Calculos para diagramas T vs X-Y y X vs Y ideales para Metanol (1)-Agua(2

Pman (Hg) 0 Patm (Hg) 585 PTOT (Hg) 585

(g/mol) (cal/g°C) (cal/mol°C) (cal/mol) A B C

Compuesto PM Cp Cp l Ctes. de Antoine (mm Hg y °C)
Metanol (1) 32.04 0.605 19.3842 8415 8.0724 1574.99 238.8
Agua (2) 18.015 0.999 17.9970 9718 7.96681 1669.21 228

Ec. Antoine Raoult/Dalton

(°C) (mm Hg) (-) (mm Hg) (-) (cal °C/mol)
Ti P1i0 P2i0 X1 P y1 hl Hv
58.07418 585.000008878 135.495476 1.000000 585.00000 1.000000 1126 9541
59.00000 607.6439252317 141.497016 0.951423 585.00000 0.988250 1140 9573
60.00000 632.9204524 148.231992 0.901131 585.00000 0.974948 1155 9609
61.00000 659.0692064724 155.237575 0.852988 585.00000 0.960988 1170 9645
62.00000 686.1135727 162.522483 0.806884 585.00000 0.946349 1185 9682
63.00000 714.077356521 170.095632 0.762717 585.00000 0.931007 1200 9720
64.00000 742.9847857915 177.966147 0.720390 585.00000 0.914938 1216 9759
65.00000 772.8605134845 186.143357 0.679811 585.00000 0.898118 1231 9799
66.00000 803.7296200 194.636805 0.640893 585.00000 0.880521 1246 9839
67.00000 835.6176154456 203.456241 0.603554 585.00000 0.862121 1262 9881
68.00000 868.5504420 212.611635 0.567718 585.00000 0.842892 1277 9923
69.00000 902.5544759391 222.113170 0.533311 585.00000 0.822807 1293 9966
70.00000 937.6565298134 231.971249 0.500264 585.00000 0.801839 1308 10011
71.00000 973.883854402 242.196498 0.468511 585.00000 0.779958 1324 10056
72.00000 1011.264140651 252.799765 0.437991 585.00000 0.757135 1340 10103
73.00000 1049.825521509 263.792126 0.408644 585.00000 0.733342 1355 10150
74.00000 1089.596573684 275.184881 0.380416 585.00000 0.708547 1371 10199
75.00000 1130.606319317 286.989565 0.353253 585.00000 0.682719 1387 10249
76.00000 1172.884227573 299.217942 0.327107 585.00000 0.655826 1402 10300
77.00000 1216.460216149 311.882012 0.301929 585.00000 0.627836 1418 10353
78.00000 1261.364652697 324.994012 0.277674 585.00000 0.598715 1434 10406
79.00000 1307.628356164 338.566416 0.254301 585.00000 0.568430 1450 10461
80.00000 1355.282598048 352.611939 0.231769 585.00000 0.536945 1465 10518
81.00000 1404.359104 367.143539 0.210040 585.00000 0.504224 1481 10575
82.00000 1454.890052738 382.174418 0.189077 585.00000 0.470232 1497 10635
83.00000 1506.9080814 397.718024 0.168846 585.00000 0.434932 1513 10695
84.00000 1560.446282 413.788054 0.149314 585.00000 0.398284 1529 10757
85.00000 1615.53820495 430.398454 0.130450 585.00000 0.360251 1545 10821
86.00000 1672.217858348 447.563422 0.112225 585.00000 0.320794 1561 10886
87.00000 1730.519709656 465.297410 0.094610 585.00000 0.279871 1577 10953
88.00000 1790.478685769 483.615123 0.077579 585.00000 0.237441 1593 11021
89.00000 1852.130173601 502.531526 0.061106 585.00000 0.193463 1609 11092
90.00000 1915.510020 522.061840 0.045167 585.00000 0.147894 1625 11163
91.00000 1980.654534532 542.221546 0.029740 585.00000 0.100690 1641 11237
93.00000 2116.385101439 584.492372 0.000331 585.00000 0.001199 1674 11390
93.02327 2118.007911904 584.999886 0.000000 585.00000 0.000000 1674 11392
a Metanol (1)-Agua(2) @ 585 mm de Hg 585.0 mmHg = 0.8 atm = 0.7799337

NOMENCLATURA DE COLOR

(°C) (cal /mol) Celdas dato (llenar)

T. eb. hli Hvi y Constantes de los componentes de la mz
58.074180 1125.7215 9540.7215 y Titulos generales del proceso de cálculo
93.0232752 1674.1385 11392.138 y Variables calculadas

Referencia
p/graficar
1.000000 Diagrama T vs x-y (mezcla metanol-agua) @
0.951423 IDEAL
0.901131 95
0.852988
0.806884
90
0.762717
li
0.720390
0.679811 85

0.640893
0.603554 80
0.567718
Temperatura, T (°C)

0.533311
0.500264 75

0.468511
0.437991 70
0.408644
0.380416
0.353253 65

0.327107
0.301929 60
0.277674
0.254301
0.231769 55
0.0 0.1 0.2 0.3 0.4 0.5 0.6
0.210140
0.189077 Fracción molar x, y

0.168846
0.149314
0.130450
0.112225
0.094610
Diagrama x vs y (mezcla Metanol-agua) @
IDEAL
0.077579 1.0
0.061106
0.045167 0.9
0.029740
0.8

0.7
or, y
 1.0

0.9

0.000331 0.8
0.000000
0.7

Fracción molar del vapor, y

0.6

0.5

0.4

0.3

0.2

0.1

0.0
0.0 0.1 0.2 0.3 0.4 0.5 0.6 0

Fracción molar del líquido, x

 bar = 0.7951 Kg/cm2

OR

mponentes de la mz
proceso de cálculo

(mezcla metanol-agua) @ 585 mm de Hg

IDEAL

liquido Vapor

0.4 0.5 0.6 0.7 0.8 0.9 1.0

Fracción molar x, y

mezcla Metanol-agua) @ 585 mm de Hg

IDEAL
3 0.4 0.5 0.6 0.7 0.8 0.9 1.0

Fracción molar del líquido, x

 Calculos para diagramas T vs X-Y y X vs Y no ideales para Metanol (1)-Agua(
Pman (Hg) 175 Patm (Hg) 585 PTOT (Hg) 760

(g/mol) (cal/g°C) (cal/mol°C) VanLaar (cal/mol) A B C

Compuesto PM Cp A12_21 l Ctes. de Antoine (mm Hg y °C)
Metanol (1) 32.04 0.605 19.3842 0.9014 8415 8.0724 1574.99 238.8
Agua (2) 18.015 0.999 17.9970 0.5559 9718 7.96681 1669.21 228

Ec. Antoine Ec. Van Laar Raoult m

(°C) (mm Hg) (-) (-) (-) (mm Hg) (-) (-) (cal °C/mol)
Ti P1 i
0
P2i
0
X1_supuesta g1 g2 P X1_calculada y1 hl Hv
64.570 759.894 182.589 1.000 1.000 1.744 759.898 1.000 1.000 1251.639 9666.353
65.318 782.563 188.808 0.950 1.001 1.685 760.000 0.950 0.979 1261.603 9706.503
66.077 806.139 195.302 0.900 1.004 1.627 760.000 0.900 0.958 1271.678 9746.498
66.851 830.813 202.124 0.850 1.009 1.572 760.000 0.850 0.937 1281.950 9786.742
67.643 856.684 209.307 0.800 1.016 1.518 760.000 0.800 0.916 1292.445 9827.305
68.455 883.881 216.889 0.750 1.027 1.466 760.000 0.750 0.895 1303.201 9868.286
69.288 912.563 224.919 0.700 1.040 1.416 760.000 0.700 0.874 1314.264 9909.817
70.148 942.942 233.460 0.650 1.058 1.368 760.000 0.650 0.853 1325.702 9952.082
71.038 975.299 242.597 0.600 1.080 1.322 760.000 0.600 0.831 1337.605 9995.334
71.967 1010.018 252.445 0.550 1.107 1.278 760.000 0.550 0.809 1350.100 10039.926
72.944 1047.636 263.167 0.500 1.140 1.237 760.001 0.500 0.786 1363.367 10086.351
73.983 1088.921 274.991 0.450 1.181 1.198 760.000 0.450 0.762 1377.659 10135.311
75.105 1135.002 288.258 0.400 1.231 1.162 760.000 0.400 0.736 1393.346 10187.828
76.341 1187.581 303.482 0.350 1.293 1.128 760.000 0.350 0.707 1410.967 10245.409
77.734 1249.306 321.467 0.300 1.369 1.098 760.000 0.300 0.675 1431.335 10310.357
79.357 1324.474 343.524 0.250 1.462 1.071 760.000 0.250 0.637 1455.706 10386.316
81.321 1420.417 371.913 0.200 1.578 1.047 760.000 0.200 0.590 1486.094 10479.343
83.817 1550.521 410.804 0.150 1.724 1.028 760.000 0.150 0.528 1525.890 10600.177
100.170 2666.862 759.261 0.000 2.462 1.000 759.842 0.000 0.001 1802.772 11519.752
ra Metanol (1)-Agua(2) @ 585 mm de Hg 585.0 mmHg = 0.8 atm = 0.7799337

NOMENCLATURA DE COLOR

(°C) (cal /mol) Celdas dato (llenar)

p.e. hli Hvi y Constantes de los componentes de la mz
64.5736 1251.706613 9666.7066 y Titulos generales del proceso de cálculo
100.1972 1803.248283 11521.248 y Variables calculadas

Referencia
p/graficar
Diagrama T vs X-Y (mezcla metanol-agua) @ 585 mm de Hg
1.000001 NO IDEAL
0.936835
105
0.870284
0.805536
100
0.742695
Column A
0.681910 Column A
95
0.623382
0.567361
90
0.514130
0.463987
Temperatura, T (°C)

85 0.417202
0.373980
80 0.334426
0.298528

75 0.266160
Diagrama X vs Y (mezcla Metanol-agua) @ 585 mm de Hg
0.237105
NO IDEAL
1.0 0.211093
70
0.187821
0.9 0.166988
65 0.148306
0.8 0.131512
60 0.116370
0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0
0.7 0.102675
0.090247 Fracción molar x, y
0.6 0.078930
Fracción molar del vapor, y

0.068592
0.5 0.059118
0.050410
0.4 0.042381
0.034959
0.3 0.028080
0.021688
0.2 0.015734
0.010178
0.1

0.0
0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0

Fracción molar del líquido, x

 0.3

Frac
0.2

0.1 0.000110
0.000001
0.0
0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0

Fracción molar del líquido, x

 bar = 0.7951 Kg/cm2

OR

mponentes de la mz
proceso de cálculo

Hg

0.9 1.0

0.9 1.0
0.9 1.0