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Densitas

Volume Air = Volume Piknometer


Massa air (g) 𝜌 air (g/mL)
(mL)
7.1828 0.99534 7.216428557

9.7902 0.994035 9.848948981


9.5902 9.661696555
0.9926 \

Massa gliserin (g) Volume Piknometer (mL) 𝜌 gliserin (g/mL)


9.743 7.216428557 1.35011383
9.7251 9.849 0.987420043
9.7407 9.661696555 1.008176974

Massa gliserin (g) Volume Piknometer (mL) 𝜌 gliserin (g/mL)


8.2704 7.216428557 1.14605167
9.6962 9.849 0.984485735
9.574 9.661696555 0.990923276

Massa gliserin (g) Volume Piknometer (mL) 𝜌 gliserin (g/mL)


7.3051 7.216428557 1.012287441
9.5507 9.849 0.969712661
9.6292 9.661696555 0.996636558
Grafik Densitas

µ0
T (℃ ) 𝜌 air (g/mL) T (℃ )
(g/m.s)
31 0.99534 0.000796 31
35 0.994035 0.00072 35
39 0.9926 0.000653 39

Viskositas

Air gliserol 3% gliserol 1.5% gliserol 0,75%


T(◦C) µ0 t 0(s) ρ0 t (s) ρ µ t (s) ρ µ t (s) ρ µ
31 0.000796 6.41 0.99534 6.34 1.35011383 0.0010679 6.37 1.14605167 0.000910809 6.4 1.012287441 0.00080829
35 0.00072 6.53 0.994035 5.94 0.987420043 0.0006506 6.18 0.984485735 0.000674863 6.22 0.969712661 0.000669038
39 0.000653 5.44 0.9926 5.84 1.00817697 0.0007120 5.85 0.990923276 0.000701029 5.84 0.996636558 0.000703865
Viskositas Instrik

T = 31◦C
Konsentrasi/C (M) μ gliserin (g/cm.s) μair (g/cm.s) μs (g/cm.s) μs/C Konsentrasi/C (M) μs/C
0.012 0.0010679 0.000796 0.341582915 28.46524288 0.012 28.46524
0.006 0.000910809 0.000796 0.144232412 24.03873534 0.006 24.03874
0.003 0.00080829 0.000796 0.015439698 5.146566164 0.003 5.146566

T = 35◦C
Konsentrasi/C (M) μ gliserin (g/cm.s) μair (g/cm.s) μs (g/cm.s) μs/C Konsentrasi/C (M) μs/C
0.012 0.0006506000000 0.00072 -0.096388889 -8.032407407 0.012 -8.03241
0.006 0.000674863 0.00072 -0.062690278 -10.44837963 0.006 -10.4484
0.003 0.000669038 0.00072 -0.070780556 -23.59351852 0.003 -23.5935

T = 39◦C
Konsentrasi/C (M) μ gliserin (g/cm.s) μair (g/cm.s) μs (g/cm.s) μs/C Konsentrasi/C (M) μs/C
0.012 0.0007120000000 0.000653 0.090352221 7.52935171 0.012 7.529352
0.006 0.000701029 0.000653 0.073551302 12.25855028 0.006 12.25855
0.003 0.000704865 0.000653 0.079425727 26.47524247 0.003 26.47524

Berat Molekul

T (℃ ) y = mx +c [μ] ln BM BM (amu)
31 y = 2345.2x +2.75 2.75 12.53788698 278698.8195
35 y = -1539.2x+24.857 24.857 15.43464815 5048734.373
39 y =2006.7x+29.642 29.642 15.66629667 6364820.992
Penentuan Nilai A dan E

5.1 Metode Perbandingan


a. Konsentreasi Gliserin 3%
T (℃ ) T (K) 1/T 𝜇(kg/m.s) ln 𝜇 1/T ln 𝜇
31 304 0.003289474 0.001068 -6.841967538 0.003267974 -6.84197
35 308 0.003246753 0.0006503 -7.338076763 0.003236246 -7.33808
39 312 0.003205128 0.000706 -7.25589532 0.003205128 -7.2559

b. Konsentreasi Gliserin 1.5%


T (℃ ) T (K) 1/T 𝜇(kg/m.s) ln 𝜇 1/T ln 𝜇
31 304 0.003289474 0.000911 -7.000967661 0.003267974 -7.00097
35 308 0.003246753 0.0006745 -7.301538882 0.003236246 -7.30154
39 312 0.003205128 0.0007011 -7.262860028 0.003205128 -7.26286

c. Konsentreasi Gliserin 0.75%


T (℃ ) T (K) 1/T 𝜇(kg/m.s) ln 𝜇 1/T ln 𝜇
31 304 0.003289474 0.000808 -7.120948499 0.003267974 -7.12095
35 308 0.003246753 0.000669 -7.309726498 0.003236246 -7.30973
39 312 0.003205128 0.000704 -7.258732202 0.003205128 -7.25873

Perhitungan Nilai A dan E (Metode


Grafis)
Konsentrasi Gliserin (mL) y = ax + b a b A E
3.0% y= 4731.8x-22.516 4.73E+03 -22.516 1.67E-10 39340.1852
1.50% y= 3012.4x-16.973 3.01E+03 -16.973 4.25E-08 25045.0936
0.75% y=1578.3x-12.357 1578.3 -12.357 4.3E-06 13121.9862
5.2 Metode Least Square
y = ax +b
x = 1/T 3% 1.50% 0.75%
a= 1645.78 3122.232269 4936.930806
b= -12.5738 -17.32671331 -23.17611196
Volume Molar Parsial

Kalibrasi
Piknometer
Massa
piknometer
kosong (g) = 14.528
Massa piknometer 𝜌 IPA 𝜌 etanol Volume piknometer = Mr IPA Mr Etanol
T (℃ ) Massa air (g)
+ air (g) (g/mL) (g/mL) Volume air (g/mol) (g/mol)
27 23.769 9.241 0.786 0.7893 9.27 60 46

Volume Volume Massa Massa Volume Volume


ρ campuran Mol IPA Mol Etanol Mol Total
Etanol IPA Piknometer + Campuran X IPA X Etanol Campuran Molar
(g/mL) (mol) (mol) (mol)
(mL) (mL) Campuran (g) (g) (mL) (mL/mol)
1 14 22.03 7.502 0.809277238 0.1834 0.017158696 0.200558696 0.914445516 0.085554484 14.57263276 72.66018916
2 13 21.994 7.466 0.805393743 0.1703 0.034317391 0.204617391 0.832285071 0.167714929 14.64699732 71.5823676
3 12 21.981 7.453 0.80399137 0.1572 0.051476087 0.208676087 0.753320624 0.246679376 14.67665007 70.33220858
4 11 22.001 7.473 0.806148867 0.1441 0.068634783 0.212734783 0.677369249 0.322630751 14.64146447 68.82496737
5 10 22.027 7.499 0.808953614 0.131 0.085793478 0.216793478 0.60426172 0.39573828 14.59477997 67.32112095
6 9 22.015 7.487 0.807659115 0.1179 0.102952174 0.220852174 0.533841247 0.466158753 14.62225805 66.20835008
7 8 22.032 7.504 0.809492988 0.1048 0.12011087 0.22491087 0.465962362 0.534037638 14.59320856 64.88440769
8 7 22.038 7.51 0.810140237 0.0917 0.137269565 0.228969565 0.400489908 0.599510092 14.5856229 63.7011425
9 6 22.053 7.525 0.81175836 0.0786 0.154428261 0.233028261 0.337298144 0.662701856 14.56061382 62.48432601
10 5 22.074 7.546 0.814023732 0.0655 0.171586957 0.237086957 0.276269943 0.723730057 14.52414657 61.26084193
11 4 22.136 7.608 0.820711974 0.0524 0.188745652 0.241145652 0.21729606 0.78270394 14.4098056 59.75561023
12 3 22.118 7.59 0.818770227 0.0393 0.205904348 0.245204348 0.160274483 0.839725517 14.44800949 58.92232179
13 2 22.139 7.611 0.821035599 0.0262 0.223063043 0.249263043 0.105109846 0.894890154 14.41216437 57.81909812
14 1 22.135 7.607 0.820604099 0.0131 0.240221739 0.253321739 0.051712893 0.948287107 14.42376416 56.93851706
y = -100.95x6 + 424.62x5 - 666.2x4 + 501.73x3 - 192.15x2 + 16.982x + 72.317
Vm terhadap X etanol
dVm / dXetanol Vm etanol Vm IPA
23.03081139 93.72061137 70.68979999
48.7815904 112.182557 63.40096661
38.46371788 99.30772053 60.84400265
35.14210392 92.62914793 57.487044
43.49919487 93.60601925 50.10682438
42.02541163 88.64324825 46.61783662
43.5545693 85.17919768 41.62462838
42.21610477 80.6082664 38.39216163
38.90569077 75.60714331 36.70145254
41.72165837 72.78728212 31.06562375
32.25084776 66.76359236 34.5127446
31.69953228 64.00294792 32.30341565
34.4215149 61.43713823 27.01562333
41.1053398 59.0641931 17.95885329
y = -100.95x6 + 181.1x5 - 57.404x4 - 64.056x3 + 47.736x2 + 9.5496x +
56.345
Vm terhadap X IPA
dVm / dXIPA Vm etanol Vm IPA
-22.86916715 74.61674895 28.14579766
-48.6791074 79.74658065 39.63249588
-38.38813507 79.80176979 43.90889208
-35.07579066 80.14149604 39.41346842
-43.42018623 84.50415078 41.97048535
-41.95307227 85.76514192 43.00017395
-43.47392834 88.1011217 45.25530056
-42.12594995 88.95607465 48.15986847
-38.80565713 88.20090699 48.44269984
-41.6297166 91.3895191 52.38382406
-32.13168167 84.90520408 52.89524351
-31.57151922 85.4337321 53.42727241
-34.2852417 88.50062336 53.51365082
-40.96140826 95.7816924 56.93851706
Grafik Volume Parsial

Volume Molar (mL/mol) X Etanol Volume Molar (mL/mol) X IPA Volume Molar (mL/mol)
72.66018916 0.085554484 72.66018916 0.914445516 72.66018916
71.5823676 0.167714929 71.5823676 0.832285071 71.5823676
70.33220858 0.246679376 70.33220858 0.753320624 70.33220858
68.82496737 0.322630751 68.82496737 0.677369249 68.82496737
67.32112095 0.39573828 67.32112095 0.60426172 67.32112095
66.20835008 0.466158753 66.20835008 0.533841247 66.20835008
64.88440769 0.534037638 64.88440769 0.465962362 64.88440769
63.7011425 0.599510092 63.7011425 0.400489908 63.7011425
62.48432601 0.662701856 62.48432601 0.337298144 62.48432601
61.26084193 0.723730057 61.26084193 0.276269943 61.26084193
59.75561023 0.78270394 59.75561023 0.21729606 59.75561023
58.92232179 0.839725517 58.92232179 0.160274483 58.92232179
57.81909812 0.894890154 57.81909812 0.105109846 57.81909812
56.93851706 0.948287107 56.93851706 0.051712893 56.93851706

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