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Introduction
X-ray diffraction techniques are very useful for crystal structure analysis and identification of different types of crystals. Experimental study of crystalline materials became possible rays. only after the discovery of X-rays. Diffraction occurs when waves traveling through an object wavelength. whose dimensions are order of wavelength. Typical inter atomic spacing in crystals is 2-3A. The x-rays have wavelengths (0.02A to 100A) in this range . x(0.02 100 Hence x-ray diffraction is utilized to study the crystal xstructures.
Braggs law
Braggs law states that, the path difference between the two reflected rays by the crystal planes should be an integral multiple of wavelength of incident x-rays for producing maxima or constructive interference.
P Q A Plane 1
90 90
R S
C Plane 2 Plane 3 B
CB BD ! nP CB ! BD ! d sinU 2d sinU ! nP
Where n = 1,2,3,..first , second order etc. For 1st order sin 1 = /2d. For 2nd order sin 2 = 2 / 2d. For 3rd order sin 3 = 3 / 2d. where 1, 2 and 3 are the glancing angles for n=1,2 and 3 respectively.
Laue Method
Consider heterogeneous beam of X-Rays in the wavelength of X0.2 0.2A to 2A originating from a suitable source. 2 In this technique, the crystal is stationary in a heterogeneous beam of X-Rays. XThe diffraction pattern consists of a bright central spot and a set of spots arranged in a definite pattern about the central spot. The symmetrical pattern caused by diffraction of X-Rays by Xcrystal planes is called the Laue pattern. pattern.
Photographic Plate
Slits X-Rays Crystal
Laue Pattern
Photographic film
o
2
X-Rays Crystal
If The Crystal is fixed, for an incident angle , the diffracted angle becomes 2 . Consider, D is the distance between the crystal and photographic film and OP = R. Tan2 = OP/OC OP = OC tan2 R = D tan2 This method is used to study the orientation of the symmetry. crystal and verify the Crystal symmetry.
r
2 2
4 !s !s
Crystal Powder
4r
Applications of Powder Method Study of d-spacing. Study of mixtures. Study of alloys. Stress determination in metals. Determination of particle size.
Defects in Crystals
Introduction
In an ideal crystal, the atomic arrangement is perfectly regular and continuous but real crystals never perfect. perfect. They always contain a considerable density defects and imperfections that affect their physical, the r chemical ,mechanical and electronic properties. properties. Crystalline imperfections can be classified on the basis of their geometry under four main divisions namely
1.Vacancies or Schottky 2.Interstitialcies or Frenkel 3.Compositional defects. a. Substitutional b. interstitial 4.Electronic defects
1.Edge dislocation 2.Screw dislocation 1.Grain boundaries 2.Tilt boundaries 3.Twin boundaries 4.Stacking faults 1.Cracks 2.Voids or air bubbles
Defects
Perfect Crystal
Vacancy:
A Vacancy refers to an atomic site from where the atom is missing.
Compositional defects
A Substitutional impurity is a point imperfection and it refers to a foreign atom that substitutes for or replaces a parent atom in the crystal. A small sized atom occupying the void space in the parent crystal disturbing the parent atoms from their regular sites is an interstitial impurity.
Frenkel Defect: An atom leaves the regular site and occupies interstitial position. Such defects are called Frenkel defects.
The point imperfections in silver halides and CaF2 are of the Frenkel type.
Schottky defect:
A pair of one cat-aion and one anion can be missing from an ionic crystal as shown in a figure. such a pair of vacant ion sites is called Schottky defect.
Electronic defects Errors in charge distribution in solids are called electronic defects. These defects are produced, when the composition of an ionic crystal does not correspond to the exact Stoichiometric formula.
U ! nEv
The total number of ways to move n number of atoms out of N number of atoms in a crystal on to its surface will be
N! P! ( N n)!n!
The increase in entropy due to formation of n vacancies can be written as
S ! K B log P
N ! K B log{ ( N n!)!n!}
F ! U TS
At thermal equilibrium, free energy is constant and minimum with respect to n, hence
dF !o dn d (nE v K BT{NlogN (N n)log(N n) nlogn}) ! 0 dn E v ! K BT{1 log(N n) 1 logn} E v ! K BTlog{ Nn } n Nn Ev ! exp{ } n K BT N
if n
Ev n $ Nexp{ } K BT
U ! nE p
The total number of ways to move n numbers of ion pairs out of N number of ionic molecules in a crystal on to the surface will be
F ! U TS N! F ! nE p K BTlog[ ]2 (N n)!n!
N! log[ ]2 ! 2[NlogN N (N n)log(N n) (N n) nlogn n] (N n)!n! N! log[ ]2 ! 2[NlogN (N n)log(N n) nlogn n] (N n)!n! F ! nE v 2K BT[NlogN (N n)log(N n) nlogn]
At thermal equilibrium, free energy is constant and minimum with respect to n, hence
dF [ ]T ! 0 dn Nn E P ! 2K BTlog[ ] n Ep Nn ] ! log[ 2K BT n
n ! (N n)exp{ if n N Ep
Ep 2K BT
n $ Nexp{
2K BT
Calculation of number of Frenkel Defects at given temperature: In ionic crystal an ion may be displaced from the regular lattice into an interstitial site or void space. If it is so, then a vacancy and an interstitial defect will be formed. A Frenkel imperfection in silver halides and calcium fluoride are of the Frenkel type. Frenkel and Schottky defects together are called Intrinsic defects.
Let us consider Ei is the energy required to move an atom from lattice site inside the crystal to a lattice site on the surface. The amount of energy required to produce n number of isolated vacancies
U ! nEi
The total number of ways to move n numbers of ions out of N number ionic molecules in a crystal on to the surface will be,
N! Ni! p ![ ][ ] (N n)!n! (N i n)!n! entropy ! K Blogp N! Ni! S ! K Blog{[ ][ ]} (N n)!n! (N i n)!n! freeenergy ! U TS N! Ni! F ! nE i K BTlog{[ ][ ]} (N n)!n! (N i n)!n!
N! Ni! log{[ ][ ]} ( N n)!n! ( N i n)!n! ! N log N N i log N i( N n) log( N n) ( N i n) log( N i n) 2n log n F ! nEi K BT {N log N N i log N i( N n) log( N n) ( N i n) log( N i n) 2n log n}
At equilibrium, the free energy is constant and minimum with respect to n, hence
Line defects
Line defects are one dimensional imperfections in the geometrical sense. There are in general two types of dislocations: 1. Edge dislocation 2. Screw dislocation
Edge dislocation
In a perfect crystal, atoms are arranged in both vertical and horizontal planes parallel to the side faces. If one of these vertical planes does not extended to full length but ends in between, within the crystal as shown in figure, it is called edge dislocation. Edge dislocations are symbolically represented by or or depending on whether the incomplete plane starts from the top or from the bottom of the crystal. These two configurations are referred to as positive and negative edge dislocations.
Perfect Crystal
Perfect crystal
The edge dislocation containing an extra plane of atoms lying above the positive slip plane (or) Burgers plane are conventionally called the positive edge dislocation. If the extra half plane of atoms containing below the slip plane called the negative edge dislocation.
Burgers vector
The magnitude and the direction of the displacement are defined by a vector called the Burgers vector. Consider two crystals one perfect and another with edge dislocation.
Fig 1.
Fig 2.
Perfect crystal
From fig. 1. Starting from the point P, we go up by 6 steps, then move towards right by 5 steps, and move down by 6 steps and finally move towards left by 5 steps to reach the starting point P, the burgers circuit gets closed in a perfect crystal. Where as in fig 2. We end up at Q instead of the starting point P. In order to reach the point P, we have to move an extra step QP. So that the burgers circuit is closed. The magnitude and the direction of the step QP defines the Burgers vector (BV)
BV = QP = b The Burgers vector is perpendicular to the edge dislocation line and it is parallel in Screw dislocation.
Screw dislocation
The second basic type of dislocation is the Screw or Burgers dislocation. In this, the atoms are displaced in two separate planes perpendicular to each other. In a figure the plane ABCD is the slipped area. The upper portion of the crystal has been sheared by an atomic distance to the right relative to the lower portion. No slip has taken place to the right of AD and AD is a dislocation line.
C D
Shear vector
Here, the dislocation is parallel to its Burgers vector or shear vector. The designation screw for this lattice defect is derived from the fact that the lattice planes of the crystal spiral the dislocation line AD.
Surface defects
Surface defects arise from a change in the stacking of atomic planes (or) across a boundary. The change may be one of the orientations (or) of the stacking sequence of the planes. Surface defects are two types. 1. External surface imperfections 2. Internal surface imperfections
Since these surface atoms are not entirely surrounded by others, they posses higher energy than that of internal atoms.
1. Grain boundary
The boundary between two miss oriented crystalline material is called grain boundary. During nucleation or crystallization this may happen. Grain boundaries also known as high angle boundaries.
Poly crystal
Grain boundaries
D =b/
b
b
D
D
b D Magnitude of burgers vector Average vertical distance between dislocations
3. Stacking faults
Stacking faults are planar surface imperfections caused by faults in the stacking sequence of atomic planes (or) layers in crystals. In FCC crystal we have three different stacking layers ABC while in HCP stacking we have only two different layers BC. Hence when FCC crystal grows we have the stacking as .ABCABCABC..
While growing if the plane A indicated by arrow above is missing then we get the sequence .ABCABCBCABC. Thus we find that the stacking in the missing region becomes HCP. This thin region is a surface imperfection and is called a stacking fault.
4.Twin boundary
The atomic arrangement on one side of a twin boundary is a mirror reflection of the arrangement on the other side, such a boundary and the region between the pair of boundaries is called twinned region. Twin boundaries are easily identified under an optional microscope.
Volume defects
Volume defects such as cracks may arise when there is only small electrostatic dissimilarity between the stacking sequences of close packed planes in metals. When clusters of atoms are missing ,a large Vacancy or void is got which is also a volume imperfection. Foreign particle inclusions, large voids or non crystalline regions which have the dimensions of the order of 0.20nm are also called volume imperfection. We can study the volume defects by using interferometric techniques and optical microscopes.