross (2009) Nelson, 2010
Interbedded sandstone (white) and limestone
222
Nelson, 2010 Lorenz & Cooper (2010)
Sharon Springs Member, Pierre Shale
Niobrara Formation
A Chalk
B Chalk
C Chalk
D chalky marl
Fort Hays
Codell SS
Carlile Formation
Lincoln LS.
Graneros
Formation
D SS & Huntsman
Mowry Formation
J SS
Skull Creek
Fort Hays
“BRITTLE”
Chalk
Sweet
Spot
Codell Marls
Carlile “DUCTILE”
Sharon
Springs
Faults and Fractures
Mowry outcrop, courtesy of Zach Hollon (2013)
Origin of Fractures
• Tectonic
• Folding and Faulting
• Wrench faults
• Solution of evaporites
• Regional Stress Field
• Far-field compression
• Regional epeirogenic uplift
• Diagenetic
• High Fluid Pressure
• Maturation of source rocks
• Compaction and dewatering
Gross and Eyal (2007)
Zahm and Hennings, 2009
“strongest material”
Generalized stress map, western US. Arrows represent direction of either least
(outward directed) or greatest (inward direction) principal horizontal stress
(modified from Zoback and Zoback, 1980)
Shmax Shmax
Regional Fractures
Systematic and Non-systematic
Modified from Lorenz et al., 1991, Nelson 2010
Regional Fractures Southern Powder River Basin
Predicted orientations
Laubach, 1992
“MATURE”
VOLUME OF GENERATED
FLUID HYDROCARBONS
VOLUME OF ORIGINAL
UNMETAMORPHOSED VOLUME OF METAMORPHOSED
“IMMATURE ORGANIC ORGANIC MATERIAL
MATERIAL (KEROGEN)
1000
2000
Pierre
3000 Shale
4000
5000 Sussex
(Terry)
Shannon
6000 Migration
(Hygiene)
9000
10000
0 1000 2000 3000 4000 5000 6000 7000
PRESSURE PSI
Weimer, 1995
Microfracture-induced hydrocarbon-phase migration during oil generation.
A. Initial stage prior to oil generation, source rock is water-wet.
B. Oil generation has occurred, oil-wet pore network around kerogen.
Bend, 2007
Polygonal Fault Systems
• Gravity collapse
• Density inversion
• Compactional loading
• Syneresis
• Diagenetically-induced shear failure
Cartwright et al., 2003; Cartwright, 2011
Selley, 1998
Density inversion
7900
Sharon Springs
A Chalk
A Marl
CORE B1 Chalk
TOC
3.17
8000
4.2
2.5
NIOBRARA
2.3 B2 Chalk
7.8
B Marl
8100
C Chalk
C Marl
Fort Hays
8200
Codell SS
AC-3
AM-2
0.06
AM-3
30 – 40 nm BC-3
0.05
(cm3/g)
BM-1
0.04 BM-2
CC-1
0.03 ~ 6 nm CM-2
0.02 CM-3
DM-2
0.01 DM-3
0.00 FH-2
0.1 1 10 100 FH-1
FH-3
Pore Diameter (nm)
282
Nitrogen Adsorption Tests
14.0 12.24
12.0 9.38 9.37
10.0 7.93
284
9273
UBS 9286
MB 9290
9311
LBS
XRF DATA
Detrital indicators
Al, Ti, K, Mn
Ca, Si
Organic Elements
Cr, Zn, Mo, V, Cu, Ni, U
Mn (?)
Organic Suite
Group 1: Al, Si, Ti, Rb, Zr, K and Th. These elements are associated to terrigenous minerals including clay minerals, feldspars, and
quartz.
Group 2: Cu, V and Cr. This group is associated with organic matter, redox conditions and is indicative of suboxic environments.
Group 3: S, Mo, Ni, Fe, U and Zn. These elements are associated to anoxic conditions.
Group 4: Ca and Sr. These elements are associated with carbonate. This is consistent with other studies that relate these elements to
diagenesis and aragonite to calcite alterations (Al Ibrahim, 2014; Pingitore Jr., 1978).
Group 5: Consists of Mn element that is associated to oxic to suboxic conditions.
Sharon Springs Member, Pierre Shale
A Chalk
Niobrara Formation
A marl
B Chalk
B marl
C Chalk
C marl
D marl
Fort Hays
Codell SS
Carlile Formation
Bridge Creek
Greenhorn
Hartland Formation
Lincoln
Graneros
Formation
Sharon Springs Member, Pierre Shale
A Chalk
Niobrara Formation
A marl
B Chalk
B marl
“K” C Chalk
C marl
D marl
Fort Hays
Codell SS
Carlile Formation
Bridge Creek
Hartland
Greenhorn
Formation
Lincoln
Graneros
Formation
GRI-method permeability is an unsteady state gas pressure-decay technique and may be determined using
particles containing as-received pore liquids, yielding an effective kg or using clean-dry particles, yielding
an absolute kg. In some cases, both permeabilities are determined. The effects of coring- or sampling-
induced fractures and cracks are eliminated by use of small-particle samples and because of this the
results are often referred to as matrix permeability or km.
Particles in the 20-35 US mesh size range (0.85 to 0.5mm), above, are used in the GRI core analysis method.
In typical shale or mudrock, each particle will contain many thousands of individual grains and the associated
pore bodies and pore throats.
KSDR=perm SDR
KTIM=perm Timur
MRI CLA=clay
QFM=quartz+feld+m
PERM CAR=carbonate
ANH=anhydrite
CAR Lodgepole
P CY
Maturity effects on
Well Log Response
0
Resistivity
SHALLOW, LOW RESISTIVITY TREND
REPRESENTS COMPACTION OF A
SALT WATER-SATURATED ORGANIC-
and Bakken
2000 RICH CALCAREOUS SHALE
hydrocarbon
generation,
depth: >6500’
DEEP, HIGH RESISTIVITY
CHARACTER
4000 REPRESENTS A HYDROCARBON-
Well Depth, feet
SUGGESTED TEMPERATURE OF
HYDROCARBON GENERATION AT 1650F
1500
Suggested
2000 temperature of HC
generation = 165oF or
74oC
2500
3000
30 ohm-m
= mature source rocks
3500
0 25 50 75 100
ELECTRICAL RESISTIVITY ohm-meters
USA
MATURE “HIGH”-RESISTIVITY
BAKKEN SHALE
Matrix Oil Saturated
ND
MT
0 50
SD
IMMATURE “LOW”-RESISTIVITY
MILES
BAKKEN SHALE
Matrix Water Saturated
Meissner, 1978
Water Wet
Change in pore-
fluid volume
(porosity) and pore-
fluid species which
may accompany
hydrocarbon-
generation
(maturity) in source
Oil Wet
rocks
Meissner, 1978
Petrographic Test for Onset of Oil
Generation
kerogen-bitumen
300oC/72h
Hydrous Pyrolysis of
Woodford Shale Cores 125 μm
bitumen-oil 352oC/72h
Lewan (1987)
Resistivity Changes
Oil to the Gas
Window
Hinds and Berg, 1990
The Wattenberg
Geothermal
Anomaly
Vitrinite Reflectance
Values, %Ro
1E+13
Eagle Ford Mudrock
1E+12
Electrical Resistivity (ohm-m)
Haynesville Mudrock
1E+11 Haynesville Kerogen
1E+10 Eagle Ford Kerogen
1E+09
1E+08
1E+07
1E+06
1E+05
1E+04
Decrease in conductive
1E+03 pathways is dominant Increase of graphitization is dominant
1E+02
0 100 200 300 400 500 600 700 800
Heat-Treatment Temperature (°C)
Tight
Oil
Pore Sizes
Nelson, 2009
Passey et al., 2012
Why Directional
Wells?
Blanket and Lenticular Reservoirs
Why
Shale not just
Drilling a horizontal well?
and Completions
Cemented Bottom Hole
Assembly
Basin Appalachian Fort Worth Oklahoma Arkoma Michigan Illinois Gulf Coast Gulf Coast Williston Denver Neuquén
Age Devonian Mississippian L. Devonian Mississippian Devonian Devonian Cretaceous Jurassic Late Dev-Miss U Cretaceous Jurassic
Silica-rich black
Black and Gray Black and Gray Siliceous Black
Play Type Siliceous Shale shale Black Shale Black Shale Calcareous Shale Siliceous Marl Marls & Chalk Siliceous Marl
Shale Shale Shale
Maturation (Vr
1.3-2.4 1.1 - 1.4 0.8-2.9 1.2 – 2.0+ 0.6 - 0.7 0.6 - 1.2 0.5-2.2 0.94-2.62 0.6-1.1 0.6-1.5 0.5-2.6
%)
Richness (wt %
4-7 2-5 3-6.5 2 – 6.9 5 - 15 5 - 20 4.5-5.5 3.0-10.0 4-12 4-6 2.0-12
TOC)
Porosity (%) 7-9 3-7 5-7 4-9 5 - 12 5 - 12 4-10 7.0-9.0 5-7 6-12 7-12
Mineralogy
45-70 45 - 70 40-70 na 55 - 70 50 - 70 50-70 50-70 40-70 50-70 50-70
(% Non - Clay)
Thickness (ft) 50-300 200 - 400 50-300 200-300 70-120 180 80-300 180-270 40-60 300-400 100-1800
Depth (ft) 5,000-8,500 7,000 - 8,500 6,000-13,000 3,000-7,000 500 - 2,500 1,000 - 2,500 5,000-12,000 10,000-13,500 8,000-10,000 7,000-9,000 8,000-11,000
Pressure Grad.
0.6+ 0.50 0.5-0.7 0.45 (?) 0.43 ~ 0.43 0.6-0.9 0.9-1.1 0.5-0.76 0.5+ 0.6-1.1
(psi/ft)
Critical to Prod.,
Natural Critical to Critical to Critical to
yes faults into lower yes yes yes yes yes yes
Fractures Productivity Productivity Productivity
water bad.
The Unconventional
Check List
Unconventional, Continuous
Tight Oil\Gas Accumulations
• Pervasive accumulations that are hydrocarbon saturated
• Not localized by buoyancy
• Abnormally pressured (high or low)
• Commonly lack downdip water
• Updip contact with regional water saturation
• Low-permeability and low matrix porosity reservoirs
• Reservoirs may be single or vertically stacked
• Commonly enhanced by fracturing
• Associated with mature source rocks that are either actively generating or have recently
ceased generation
• Hydrocarbons of thermal origin
• Fields have diffuse boundaries
• Inverted Petroleum Systems
• Tectonically quiet
• GOR ~ 1000 cu ft / bbl