ΔH,(kcal/mol) ΔS,(kcal/mol) T inicial, K T fusion, K

Al(s) -266 -4.60E-02 273.15 1273

Al(l) -266 -4.60E-02 1273 2000

Temperatura (°K) Temperatura (°C) ΔG(f) ΔG(e)

273.15 0 -253.44 Dia
293.15 20 -252.52 0.00
313.15 40 -251.60
-50.00
333.15 60 -250.68
353.15 80 -249.76 -100.00
373.15 100 -248.84

ΔG,(kcal
-150.00
393.15 120 -247.92
413.15 140 -247.00 -200.00 0
433.15 160 -246.08 3 /4 Al(s)+ 2
453.15 180 -245.16 -250.00 A l 2O 3
473.15 200 -244.24 -300.00
493.15 220 -243.32 0 200 400

513.15 240 -242.40

533.15 260 -241.48
553.15 280 -240.56
573.15 300 -239.64
593.15 320 -238.72
613.15 340 -237.80
633.15 360 -236.88
653.15 380 -235.96
673.15 400 -235.04
693.15 420 -234.12
713.15 440 -233.20
733.15 460 -232.28
753.15 480 -231.36
773.15 500 -230.44
793.15 520 -229.52
813.15 540 -228.60
833.15 560 -227.68
853.15 580 -226.76
873.15 600 -225.84
893.15 620 -224.92
913.15 640 -224.00
 933.15 660 -223.08
953.15 680 -222.16
973.15 700 -221.24
993.15 720 -220.32
1013.15 740 -219.40
1033.15 760 -218.48
1053.15 780 -217.56
1073.15 800 -216.64
1093.15 820 -215.72
1113.15 840 -214.80
1133.15 860 -213.88
1153.15 880 -212.96
1173.15 900 -212.04
1193.15 920 -211.12
1213.15 940 -210.20
1233.15 960 -209.28
1253.15 980 -208.36
1273.15 1000 -207.44
1293.15 1020 -206.52
1313.15 1040 -205.60
1333.15 1060 -204.68
1353.15 1080 -203.76
1373.15 1100 -202.84
1393.15 1120 -201.92
1413.15 1140 -201.00
1433.15 1160 -200.08
1453.15 1180 -199.16
1473.15 1200 -198.24
1493.15 1220 -197.32
1513.15 1240 -196.40
1533.15 1260 -195.48
1553.15 1280 -194.56
1573.15 1300 -193.64
1593.15 1320 -192.72
1613.15 1340 -191.80
1633.15 1360 -190.88
1653.15 1380 -189.96
1673.15 1400 -189.04
1693.15 1420 -188.12
1713.15 1440 -187.20
1733.15 1460 -186.28
1753.15 1480 -185.36
1773.15 1500 -184.44
1793.15 1520 -183.52
1813.15 1540 -182.60
1833.15 1560 -181.68
1853.15 1580 -180.76
1873.15 1600 -179.84
1893.15 1620 -178.92
1913.15 1640 -178.00
1933.15 1660 -177.08
1953.15 1680 -176.16
1973.15 1700 -175.24
1993.15 1720 -174.32
2013.15 1740 -173.40
 Diagrama de Ellingham
0.00

-50.00

-100.00
ΔG,(kcal

-150.00
= 2 / 3 A l2 O 3
3 /4 A l( l) +0 2
-200.00 0 =2 /3
3 /4 Al(s)+ 2
-250.00 A l 2O 3
-300.00
0 200 400 600 800 1000 1200 1400 1600 1800 2000
Temperatura °C
ΔH,(kcal) ΔS,(kcal) T(i),K T(f),K
-303.1 -69.2 273.15 923.15
-260.79 -22.5 923.15 1367.15
-463.89 -170.11 1640.3 2273.15

0.0000
Temp. (K) Temp. (°C) ΔG(Mgs) ΔG(Mgl) ΔG(Mgg)
273.15 0 -284.1980 -50.0000
293.15 20 -282.8140
313.15 40 -281.4300 -100.0000
333.15 60 -280.0460
353.15 80 -278.6620

ΔG(kcal)
-150.0000
373.15 100 -277.2780
393.15 120 -275.8940
-200.0000
413.15 140 -274.5100
433.15 160 -273.1260
453.15 180 -271.7420 -250.0000 +
7 Mg (s
)
473.15 200 -270.3580
493.15 220 -268.9740 -300.0000
0 200
513.15 240 -267.5900
533.15 260 -266.2060
553.15 280 -264.8220
573.15 300 -263.4380
593.15 320 -262.0540
613.15 340 -260.6700
633.15 360 -259.2860
653.15 380 -257.9020
673.15 400 -256.5180
693.15 420 -255.1340
713.15 440 -253.7500
733.15 460 -252.3660
753.15 480 -250.9820
773.15 500 -249.5980
793.15 520 -248.2140
813.15 540 -246.8300
833.15 560 -245.4460
853.15 580 -244.0620
873.15 600 -242.6780
893.15 620 -241.2940
913.15 640 -239.9100
923.15 650 -239.2180
943.15 670 -239.569125
963.15 690 -239.119125
983.15 710 -238.669125
1003.15 730 -238.219125
1023.15 750 -237.769125
1043.15 770 -237.319125
1063.15 790 -236.869125
1083.15 810 -236.419125
1103.15 830 -235.969125
1123.15 850 -235.519125
1143.15 870 -235.069125
1163.15 890 -234.619125
1183.15 910 -234.169125
1203.15 930 -233.719125
1223.15 950 -233.269125
1243.15 970 -232.819125
1263.15 990 -232.369125
1283.15 1010 -231.919125
1303.15 1030 -231.469125
1323.15 1050 -231.019125
1343.15 1070 -230.569125
1367.15 1094 -230.029125
1387.15 1114 -227.921913
1407.15 1134 -224.519713
1427.15 1154 -221.117513
1447.15 1174 -217.715313
1467.15 1194 -214.313113
1487.15 1214 -210.910913
1507.15 1234 -207.508713
1527.15 1254 -204.106513
1547.15 1274 -200.704313
1567.15 1294 -197.302113
1587.15 1314 -193.899913
1607.15 1334 -190.497713
1627.15 1354 -187.095513
1647.15 1374 -183.693314
1667.15 1394 -180.291113
1687.15 1414 -176.888913
1707.15 1434 -173.486713
1727.15 1454 -170.084513
1747.15 1474 -166.682313
1767.15 1494 -163.280113
1787.15 1514 -159.877913
1807.15 1534 -156.475713
1827.15 1554 -153.073513
1847.15 1574 -149.671313
1867.15 1594 -146.269113
1887.15 1614 -142.866913
1907.15 1634 -139.464713
1927.15 1654 -136.062513
1947.15 1674 -132.660313
1967.15 1694 -129.258113
1987.15 1714 -125.855913
2007.15 1734 -122.453713
 0.0000

-50.0000

-100.0000

gO
ΔG(kcal)

-150.0000 =M
+O
2

g ( g)
-200.0000 9M
8Mg(l)+O2=MgO
O
-250.0000 =Mg
+O 2
7 Mg (s
)

-300.0000
0 200 400 600 800 1000 1200 1400 1600 1800 2000
Temperatura (°C)
 ΔH,Kcal ΔS,Cal T(i),K
-94.06 -0.75 273.15
-52.01 42.41 273.15
-135 -41.88 273.15

T(°K) T(°C) ΔG(kcal) ΔG(Kcal)2 ΔG(Kcal)3

273.15 0 -93.8551375 -63.5942915 -123.560478 Chart Titl
323.15 50 -93.8176375 -65.7147915 -121.466478 0
373.15 100 -93.7801375 -67.8352915 -119.372478 0 500 1000
-20
423.15 150 -93.7426375 -69.9557915 -117.278478
473.15 200 -93.7051375 -72.0762915 -115.184478 -40
523.15 250 -93.6676375 -74.1967915 -113.090478
-60
573.15 300 -93.6301375 -76.3172915 -110.996478
623.15 350 -93.5926375 -78.4377915 -108.902478 -80
673.15 400 -93.5551375 -80.5582915 -106.808478
-100
723.15 450 -93.5176375 -82.6787915 -104.714478
773.15 500 -93.4801375 -84.7992915 -102.620478 -120
823.15 550 -93.4426375 -86.9197915 -100.526478 -140
873.15 600 -93.4051375 -89.0402915 -98.432478
923.15 650 -93.3676375 -91.1607915 -96.338478 -160
973.15 700 -93.3301375 -93.2812915 -94.244478
1023.15 750 -93.2926375 -95.4017915 -92.150478
1073.15 800 -93.2551375 -97.5222915 -90.056478
1123.15 850 -93.2176375 -99.6427915 -87.962478
1173.15 900 -93.1801375 -101.763292 -85.868478
1223.15 950 -93.1426375 -103.883792 -83.774478
1273.15 1000 -93.1051375 -106.004292 -81.680478
1323.15 1050 -93.0676375 -108.124791 -79.586478
1373.15 1100 -93.0301375 -110.245292 -77.492478
1423.15 1150 -92.9926375 -112.365792 -75.398478
1473.15 1200 -92.9551375 -114.486292 -73.304478
1523.15 1250 -92.9176375 -116.606791 -71.210478
1573.15 1300 -92.8801375 -118.727292 -69.116478
1623.15 1350 -92.8426375 -120.847792 -67.022478
1673.15 1400 -92.8051375 -122.968291 -64.928478
1723.15 1450 -92.7676375 -125.088791 -62.834478
1773.15 1500 -92.7301375 -127.209292 -60.740478
1823.15 1550 -92.6926375 -129.329792 -58.646478
1873.15 1600 -92.6551375 -131.450292 -56.552478
1923.15 1650 -92.6176375 -133.570791 -54.458478
1973.15 1700 -92.5801375 -135.691292 -52.364478
2023.15 1750 -92.5426375 -137.811792 -50.270478
2073.15 1800 -92.5051375 -139.932292 -48.176478
2123.15 1850 -92.4676375 -142.052791 -46.082478
2173.15 1900 -92.4301375 -144.173292 -43.988478
2223.15 1950 -92.3926375 -146.293792 -41.894478
2273.15 2000 -92.3551375 -148.414292 -39.800478
 T(f),K ΔS,Kcal
2273.15 -0.00075
2273.15 0.04241
2273.15 -0.04188

Chart Title
500 1000 1500 2000 2500

2C0 2
C02

2C0