Beruflich Dokumente
Kultur Dokumente
Title of course.
Adsorption
Absorption
Adsorption is ideally suited key tool for purification Applications as well as difficult separations. Different adsorbent materials are used in the application of surface chemistry.
Hydrophilic and polar (e.g.: silica gel and Hydrophobic and non-polar (e.g.: activated
carbon and graphite ) 2.Carbon-based compounds
3.Polymer-based compounds
ACTIVATION OF ADSORBENTS
ACTIVATION is a physical or chemical process by
which adsorbent with following characteristics are produced. rods and mouldings have high abrasion resistance, high thermal stability and small pore diameters which result in large surface capacity for adsorption.
of adsorbents.
Activated Carbon
ACTIVATED CARBON
REACTIONS
+ O2 ---- CO2
H2
+ O2 ----- H2O
H= - 238 KJ
Because of its large, accessible internal surface (and large pore volume), it adsorbs more non-polar and weakly polar organic molecules than other sorbents do. The heat of adsorption, or bond strength, is generally lower on activated carbon than on other sorbents. This is because only nonspecific, van der Waals forces are available as the main forces for adsorption.
ACTIVATED CARBON
Coconut shell
Fertilizer slurry Palm tree cobs Coconut shell Petroleum coke Raffination earth Algerian coal Pine saw dust Almond and peach shells
COCONUT SHELL
Feedstock Bituminous coal Coal Petroleum coke Lignite Peanut hulls Fly ash
Condition N2/400-700C
Phosgene or chlorine gas at 180C Dehydration at 400C , Activation in 500-900C Inert atmosphere /600-800C
150C,sodium bicarbonate Forth flotation, hydrophobic char was separated from hydrophilic ash with the help of methyl isobutyl ketone Fast pyrolysis at 500C with inert nitrogen
H2SO4
Steam
K2CO3
SILICA GEL
SILICA GEL
Many techniques have been used to identify and quantify the different silanol groups. IR spectroscopy of the adsorbed water and hydroxyls the most useful absorption band is the OH stretching frequency. In addition to the surface OH groups, there also exist internal OH groups in the silica structure.
ACTIVATED ALUMINA
The primary structural units of zeolites are the They are potentially strong sorbents due to
tetrahedra of silicon and aluminum giving three dimensional frame work. presence of cavities, channels and cage like frame work.
APPLICATIOS OF ZEOLITES
occuring. Many more zeolite-like, crystalline molecular sieves have been successfully synthesized by using amine additives as templating agents Many alkali metal hydroxides and raw materials containing silica and alumina can be used in lowtemperature synthesis. The steps involve the Na2OAl2O3-SiO2-H2O system. Zeolites do not need any extra activation treatment in view of their special structures.
Polymeric resins and their derivatives have A broad range of synthetic non-ionic polymers The polymeric resins and carbonaceous These are ease in regeneration The sorbent sorbets interactions are
are available for use a sorbents , ionexchanger and chromatographic column packings. been used commercially for adsorption and ion exchange.
stronger on the carbonized resins are suited for achieving high particles or ultra purification.
CARBON NANOTUBES
These are not commercially used
However they each have interesting and unique adsorption properties and are subjects of active research . Carbon Nanotubes in particular hold tremendous potential for applications because of their unique electrical conductivities , high strength and high stiffness. A single-wall nano-tubes (SWNT) is a seamless cylinder wrapped by a graphite sheet. Carbon Nanotubes have high cylindrical pores are adsorbate molecule interacts with the carbon atoms on the surrounding walls. Carbon nanotubes can adsorb molecules much more strongly than activated carbon.