Beruflich Dokumente
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SC-EPC
Felicitas Berger
Lecture 6: Electrolysis-Part 2
In an experiment 0,03 l Hydrogen were produced
by applying a voltage of 1,95 V
with a current of 1 A over
a time of 300 s. Calculate the energy efficiency !
h= Eproduct/Eelectrical x 100 (%)
h= 0.64 m3 x J / V x A x s x m3
h= 0.64 = 64 %
1 4. Electrolysis
4. Electrolysis
4. Electrolysis
4.3 Chloralkaline process
4. Electrolysis
➊ Diaphragma-Verfahren
Membran
Titan + Titan Titan
Na Na− +
_ H 2O H 2O Cl
_
_ ! Na
Verarmung an Cl durch ! Ausnutzung der hohen Cl _ (
_ _ H 2O _
e e _ e e e
Anoden-Reaktione
Überspannung von HAnolyt
2 an Hg
! M
Hg
Katholyt Anolyt Katholyt
Katholyt Anolyt
g/l NaOH
no new facilitiesmöglich
NaOH-Konzentrationen in Ger.
Skizze einer Einfachstanlage clean but expensive
50%T market
= 90 C; U share
! inVUS
= 3.5 - 4.2 o forbidden in Japan s. 1987 50% market share in US
US < 10% market share
Europe 40%
- Asbestos! - mercury!
➊ Diaphragma-Verfahren: Prinzip
4 4. Electrolysis
4. Electrolysis H2 Cl 2
4.3 Chloralkaline process NaCl−Lsg. Betrieb
K + A ! Sa
Diaphragma
+
Eisen Na Na Titan
_ H 2O H 2O Cl
_
_ ! V
e e
Katholyt Anolyt A
NaOH− Lsg. ! D
NaCl−Lsg.
D
! V
Diaphragm process: The Partition aus
! Diaphragma is made out of asbestos covered
Weiss-Asbest:
polymers. The Cathode +consists of iron, the anode of tinanium, the ! R
Na - und H2 O-durchlässig
electrolyte, konzentrated sodium chloride solution is filled to the anode A
container. ! A früher Graphit, heute Ti-Blech
(C
(O- 2 -Abscheidung gehemmt)
Cathode:2H2O + 2e 2H2 + 2OH- Anode:2Cl- Cl2 + 2e- ab
! K Eisen oder Stahl
!
➊ Diaphragma-Verfahren: Prinzip
5 4. Electrolysis
4. Electrolysis H2 Cl 2
4.3 Chloralkaline process NaCl−Lsg. Betrieb
K + A ! Sa
Diaphragma
+
Eisen Na Na Titan
_ H 2O H 2O Cl
_
_ ! V
e e
Katholyt Anolyt A
NaOH− Lsg. ! D
NaCl−Lsg.
D
! V
Unwanted side reactions aus Weiss-Asbest: Cl2 +
at the anode:
! Diaphragma Anode:2Cl- 2e-
+
Na - und H2½O-durchl ässig
! R
2 OH- O2 + H2O + 2e-
A
! A früher Graphit, heute Ti-Blech
Cl2 + 2 OH- ClO- + Cl- + H2O (C
(O2 -Abscheidung gehemmt)
ab
6ClO- + 3H2O 2 ClO3- + 4 Cl- + 6 H+ + 1,5 O2 + 6 e-
! K Eisen oder Stahl
!
6 4. Electrolysis
H2 Cl 2
4. Electrolysis
H 2O NaCl−Lsg.
4.3 Chloralkaline process
Graphit K A
_
+
Na Cl Titan
Na Na
+
_
_ e
e
Hg
Katholyt Anolyt
Graphit K A
_
+
Na Cl Titan
Na Na
+
_
_ e
e
Hg
Katholyt Anolyt
Almost no side reaction are observed, because OH- cannot enter the
anolyte. The sodium-amalgam is rinsed with water in a seperate
container. Pure sodium hydroxide is formed.
Overall: 2 NaCl + xHg Cl2 + 2NaHgx
4. Electrolysis
4.3 Chloralkaline process
9 4. Electrolysis
4. Electrolysis H2 Cl 2
4.3 Chloralkaline process NaOH−Lsg. NaCl−Lsg.
K + + A
Nickel Na Na Titan
Membran
_
_ H 2O Cl _
e e
Katholyt Anolyt
4. Electrolysis
4.3 Chloralkaline process
A Ti mit TiO2 /RuO2 -Deckschicht
K Ni Purification steps needed for the Kathoden− H2 Cl 2
Kanal Anoden−
verdünnte
Umlauf) Sole
Natronlauge
Solesättigung
Rohsole
elektr.
Kontakte
H2
Fällung Fällmittel Cl 2
Cl2 -Blasen, Ausleitung gelöst in NaCl
Entchloren
Filtration Rückstand
Salzsäure
Kathodenhalbraum
H
ohne Einbauten
Chlorat− Feinreinigung
zersetzung
Salzsäure
trom in Reihe durch Module Anolyt
Elektrolyse
Wasser
Leitblech
Vol.-%) H2 Cl 2 NaOH
Kompression Kühlen
ch
ndlich Verflüssigung Lagern
NaOH− NaCl−
Zuleitung Zuleitung
h
Verdampfen
11
➌ Membran-Verfahren 4. Electrolysis
4. Electrolysis
4.3 Chloralkaline process
➋ Membran-Verfahren (Foto)
4. Electrolysis
4.4 Production of metals
Gold, silver, copper, lead, tin, nickel, cobald, chrome and zinc are
produced by electrolysis.
13 4. Electrolysis
4. Electrolysis
4.4 Production of metals
4. Electrolysis
4.5 Electroplating
Zinc, nickel, silver and other metals are also used as material for
electroplating of a variety of metals like copper, steel, iron and others.
The surface of the carrier metal is altered by that process and proprties
like hardness, luster or corrosion resistance can be changed.
15 4. Electrolysis
4. Electrolysis
4.5 Electroplating
16 4. Electrolysis
4. Electrolysis
4.5 Electroplating
m = M x Q / z x F or m = M x I x t / z x F
4. Electrolysis
4.5 Electroplating
r x Axs=MxIxt/zxF
s=MxIxt/r x A xF
s=
58,6934 g/mol x 50 A x 7200 s / 8910 kg/m3 x 0,5 m2 x 2 x 96485 As/mol
s = 24,5 µm
18 4. Electrolysis
4. Electrolysis
4.5 Electroplating
4. Electrolysis
4.6 Anodization
Anodization is a process,
used to thicken th
eprotective oxide layer,
found on many metals,
like aluminium or
titanium.
20 4. Electrolysis
4. Electrolysis
4.6 Anodizing
The metal that should be anodized, forms the anode. Oxygen is formed
and reacts with the metal. At the cathode Hydrogen is formed.
4. Electrolysis
4.7 Fused salt electrolysis
Anode: O2- + 4 e- ½ O2