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Quantum Mechanics
It is strange yet successful Contradictory Yet fundamental Mysterious Yet intellectual Unreal Yet very very real
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What is it?
Quantum Mechanics
The most successful theory that humanity has ever developed; the brightest jewel in our intellectual crown
D. F. Styer
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Because ...
Niels Bohr 1927 said: Anyone who is not shocked by quantum mechanics has not understood it
Richard Feynmann 1967 said: I can safely said that nobody understands it
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Classical mechanics is the mechanics of everyday objects like tables and chairs 1. An object in motion tends to stay in motion. 2. Force equals mass times acceleration 3. For every action there is an equal and Sir Isaac Newton opposite reaction.
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1788 Lagranges Mecanique Analytique 1834 Hamiltonian mechanics 1864 Maxwells equations 1900 Boltzmanns entropy equation
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However, several experiments at the beginning of the 20th -century defied explanation
?
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Stern-Gerlach experiment Otto Stern wanted to test the quantization of the angular momentum L in atoms by testing the quantization of the magnetic moment it would imply. He shot atoms through an asymmetric magnetic field. If the atoms have magnetic moment of 1 Bohr magneton, the beam should split into three parts as the magnetic force depends on the direction of the magnetic moment. Stern and Walther Gerlach so the splitting of the beam in 1922 using silver atoms.
The splitting is actually due to the internal angular momentum, the spin
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Quantum mechanics was developed to explain these results and developed into the most successful physical theory in history
1900 Plancks constant
Increasing weirdness
1913 Bohrs model of the atom 1925 Pauli exclusion principle 1926 Schrodinger equation 1948 Feynmanns path integral formulation 1954 Everetts many-world theory
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Although quantum mechanics applies to all objects, the effects of quantum mechanics are most noticeable only for very small objects
How small is very small? 1 meter 1 millimeter 1 micrometer Looks classical Looks classical Looks classical
1 nanometer
Looks quantum!
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Particles
Position x Mass m Momentum p = mv
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Waves
Wavelength
Amplitude A
Frequency f
number of cycles per second
f=c/
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Diffraction
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Interference
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de Broglie
All matter, usually thought of as particles, should exhibit wave-like behaviour Implies that electrons, neutrons, etc., are waves!
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de Broglie Wavelength
Wave-Particle Duality
particle wave function
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Photoelectric Effect
When blue light is shone on the emitter plate, a current flows in the circuit
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Experimental Observations
Only light with a frequency greater than a certain threshold will produce a current Current begins almost instantaneously, even for light of very low intensity Current is proportional to the intensity of the incident light
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Einsteins Explanation
Light consists of particles, now known as photons A photon hitting the emitter plate will eject an electron if it has enough energy Each photon has energy: E = hf (same as Plancks formula)
(1905)
Albert Einstein won a Nobel Prize for his work on the photoelectric effect and not his theory of relativity!
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The laws of quantum mechanics are founded upon several fundamental postulates
The Fundamental Postulates of Quantum Mechanics: 1. Postulate 1: All information about a system is provided by the systems wave function. Postulate 2: The motion of a nonrelativistic particle is governed by the Schrodinger equation Postulate 3: Measurement of a system is associated with a linear, Hermitian operator
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Postulate 1: All information about a system is provided by the systems wave function.
Interesting facts about the wave function: 1. The wave function can be positive, negative, or complex-valued. 2. The squared amplitude of the wave function at position x is equal to the probability of observing the particle at position x. 3. The wave function can change with time. 4. The existence of a wave function implies particle-wave duality.
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Wave Function
Completely describes all the properties of a given particle Called = (x,t); is a complex function of position x and time t What is the meaning of this wave function?
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Copenhagen Interpretation:
probability waves
The quantity | | 2 is interpreted as the probability that the particle can be found at a particular point x and a particular time t The act of measurement collapses the wave function and turns it into a particle
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The Weirdness of Postulate 1: Quantum particles are usually delocalized, meaning they do not have a well-specified position
Classical particle
Position = x
Quantum particle
Wavefunction = (x)
With some high probability, the particle is probably somewhere around here
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The Weirdness of Postulate 1: At a given instant in time, the position and momentum of a particle cannot both be known with absolute certainty
Classical particle Hello, my name is: Classical particle Quantum particle
Wavefunction = (x)
I can tell you my exact position, but then I cant tell you my momentum. I can tell you my exact momentum, but then I cant tell you my position. I can give you a pretty good estimate of my position, but then I have to give you a bad estimate of my momentum. I can
The Weirdness of Postulate 1: a particle can be put into a superposition of multiple states at once
Classical elephant: Valid states:
Gray Gray Multicolored
Multicolored
The Weirdness of Postulate 2: A quantum mechanical particle can tunnel through barriers rather than going over them.
Classical ball Quantum ball
This effect is the basis for the scanning tunneling electron microscope (STEM)
The Schrodinger equation indicates that there is a nonzero probability for a particle to take any path
This consequence is stated rigorously in Feymnanns path integral 48 formulation of quantum mechanics
Postulate 3: Measurement of a quantum mechanical system is associated with some linear, Hermitian operator .
Interesting facts about the measurement postulate: 1.It implies that certain properties can only achieve a discrete set of measured values 2. It implies that measurement is inherently probabilistic. 3.It implies that measurement necessarily alters the observed system.
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The Weirdness of Postulate 3: Even if the exact wave function is known, the outcome of measurement is inherently probabilistic
Classical Elephant: Before measurement or After measurement For a known state, outcome is deterministic. For a known state, outcome is probabilistic.
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Quantum Elephant:
Before measurement
After measurement State of the system is unchanged by measurement. Measurement changes the state of the system.
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The Weirdness of Postulate 3: Properties are actions to be performed, not labels to be read
Classical Elephant:
Position = here Color = grey Size = large
Quantum Elephant:
Position:
The position of an object exists independently of measurement and is simply read by the observer
In other words, properties like position or momentum do not exist 52 ) independent of measurement! (*unless yourea neorealist
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Role of an Observer
The observer is objective and passive Physical events happen independently of whether there is an observer or not This is known as objective reality
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The more accurately you know the position (i.e., the smaller x is) , the less accurately you know the momentum (i.e., the larger p is); and vice versa
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Implications
It is impossible to know both the position and momentum exactly, i.e., x=0 and p=0 These uncertainties are inherent in the physical world and have nothing to do with the skill of the observer Because h is so small, these uncertainties are not observable in normal everyday situations
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Example of Baseball
A pitcher throws a 0.1-kg baseball at 40 m/s So momentum is 0.1 x 40 = 4 kg m/s Suppose the momentum is measured to an accuracy of 1 percent , i.e., p = 0.01 p = 4 x 10-2 kg m/s The uncertainty in position is then 2 No wonder one does not observe the effects of the uncertainty principle in everyday life!
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Example of Electron
Same situation, but baseball replaced by an electron which has mass 9.11 x 10-31 kg So momentum = 3.6 x 10-29 kg m/s and its uncertainty = 3.6 x 10-31 kg m/s The uncertainty in position is then
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In the one-slit experiment, particles that pass through the single slit produce an image on the detector
The One Slit Experiment
Gaussian distribution of detected particles
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If we use two slits, we might expect to obtain the sum of two single-slit distributions
The Two Slit Experiment
Expected result: sum of two Gaussians
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but an even cleverer physicist can test this hypothesis by configuring the emitter to emit the particles one at a time
The Two Slit Experiment
Electron interference pattern after (a) 8 electrons, (b) 270 electrons, (c) 2000 electrons, and (d) 6000 electrons
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The quantum mechanical explanation is that each particle passes through both slits and interferes with itself
The Quantum Explanation
Superposition state
Detector
The wave function of each particle is a probability wave which produces a probability interference pattern when it passes through the two slits.
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If a measurement device is placed on one of the slits, then the interference pattern disappears
Curioser and Curioser
Measurement device
Detector
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The measurement device has collapsed the wave function, leading to a loss of interference
Curioser and Curioser
Measuring device
Wavefunction collapse!
or
Detector
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Einstein suggested that there are hidden variables that actually determine the destiny of each particle. 77
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