Taratura

Dati dello standard (ac. Benzoico)

DcombH° = -3228.24 kJ mol-1
DcombCp° = 117.74 J K-1 mol-1
Dn(gas) = -0.5
PM = 122.12 nome file
TURNO6
Db(gas) = 0.059965 l mol-1 uscita:

dati taratura
gac. benzoico lfilo lfilo inc. lfilo comb.
0.5182 20 9.9 10.1
P= 9 bar
Tcomb = 22.7 °C DTcorr = 0.8235 Volt

DcombU = -3227.23 kJ mol-1 qcomb = 13757.72 J

C' = ì J Volt-1

Taratura Esperienza
t (s) V (Volt) V (Volt) V (Volt)
0 0.001945 0.001558 0.002382
5 0.00186 0.001679 0.002683
10 0.001748 0.001832 0.002865
15 0.001647 0.00195 0.003136
20 0.001686 0.002024 0.003442
25 0.001637 0.002228 0.00359
30 0.001534 0.002356 0.003819
35 0.00144 0.002569 0.004154
40 0.001356 0.002645 0.004377
45 0.001191 0.002878 0.004569
50 0.001179 0.002992 0.004891
55 0.001166 0.003097 0.005108
60 0.001046 0.003255 0.005378
65 0.001104 0.003418 0.005554
70 0.000982 0.003583 0.005815
75 0.000951 0.003644 0.006025
80 0.000936 0.003802 0.006192
1
85 0.000933 0.003819 0.006489
90 0.000917 0.00399 0.006707
95 0.000779 0.004106 0.00687
T / volt

100 0.000777 0.004211 0.007113 0.8

105 0.00069 0.004333 0.0074
110 0.000826 0.004456 0.007559
115 0.000804 0.004578 0.007751 0.6

0.4

0.2
 T / volt
0.8

0.6
120 0.0008 0.004622 0.007979
125 0.0007 0.004887 0.008141
130 0.000684 0.004879 0.008322 0.4
135 0.00064 0.00506 0.008567
140 0.001413 0.005615 0.008858
145 0.006147 0.009205 0.008929 0.2
150 0.01645 0.019227 0.009212
155 0.033588 0.036797 0.009447
160 0.059315 0.063748 0.011188 0
165 0.095525 0.102691 0.017539 0 200
170 0.140516 0.147451 0.030773
175 0.188413 0.195549 0.053053
180 0.23909 0.242556 0.085999
185 0.288467 0.286359 0.128994
190 0.332955 0.326172 0.17519
195 0.376516 0.362815 0.221715
200 0.415256 0.395139 0.265847 0.8
205 0.450761 0.42353 0.306232
210 0.48174 0.448979 0.343213

T / volt
215 0.508794 0.471762 0.376896
0.6
220 0.532739 0.491734 0.406302
225 0.554366 0.509711 0.432784
230 0.572928 0.526329 0.45654
235 0.589833 0.540773 0.477851 0.4
240 0.604713 0.553783 0.496741
245 0.618338 0.565468 0.51352
250 0.630515 0.576004 0.528486
255 0.641595 0.585688 0.542008 0.2
260 0.651716 0.594415 0.554252
265 0.660791 0.60231 0.565469
270 0.669382 0.609801 0.575635
275 0.677215 0.616623 0.584969 0
280 0.684299 0.622947 0.593405 0 200
285 0.691005 0.628971 0.600983
290 0.697234 0.634691 0.608363
295 0.702797 0.640004 0.614901
300 0.70788 0.644941 0.621012
305 0.712904 0.649613 0.626921
310 0.717539 0.653986 0.632449
315 0.722078 0.658134 0.637549 0.8
320 0.726381 0.662135 0.642384
325 0.73047 0.665858 0.646973
T / volt

330 0.734134 0.66925 0.651267

335 0.73772 0.672649 0.655356
0.6
340 0.741143 0.675724 0.659256
345 0.744298 0.678779 0.663043
350 0.747158 0.681797 0.666573
0.4
355 0.750071 0.684583 0.669884
360 0.752984 0.687255 0.672941

0.2

0
 T
0.4

365 0.75574 0.68967 0.675977

370 0.758073 0.692099 0.67894 0.2
375 0.760677 0.694401 0.681688
380 0.763017 0.696596 0.684352
385 0.765068 0.698867 0.686963
390 0.767167 0.700925 0.689324 0
395 0.76928 0.70293 0.691625 0 200
400 0.771417 0.704787 0.693924
405 0.773112 0.706482 0.696109
410 0.775115 0.708354 0.698169
415 0.776839 0.709953 0.700168
420 0.778547 0.711568 0.702188
425 0.7801 0.71315 0.704069
430 0.781826 0.714654 0.705969
435 0.783396 0.716245 0.707694
440 0.784823 0.717688 0.709412
445 0.786167 0.719062 0.710875
450 0.787444 0.720235 0.712507
455 0.78887 0.721598 0.713943
460 0.790249 0.722789 0.71539
465 0.791562 0.723939 0.716809
470 0.792783 0.725144 0.71825
475 0.793978 0.726221 0.719632
480 0.795015 0.727195 0.720953
485 0.79625 0.728248 0.722133
490 0.797243 0.729198 0.723265
495 0.798319 0.730104 0.724464
500 0.799443 0.731123 0.725477
505 0.80025 0.731909 0.726594
510 0.801169 0.732719 0.727672
515 0.802171 0.733622 0.728708
520 0.802931 0.734397 0.729618
525 0.803746 0.735151 0.730718
530 0.804515 0.735895 0.731688
535 0.805325 0.736731 0.73253
540 0.806154 0.737421 0.733409
545 0.806989 0.737995 0.734296
550 0.807648 0.738706 0.735074
555 0.808209 0.73938 0.735974
560 0.808922 0.739929 0.736743
565 0.80962 0.740557 0.737485
570 0.810217 0.741157 0.738196
575 0.810928 0.74163 0.73897
580 0.811536 0.742139 0.739747
585 0.812122 0.742578 0.74038
590 0.81263 0.743089 0.741047
595 0.813148 0.74365 0.741551
600 0.813676 0.744024 0.742174
605 0.814176 0.744576 0.742787
610 0.814709 0.74493 0.743362
615 0.815245 0.745333 0.74394
620 0.815649 0.745676 0.744481
625 0.816162 0.746015 0.745034
630 0.816602 0.746362 0.745561
635 0.816909 0.746819 0.746002
640 0.817402 0.747253 0.746437
645 0.817737 0.747434 0.746905
650 0.818103 0.747765 0.747401
655 0.818507 0.748094 0.747774
660 0.818844 0.748425 0.748214
665 0.819213 0.748672 0.748602
670 0.819535 0.748949 0.749013
675 0.819851 0.749197 0.749471
680 0.820089 0.749455 0.749891
685 0.820407 0.749761 0.750247
690 0.820783 0.749981 0.750627
695 0.820938 0.750305 0.750902
700 0.821164 0.750593 0.751275
705 0.821408 0.750757 0.751575
710 0.821749 0.750879 0.751885
715 0.822103 0.751143 0.752266
720 0.822283 0.751248 0.752649
725 0.822536 0.751408 0.752931
730 0.822732 0.751689 0.753133
735 0.822974 0.751868 0.753539
740 0.823107 0.752007 0.75373
745 0.823249 0.752218 0.754012
750 0.823603 0.752296 0.75426
755 0.823622 0.752444 0.754522
760 0.823892 0.752558 0.754761
765 0.824196 0.752562 0.754963
770 0.824146 0.752771 0.755283
775 0.824303 0.752932 0.755421
780 0.824512 0.753026 0.755684
785 0.824611 0.753041 0.756019
790 0.824679 0.753177 0.756112
795 0.824896 0.753289 0.756338
800 0.82497 0.753478 0.756593
805 0.825064 0.75351 0.756718
810 0.825071 0.753567 0.756917
815 0.825321 0.753536 0.757194
820 0.825453 0.753611 0.757319
825 0.825625 0.753659 0.757423
830 0.825673 0.75371 0.757629
835 0.82583 0.753756 0.757931
840 0.825798 0.753859 0.758076
845 0.825876 0.753867 0.758152
850 0.825907 0.753841 0.758318
 855 0.825977 0.753985 0.75851
860 0.825936 0.754142 0.758511
865 0.826032 0.754055 0.758655
870 0.826188 0.754005 0.758801
875 0.826214 0.754085 0.75894
880 0.826217 0.754119 0.75899
885 0.826249 0.754091 0.759146
890 0.826325 0.754116 0.75931
895 0.826409 0.754222 0.75939
900 0.826424 0.754142 0.759477
905 0.826537 0.75423 0.759611
910 0.826485 0.754262 0.759793
915 0.826534 0.754289 0.7598
920 0.826602 0.754178 0.759825
925 0.826656 0.754251 0.759951
930 0.826628 0.754203 0.760053
935 0.826606 0.754201 0.760178
940 0.826648 0.754123 0.760198
945 0.826724 0.754108 0.760319
950 0.826827 0.754141 0.760438
955 0.826785 0.754092 0.760525
960 0.826727 0.754116 0.760615
965 0.826729 0.754108 0.760642
970 0.82671 0.754074 0.760737
975 0.826731 0.753936 0.760838
980 0.826756 0.753891 0.760818
985 0.826736 0.753912 0.760917
990 0.826845 0.753777 0.760905
995 0.826763 0.753779 0.761024
1000 0.826754 0.753773 0.761041
1005 0.826817 0.753741 0.76115
1010 0.826832 0.753669 0.761184
1015 0.826803 0.753604 0.761218
1020 0.826746 0.753589 0.761298
1025 0.826742 0.753482 0.761446
1030 0.826685 0.753446 0.761542
1035 0.826778 0.753354 0.761498
1040 0.826796 0.753179 0.76153
1045 0.82666 0.753145 0.761549
1050 0.826699 0.753168 0.761595
1055 0.826636 0.753132 0.761707
1060 0.826587 0.753015 0.761724
1065 0.826618 0.752909 0.761849
1070 0.826554 0.752904 0.761825
 Combustione saccarosio

Dati del saccarosio

DcombCp° = 909 J K-1 mol-1
Dn(gas) = 0
PM = 342.3
Db(gas) = 0.13008 l mol-1
TURNO6

dati combustione 1
gsaccarosio lfilo lfilo inc. lfilo comb.
0.75 20 11.3 8.7
P= 9 bar
Tcomb = 22.9 °C DTcorr = 0.7461 Volt

qcomb = #VALUE!

DcombU(T) = DcombH(T) = #VALUE! kJ mol-1 DcombH(298) = #VALUE! kJ mol-1

DcombH°(298) = #VALUE! kJ mol-1

dati combustione 2
gsaccarosio lfilo lfilo inc. lfilo comb.
0.7375 20 9.5 10.5
P= 9 bar
Tcomb = 22.6 °C DTcorr = 0.7319 Volt

qcomb = #VALUE!

DcombU(T) = DcombH(T) = #VALUE! kJ mol-1 DcombH(298) = #VALUE! kJ mol-1

DcombH°(298) = #VALUE! kJ mol-1

DcombH°(298) = #VALUE! kJ mol-1

1 taratura (acido benzoico)

T / volt

0.8

0.6

0.4

0.2
T / volt
0.8

0.6

0.4

0.2

0
0 200 400 600 800 1000 1200
t / sec

0.8 combustione saccarosio 1

T / volt

0.6

0.4

0.2

0
0 200 400 600 800 1000 1200
t / sec

0.8
combustione saccarosio 2
T / volt

0.6

0.4

0.2

0
T
0.4

0.2

0
0 200 400 600 800 1000 1200
t /sec
 Csol. madre = 2 g/100ml 0.50

Acqua 1° soluz. 2° soluz. 3° soluz. 4° soluz. 5° soluz. 0.089097 0.373618

1° 157.74 165.21 172.57 179.02 185.20 190.98 0.004004 0.001398
2° 157.74 165.36 172.21 178.72 184.91 190.40
0.45
0.993977 0.001187
3° 157.70 165.25 172.45 178.93 185.16 190.92 495.1277 3

hrid
4° 157.72 165.42 172.38 178.69 185.03 190.55
f(x) = 0.089097150581082 x + 0.373618349797962
5° 0.40
tmedio 157.73 165.31 172.40 178.84 185.08 190.71
s 0.02 0.08 0.13 0.14 0.11 0.24

0.35
tAcqua = 157.7 sec

mlAcqua mlSol. Madre mltot Cpolimero tmedio hrel hrid 0.30

1° soluz. 15 1 16 0.125 165.3 1.048 0.385
2° soluz. 15 2 17 0.235 172.4 1.093 0.395
3° soluz. 15 3 18 0.333 178.8 1.134 0.402
0.25
4° soluz. 15 4 19 0.421 185.1 1.173 0.412
0.0 0.1 0.2 0.3 0.4 0.5 0.6
5° soluz. 15 5 20 0.500 190.7 1.209 0.418 C (g/100ml)

[h] = 0.374 ± 0.001

a = 0.804 k = 1.30E-04

PM = 20026 ± 93 u.m.a.

PM  
     
 
k  k 
1
1
 PM  1   
PM     
     k  k 
   
 1

PM  
    
 
k  k 
1
1
 PM  1    
PM       
    k  k 
 
0.5 0.6
 Soluzione madre
[TTAB] = 0.007 Fitting 1° tratto in acqua
diluizioni a 500 ml -640.038 71.95143
8.996723 0.311114
n. diluizione ml soln madre [TTAB] [TTAB]^½ g(mN/m) 0.99921 0.404503
acqua 0 0 0 71.90 5061.073 4
1 12.5 0.00018 0.01323 63.35
2 50 0.00070 0.02646 55.63 Fitting 2° tratto in acqua
3 100 0.00140 0.03742 47.51 35.52169 34.17167
4 150 0.00210 0.04583 42.59 24.91874 1.786658
5 200 0.00280 0.05292 38.19 0.403822 0.486475
6 250 0.00350 0.05916 36.75 2.032053 3
7 300 0.00420 0.06481 36.25
8 357 0.00500 0.07070 36.19 cmc in acqua
9 429 0.00601 0.07750 36.75 0.003127
10 500 0.00700 0.08367 37.55
Retta 1° tratto H2O
75 cmcTTAB in acqua
0 71.95143

g / mN m-1
0.059 34.1892 70
65

Retta 2° tratto H2O 60

0.052 36.0188
55
0.09 37.36862
50
Segmento intersezione 45
0.055924 30
0.055924 36.15817 40
35
30
0 0.01 0.02 0.03 0.04 0.05 0.06 0.07 0.08 0.09
[TTAB]1/2
n acqua

5 0.06 0.07 0.08 0.09

/2
24
 Calcolo costanti del densimetro

tacqua = 5.3096
taria = 3.9377 A=
patm(hPa) = 1006.8 B=

racqua(25°) = 0.9970429
raria(25°) = 0.001176798

Acqua - 1,4-Diossano

PMacqua = 18.015
PMdiossano = 88.110

6-Apr 7-Apr
racqua = 0.99704 0.99704
rdiossano = 1.02801 1.02803

Sol. n° gacqua gdiossano xdiossano

1 3.989 1.040 0.05061
2 3.394 1.775 0.09660
3 2.269 2.779 0.20027
4 1.611 3.433 0.30348
5 1.190 3.832 0.39701
6 0.864 4.162 0.49620
7 0.605 4.429 0.59948
8 0.398 4.590 0.70220
 9 0.287 4.776 0.77285
10 0.115 4.890 0.89684
l densimetro

12.73903
15.49049

ossano
0,0

-0,1

-0,2 -- Re
--
-0,3
VE / cm3 mol-1

--

A0
-0,4 A1
r (g cm )
-3
V (cm mol )
E 3 -1 A2
1.01445 -0.236 -0,5
1.02442 -0.407
1.03485 -0.641 -0,6
1.03680 -0.703
1.03622 -0.682 -0,7
1.03487 -0.614
1.03330 -0.517 -0,8
1.03152 -0.383 0,0 0,2
 -0,7

-0,8
0,0 0,2
1.03058 -0.299
1.02910 -0.139
 Acqua - 1,4-Diossano
0
Punti sperimentali
1 Redlich-Kister (User) Fit
VE = x(1-x)[A0 + A1(2x - 1) + A2(2x - 1)2]
2 -- Reduced Chi-Sqr 5,04108E-5
-- Adj. R-Square 0,99873
3 -- Value Standard Error
A0 -2,4463 0,01614
4 A1 1,90981 0,03205
A2 -0,99805 0,07326

8
0,0 0,2 0,4 0,6 0,8 1,0
xdiossano
7

8
0,0 0,2 0,4 0,6 0,8 1,0
xdiossano
1,0
1,0
t(s) a(t) t(s) a(t) t(s) a(t) t(s) a(t) t(s)
0 0.001 327 9.509 658 8.651 988 7.955 1317
8 0.001 337 9.480 668 8.627 998 7.936 1327
17 0.001 347 9.452 678 8.604 1007 7.919 1337
27 0.001 357 9.423 688 8.581 1017 7.900 1347
37 0.001 367 9.395 698 8.558 1027 7.882 1357
48 0.001 377 9.367 708 8.536 1037 7.863 1367
57 0.001 387 9.339 718 8.513 1048 7.843 1377
67 0.001 397 9.312 728 8.491 1057 7.827 1387
77 0.540 407 9.284 738 8.468 1067 7.809 1397
87 8.802 417 9.257 748 8.446 1077 7.791 1407
97 10.233 427 9.230 758 8.424 1087 7.773 1417
107 10.197 437 9.203 768 8.403 1097 7.756 1428
117 10.161 447 9.176 778 8.381 1107 7.736 1437
127 10.128 457 9.149 788 8.360 1117 7.719 1447
137 10.094 467 9.123 798 8.338 1127 7.701 1457
147 10.061 477 9.097 808 8.317 1137 7.686 1467
157 10.027 487 9.070 818 8.296 1147 7.669 1477
167 9.995 497 9.045 828 8.274 1157 7.650 1487
177 9.963 507 9.019 838 8.253 1167 7.633 1498
187 9.932 517 8.993 848 8.231 1177 7.616 1507
197 9.900 528 8.968 858 8.209 1187 7.600 1517
207 9.869 537 8.942 868 8.188 1197 7.583 1527
217 9.838 547 8.917 878 8.167 1207 7.567 1538
227 9.807 558 8.892 889 8.147 1217 7.550 1547
237 9.776 567 8.867 898 8.127 1227 7.534 1558
247 9.745 577 8.843 908 8.107 1237 7.517 1567
257 9.715 588 8.818 918 8.087 1247 7.501 1577
267 9.685 597 8.794 928 8.069 1257 7.485 1588
277 9.656 607 8.770 938 8.050 1267 7.470 1598
287 9.626 618 8.745 948 8.031 1277 7.454 1608
297 9.597 628 8.722 958 8.012 1287 7.438 1618
307 9.567 638 8.698 969 7.991 1297 7.423 1628
317 9.538 648 8.674 978 7.973 1307 7.407 1638

12 Punti sperimentali
Cinetica (User) Fit
-kapp×t
a(t) = aeq + (a0 - aeq)×e

10 -- Reduced Chi-Sqr 1,00041E-6

-- Adj. R-Square 1
-- Value Standard Error
a(t)

alfa0 10,56067 2,23243E-4

8 alfaeq 4,99931 1,97823E-4
 -kapp×t
a(t) = aeq + (a0 - aeq)×e

10 -- Reduced Chi-Sqr 1,00041E-6

-- Adj. R-Square 1
-- Value Standard Error

a(t) alfa0 10,56067 2,23243E-4

8 alfaeq 4,99931 1,97823E-4
kapp 6,40187E-4 7,32867E-8

0 1000 2000 3000 4000 5000

t/s
 Dati sperimentali
a(t) t(s) a(t) t(s) a(t) t(s) a(t) t(s) a(t)
7.392 1648 6.936 1979 6.566 2342 6.240 2745 5.958
7.376 1658 6.924 1989 6.556 2353 6.232 2758 5.951
7.361 1668 6.912 1999 6.546 2364 6.223 2771 5.943
7.346 1678 6.900 2010 6.535 2376 6.214 2784 5.935
7.331 1688 6.887 2021 6.525 2388 6.204 2797 5.927
7.317 1698 6.875 2032 6.514 2400 6.195 2810 5.919
7.302 1708 6.863 2042 6.503 2412 6.186 2823 5.912
7.287 1718 6.852 2052 6.495 2424 6.177 2836 5.904
7.272 1728 6.840 2063 6.484 2436 6.168 2849 5.897
7.258 1738 6.828 2074 6.474 2448 6.159 2862 5.889
7.244 1748 6.816 2085 6.463 2460 6.150 2875 5.882
7.229 1758 6.805 2096 6.453 2472 6.141 2888 5.875
7.215 1768 6.793 2107 6.443 2485 6.132 2901 5.867
7.201 1778 6.782 2118 6.433 2496 6.124 2914 5.860
7.187 1788 6.770 2129 6.423 2508 6.115 2928 5.852
7.173 1798 6.759 2140 6.413 2520 6.107 2941 5.845
7.159 1808 6.748 2151 6.403 2532 6.098 2954 5.838
7.145 1818 6.737 2162 6.393 2545 6.090 2967 5.831
7.132 1828 6.726 2173 6.383 2557 6.081 2980 5.824
7.118 1838 6.715 2184 6.373 2569 6.073 2994 5.817
7.105 1848 6.704 2195 6.363 2581 6.065 3008 5.810
7.091 1858 6.693 2206 6.354 2593 6.056 3021 5.803
7.078 1868 6.682 2217 6.344 2605 6.048 3035 5.796
7.065 1878 6.671 2228 6.334 2617 6.040 3049 5.789
7.052 1888 6.660 2239 6.325 2630 6.032 3063 5.781
7.038 1898 6.650 2250 6.317 2642 6.024 3077 5.775
7.025 1909 6.639 2261 6.307 2654 6.016 3091 5.768
7.013 1919 6.628 2272 6.297 2667 6.008 3105 5.761
7.000 1929 6.617 2284 6.287 2680 5.999 3119 5.754
6.987 1939 6.607 2295 6.278 2693 5.991 3133 5.747
6.974 1949 6.597 2307 6.269 2706 5.983 3147 5.741
6.961 1959 6.587 2318 6.260 2719 5.975 3161 5.734
6.949 1969 6.576 2330 6.250 2732 5.966 3175 5.727

T/°C =

mGlucosio/g = 2.005 macqua/g = 19.943 %p/p = 10.0537

a° = 10.5607 ± 2.20E-04 aeq = 4.9993

Keq = 1.8062

k1 = 4.121E-04
-Sqr 1,00041E-6
k-1 = 2.281E-04
uare 1

Standard Error
067 2,23243E-4
931 1,97823E-4
-Sqr 1,00041E-6
uare 1

Standard Error
 eq   0 K eq kapp k app
067 2,23243E-4 K eq  k1  k 1 
l 1+K eq 1+K eq
931 1,97823E-4 C0     eq
100
7E-4 7,32867E-8
2
2 2  
 K eq  2  K eq  2  1 
 K eq     0    eq    

  0    eq   l C0     eq 
 100  
2
 k
2
 2  k1
2
 2  
 k1   1   K eq     kapp  
kapp   2   K
 K eq   kapp   2 K eq 
4000 5000      
 1+K eq  
  1+
2
 k1  2
2 2
 k 1  2  
 k1    K eq     kapp  
 kapp   2  
 K eq   kapp  2 K eq 
     1+K eq
   
  1+
 t(s) a(t) t(s) a(t) t(s) a(t)
3189 5.721 3684 5.525 4218 5.373
3203 5.714 3700 5.520 4235 5.369
3217 5.708 3716 5.514 4252 5.365
3231 5.702 3731 5.509 4269 5.361
3245 5.695 3747 5.504 4286 5.357
3259 5.689 3763 5.499 4303 5.353
3274 5.683 3779 5.494 4320 5.350
3289 5.676 3795 5.489 4337 5.346
3304 5.670 3811 5.484 4354 5.342
3319 5.663 3827 5.479 4371 5.338
3334 5.657 3843 5.474 4389 5.335
3349 5.651 3859 5.469 4406 5.331
3364 5.644 3875 5.465 4422 5.327
3379 5.638 3891 5.460 4440 5.324
3394 5.632 3907 5.455 4457 5.321
3409 5.626 3923 5.451 4474 5.317
3426 5.620 3939 5.446 4491 5.314
3440 5.614 3955 5.441 4509 5.310
3456 5.608 3971 5.437 4526 5.307
3470 5.602 3987 5.433 4544 5.303
3486 5.596 4003 5.428 4562 5.300
3500 5.590 4019 5.424 4580 5.296
3516 5.584 4035 5.420 4599 5.293
3531 5.579 4051 5.415 4617 5.289
3546 5.574 4067 5.411 4635 5.286
3561 5.568 4083 5.407 4653 5.283
3576 5.563 4100 5.403 4671 5.279
3591 5.557 4117 5.398 4689 5.276
3606 5.552 4134 5.394 4707 5.273
3622 5.546 4151 5.390 4725 5.270
3637 5.541 4168 5.385 4743 5.267
3653 5.536 4185 5.381 4761 5.264
3669 5.530 4201 5.377 4779 5.261

30

d /g ml-1 = 1.0348 %p/v = 10.404 [a]b = 18.46

± 0.0002 kapp = 6.402E-04 ± 7.30E-08

± 0.00020

± 4.96E-08
± 3.05E-08
kapp kapp
k1 
K eq 1+K eq

2
2  l 
 
  2
 C0    0 
1
 l   0   100  2
 eq
 l 2
 C     eq 
0
  
C     eq  
0
 100 
 100  
2
  2
 kapp   2   K eq   2
 2 K eq  kapp
1+K eq 

 1+K eq  
 
2
  2
  kapp   2   1   2
 2 K eq  kapp
1+K eq 
 
 1+K eq  
 
 Turno 1 Turno 2
t/°C = 25 t/°C = 20

Keq = 1.813145 ± 0.000695 Keq = 1.850672 ±

k1 = 0.000261 ± 7.93E-08 k1 = 0.000159 ±

k-1 = 0.000144 ± 5.29E-08 k-1 = 0.000086 ±

Turno 4 Turno 5
t/°C = 25 t/°C = 27.5

Keq = 1.814155 ± 0.000316 Keq = 1.817701 ±

k1 = 0.000258 ± 3.89E-08 k1 = 0.000327 ±

k-1 = 0.000142 ± 2.52E-08 k-1 = 0.000180 ±

t/°C T/K 1/T Keq k1 k-1 ln(Keq) ln(k1)

25 298.15 0.00335 1.81314 2.614E-04 1.442E-04 0.5951 -8.2494
20 293.15 0.00341 1.85067 1.593E-04 8.606E-05 0.6155 -8.7449
22.5 295.65 0.00338 1.82102 2.027E-04 1.113E-04 0.5994 -8.5039
25 298.15 0.00335 1.81415 2.580E-04 1.422E-04 0.5956 -8.2626
27.5 300.65 0.00333 1.81770 3.266E-04 1.797E-04 0.5976 -8.0266
30 303.15 0.00330 1.80616 4.121E-04 2.281E-04 0.5912 -7.7944

DrH°(298 K) = -1501.3 J mol-1 DrG°(298 K) = -1484.9 J mol-1

DrS°(298 K) = -0.055 J K-1 mol-1 Keq(298 K) = 1.8203

Reazione diretta Reazione inversa

Eatt = 70.3 kJ mol -1
Eatt = 71.8 kJ mol-1
A = 5.36E+08 A = 5.40E+08

[Eatt(1) - Eatt(-1)] x 1000 = -1501.3 J mol-1

-2
ln(k1)

-4

-6

-8
 0

-2

ln(k1)
-4

-6

-8 f(x) = − 8455.57913815764 x + 20.0998379140303

-10

-12
0.00328 0.00333 1/T / K-1 0.00338 0.0034
o2 Turno 3
t/°C = 22.5

0.001236 Keq = 1.821020 ± 0.000431

6.93E-08 k1 = 0.000203 ± 3.76E-08

4.89E-08 k-1 = 0.000111 ± 2.51E-08

o5 Turno 6
t/°C = 30

0.000445 Keq = 1.806160 ± 0.000196

8.24E-08 k1 = 0.000412 ± 4.96E-08

5.12E-08 k-1 = 0.000228 ± 3.05E-08

ln(k-1)
0.70
-8.8445 180.5586811 -0.00660059 -8455.57914
-9.3605 57.79815577 0.193890049 68.1545288
-9.1033 0.709282844 0.005141794 0.999740194
ln(Keq)

-8.8582 9.759077912 4 15392.0788

-8.6242 0.65
-8.3856

0.60 f(x) = 180.558681080326 x − 0.0066005914810896

0.55

0.50
0.00328 0.00333 1/T / K-1 0.00338

-2
ln(k-1)

-4

-6

-8
 0

-2

ln(k-1)
-4

-6

-8
f(x) = − 8636.13781923796 x + 20.1064385055114

-10

-12
0.00343 0.00328 0.00333 1/T / K-1 0.00338
 20.09983791 -8636.13782 20.10643851
0.228631602 100.9529713 0.33865746
0.006063109 0.999453712 0.008980898
4 7318.143423 4

66005914810896

1/T / K-1 0.00338 0.00343

064385055114

1/T / K-1 0.00338 0.00343

 Dati sperimentali
t(°C) T(K) p(hPa)
24.2 297.35 194.5
25.9 299.05 209.6
27.3 300.45 222.1 550 Punti sperimentali
28.2 301.35 230.1
28.6 301.75 235.0 Antoine (User) Fit
29.2 302.35 240.4 500
29.6
31.1
302.75
304.25
245.1
260.5
p = e[A - B/(C + T)]
31.7 304.85 266.7 450
32 305.15 269.9
32.4 305.55 274.7
33.3 306.45 284.6
400

p / hPa
33.8 306.95 290.8
35 308.15 305.2 350
35.6 308.75 313.0
36.1 309.25 319.6
36.6 309.75 325.0 300 -- Reduced Chi-Sqr
37 310.15 330.1 -- Adj. R-Square
37.4 310.55 335.4 Value St
37.8 310.95 340.6 250
38.2 311.35 346.6
A 15,75367
39 312.15 356.7 B 2513,27205
39.5 312.65 364.0
200 C -57,63946
40 313.15 370.7
40.5 313.65 378.9 150
41.5 314.65 394.0
42 315.15 401.5
295 300 305 310 315 3
42.5
43
315.65
316.15
408.8
417.6 T/K
43.6 316.75 425.8
45.5 318.65 457.9
46 319.15 465.4
 46.5 319.65 473.6
47.2 320.35 486.1
47.7 320.85 495.2
48.4 321.55 507.5

n-esano dati critici: Pc/bar = 30.1 Tc/K = 507.5 Vc/cm3mol-1= 370

PMesano = 86.178 w = 0.299

Eq. di Antoine: lnP(hPa) = A - B/[C + T]

Parametri di Antoine A = 15.7537 B = 2513.272 C = -56.6395

Calcolati dall'Eq. Di Antoine Vapore ideale Calc. con l'Eq. Di Peng-Robinson Vap. e liq. reali
t/°C P/hPa dlnP/dT DvapH°/kJ mol-1
Zvap Zliq DvapH°/kJ mol-1
24 201.13 0.0434 31.90 0.9881 1.06E-03 31.48
25 210.03 0.0431 31.85 0.9877 1.11E-03 31.42
26 219.23 0.0427 31.80 0.9873 1.16E-03 31.36
27 228.77 0.0424 31.75 0.9868 1.20E-03 31.29
28 238.63 0.0420 31.70 0.9864 1.25E-03 31.23
29 248.83 0.0417 31.65 0.9859 1.30E-03 31.16
30 259.38 0.0414 31.60 0.9855 1.36E-03 31.10
31 270.29 0.0410 31.55 0.9850 1.41E-03 31.04
32 281.56 0.0407 31.51 0.9845 1.47E-03 30.97
33 293.21 0.0404 31.46 0.9840 1.52E-03 30.91
34 305.24 0.0400 31.41 0.9834 1.58E-03 30.84
35 317.66 0.0397 31.37 0.9829 1.64E-03 30.78
36 330.49 0.0394 31.32 0.9824 1.71E-03 30.72
37 343.72 0.0391 31.28 0.9818 1.77E-03 30.65
38 357.37 0.0388 31.23 0.9812 1.84E-03 30.59
39 371.45 0.0385 31.19 0.9807 1.91E-03 30.52
40 385.97 0.0382 31.14 0.9801 1.98E-03 30.46
41 400.94 0.0379 31.10 0.9795 2.05E-03 30.40
42 416.37 0.0376 31.06 0.9788 2.13E-03 30.33
43 432.26 0.0373 31.01 0.9782 2.21E-03 30.27
44 448.64 0.0370 30.97 0.9776 2.28E-03 30.20
45 465.50 0.0368 30.93 0.9769 2.37E-03 30.14
46 482.85 0.0365 30.89 0.9762 2.45E-03 30.08
47 500.72 0.0362 30.84 0.9755 2.54E-03 30.01
48 519.10 0.0359 30.80 0.9748 2.63E-03 29.95
49 538.02 0.0357 30.76 0.9741 2.72E-03 29.88
50 557.47 0.0354 30.72 0.9734 2.81E-03 29.82
tali
Fit

ed Chi-Sqr 0,22658
. R-Square 0,99997
Value Standard Error
15,75367 0,34217
513,27205 179,93062
-57,63946 8,56044

315 320 325

 XMeC Xept n m= 0.03512
Eptano 0 1 1.38958 1.435
Me-cicloesano 1 0 1.42470
coda 0.74374 0.25626 1.41570 0.468252 0.531748
1.425
testa 0.46825 0.53175 1.40603 0.468252 0.531748

1.415 0.743736 0.256264

n
0.743736 0.256264

1.405

Parametri di Antoine
A B C 1.395
1) n-Eptano 15.874 2911.32 -56.51
2) Me-cicloesano 15.747 2944.02 -50.98
1.385
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8
xEptano
T(coda) = 101 °C
T(testa) = 99 °C

T(media) = 100 °C

P°Eptano(Tmedia) = 792.29 torr aideale = 1.0724 n= 16.051

P°Me-cicloesano(Tmedia) = 738.77 torr

x y
0.00 0.00000
0.01 0.01072 1
0.02 0.02142
0.03 0.03210
yEptano

0.04 0.04277 0.8

0.05 0.05343
0.06 0.06407
0.07 0.07469
0.6
0.08 0.08530
0.09 0.09590
0.10 0.10647
0.11 0.11704 0.4 0.256264 0
0.12 0.12758 0.256264 0.256264
0.13 0.13812
0.14 0.15064 0.2 0.531748 0
0.15 0.16114 0.531748 0.531748
0.16 0.17163
0.17 0.18210
0
0.18 0.19256
0.19 0.20300
0 0.2 xEptano
0.4 0.6 0.8
0.20 0.21343
 0
0 0.2 xEptano
0.4 0.6 0.8

0.21 0.22384
0.22 0.23424
0.23 0.24462
0.24 0.25499 0.6
0.25 0.26534
0.26 0.27568

yEptano
0.27 0.28601
0.28 0.29632 0.5
0.29 0.30661
0.30 0.31689
0.31 0.32716
0.32 0.33741 0.4
0.33 0.34764
0.34 0.35787
0.35 0.36807
0.36 0.37827
0.3
0.37 0.38845
0.38 0.39861
0.39 0.40876
0.40 0.41890
0.41 0.42902 0.2
0.42 0.43913 0.2 0.3 xEptano
0.4 0.5
0.43 0.44922
0.44 0.45930
0.45 0.46936
0.46 0.47942
0.47 0.48945
0.48 0.49948
0.49 0.50948
0.50 0.51948
0.51 0.52746
0.52 0.53743
0.53 0.54738
0.54 0.55732
0.55 0.56724
0.56 0.57716
0.57 0.58705
0.58 0.59694
0.59 0.60681
0.60 0.61666
0.61 0.62651
0.62 0.63633
0.63 0.64615
0.64 0.65595
0.65 0.66574
0.66 0.67552
0.67 0.68528
0.68 0.69502
0.69 0.70476
0.70 0.71448
0.71 0.72419
0.72 0.73388
0.73 0.74356
0.74 0.75323
0.75 0.76288
0.76 0.77252
0.77 0.78215
0.78 0.79177
0.79 0.80137
0.80 0.81096
0.81 0.82053
0.82 0.83009
0.83 0.83964
0.84 0.84918
0.85 0.85870
0.86 0.86821
0.87 0.87771
0.88 0.88719
0.89 0.89666
0.90 0.90612
0.91 0.91557
0.92 0.92500
0.93 0.93442
0.94 0.94383
0.95 0.95322
0.96 0.96260
0.97 0.97197
0.98 0.98133
0.99 0.99067
1.00 1.00000
 1.385
1.406025

1.385
1.4157

0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

xEptano

Piatti teorici
5 0.25626 0.25626 22 0.25626
0.25626 0.26982 0.26982
6 0.26982 0.26982 23 0.26982
0.26982 0.28382 0.28382
7 0.28382 0.28382 24 0.28382
0.28382 0.29825 0.29825
8 0.29825 0.29825 25 0.29825
0.29825 0.31309 0.31309
9 0.31309 0.31309 26 0.31309
0.31309 0.32833 0.32833
10 0.32833 0.32833 27 0.32833
0.32833 0.34393 0.34393
11 0.34393 0.34393 28 0.34393
0.34393 0.35988 0.35988
12 0.35988 0.35988 29 0.35988
0.35988 0.37615 0.37615
13 0.37615 0.37615 30 0.37615
0.37615 0.39270 0.39270
0.2 xEptano
0.4 0.6 0.8 1
14 0.39270 0.39270 31 0.39270
0.39270 0.40950 0.40950
0.2 xEptano
0.4 0.6 0.8 1

15 0.40950 0.40950 32 0.40950

0.40950 0.42651 0.42651
16 0.42651 0.42651 33 0.42651
0.42651 0.44370 0.44370
17 0.44370 0.44370 34 0.44370
0.44370 0.46103 0.46103
18 0.46103 0.46103 35 0.46103
0.46103 0.47845 0.47845
19 0.47845 0.47845 36 0.47845
0.47845 0.49592 0.49592
20 0.49592 0.49592 37 0.49592
0.49592 0.51340 0.51340
21 0.51340 0.51340 38 0.51340
0.51340 0.53085 0.53085
0.53085 0.53085
0.53085 0.54823

0.3 xEptano
0.4 0.5 0.6
0.26982
0.26982
0.28382
0.28382
0.29825
0.29825
0.31309
0.31309
0.32833
0.32833
0.34393
0.34393
0.35988
0.35988
0.37615
0.37615
0.39270
0.39270
0.40950
0.40950
0.42651
0.42651
0.44370
0.44370
0.46103
0.46103
0.47845
0.47845
0.49592
0.49592
0.51340
0.51340
0.53085
0.53085