λ0 1.

47 μS V solução (L) V SDS adicionado (L) nSDS

V água início 0.04 L 0.04 0 0
0.0405 0.0005 0.00002
[SDS] INÍCIO 0.04 mol/L 0.041 0.001 0.00004
0.0415 0.0015 0.00006
0.042 0.002 0.00008
0.0425 0.0025 0.0001
0.043 0.003 0.00012
0.0435 0.0035 0.00014
0.044 0.004 0.00016
0.0445 0.0045 0.00018
0.045 0.005 0.0002
0.0455 0.0055 0.00022
0.046 0.006 0.00024
0.0465 0.0065 0.00026
0.047 0.007 0.00028
0.0475 0.0075 0.0003
0.048 0.008 0.00032
0.0485 0.0085 0.00034
0.049 0.009 0.00036
R= 7,38 mmol/L 0.0495 0.0095 0.00038
0.05 0.01 0.0004
0.0505 0.0105 0.00042
0.051 0.011 0.00044
0.0515 0.0115 0.00046
0.052 0.012 0.00048
0.0525 0.0125 0.0005
0.053 0.013 0.00052

EXTRAPOLAÇÃO DAS RETAS λN x [

450 450
400 f(x) = 29.3098792196919 x + 132.34383257308 400
350 350
300 f(x) = 45.6178493862405 x + 11.9870893887534 300
250 250
λN

λN

200 200
150 150
100 100
50 50
0 0
5 5.5 6 6.5 7 7.5 8 8.5 9 9.5 10 0.45 1.45 2.45 3.45

[SDS] (mmol/L) [SDS]

 [SDS] (mmol/L) λ λN dλN/d[SDS] Diferença λ0 558
0 1.47 1 V Solução N 0.04
0.493827160494 38.34 26.08163
0.975609756098 54.6 37.14286 22.95895408
1.44578313253 72.1 49.04762 25.31994048 2.36098639455781
1.904761904762 137.7 93.67347 97.22857143 71.908630952381
2.352941176471 171.4 116.5986 51.15178571 -46.0767857142857
2.790697674419 200.7 136.5306 45.53210034 -5.61968537414985
3.218390804598 230 156.4626 46.60344388 1.07134353741512
3.636363636364 260.1 176.9388 48.98928571 2.38584183673469
4.044943820225 287 195.2381 44.78758503 -4.20170068027215
4.444444444444 313 212.9252 44.27295918 -0.51462585034011
4.835164835165 339 230.6122 45.26785714 0.994897959183675
5.217391304348 368 250.3401 51.61309524 6.34523809523803
5.591397849462 390.7 265.7823 41.28852041 -10.3245748299319
5.957446808511 417.4 283.9456 49.61977041 8.33124999999987
6.315789473684 444.2 302.1769 50.87670068 1.25693027210916
6.666666666667 462.7 314.7619 35.86734694 -15.009353741497
7.010309278351 484.2 329.3878 42.56122449 6.6938775510207
7.34693877551 504.7 343.3333 41.42708333 -1.13414115646265
7.676767676768 520.1 353.8095 31.7625 -9.66458333333333
8 537 365.3061 35.56760204 3.80510204081606
8.316831683168 550.9 374.7619 29.84481293 -5.72278911564604
8.627450980392 566.3 385.2381 33.72678571 3.88197278911574
8.932038834951 578.4 393.4694 27.02436224 -6.70242346938784
9.230769230769 593.2 403.5374 33.70272109 6.67835884353739
9.52380952381 606 412.2449 29.71428571 -3.98843537414988
9.811320754717 616.2 419.1837 24.13392857 -5.58035714285668

λN x [SDS] em água
450
400
350
300
250
λN

200
150
100
50
0
0.45 1.45 2.45 3.45 4.45 5.45 6.45 7.45 8.45 9.45 10.45
[SDS] em água (mmol/L)
μS V solução (L) Volume SDS+NaCl adicionado (mL) nSDS (mmol)
L 0.04 0.0 0.000
0.0405 0.5 0.020
0.041 1.0 0.040
0.0415 1.5 0.060
0.042 2.0 0.080
0.0425 2.5 0.100
0.043 3.0 0.120
0.0435 3.5 0.140
0.044 4.0 0.160
0.0445 4.5 0.180
0.045 5.0 0.200
0.0455 5.5 0.220
0.046 6.0 0.240
0.0465 6.5 0.260
0.047 7.0 0.280
0.0475 7.5 0.300
0.048 8.0 0.320
0.0485 8.5 0.340
0.049 9.0 0.360
0.0495 9.5 0.380
0.05 10.0 0.400
0.0505 10.5 0.420
0.051 11.0 0.440
0.0515 11.5 0.460
0.052 12.0 0.480

λN x [SDS] em NaCl
2.100
1.900
1.700
1.500
λN

1.300
1.100
0.900
0.700
0.000 1.000 2.000 3.000 4.000 5.000 6.00
[SDS] (mmol/L)
 [SDS] (mmol/L) λ λN dλN/d[SDS] Diferença
0.000 558.0 1.000 - -
0.494 592.2 1.061 - -
0.976 625.1 1.120 0.122 -
1.446 655.6 1.175 0.116 -0.006
1.905 693.3 1.242 0.147 0.031
2.353 694.9 1.245 0.006 -0.141
2.791 739.6 1.325 0.183 0.177
3.218 764.6 1.370 0.105 -0.078
3.636 793.8 1.423 0.125 0.020
4.045 813.2 1.457 0.085 -0.040
4.444 852.8 1.528 0.178 0.093
4.835 879.7 1.577 0.123 -0.054
5.217 905.7 1.623 0.122 -0.001
5.591 930.1 1.667 0.117 -0.005
5.957 952.0 1.706 0.107 -0.010
6.316 973.8 1.745 0.109 0.002
6.667 988.9 1.772 0.077 -0.032
7.010 1005.0 1.801 0.084 0.007
7.347 1014.0 1.817 0.048 -0.036
7.677 1026.0 1.839 0.065 0.017
8.000 1036.0 1.857 0.055 -0.010
8.317 1047.0 1.876 0.062 0.007
8.627 1053.0 1.887 0.035 -0.028
8.932 1062.0 1.903 0.053 0.018
9.231 1073.0 1.923 0.066 0.013

R: 6,38 mmol.L-1

[SDS] em NaCl EXTRAPOLAÇÃO DAS RETAS

2.500

2.000
f(x) = 0.0525564305363231 x + 1.43598798497919
1.500 f(x) = 0.129146525020085 x + 0.948061694378565
λN

1.000

0.500

0.000
4.000 5.000 6.000 7.000 8.000 9.000 10.000
4.000 5.000 6.000 7.000 8.000 9.000 10.000
[SDS] (mmol/L) [SDS] (mmol/L)
98497919

10.000