Freundlich

1
q=K P n
1
ln ( q )=ln K + ln ( P )
n
y=mx+b
X Y
P, TORR q/mmol/g ln(P) ln(q)
11.1 0.0564 2.4069 -2.8753
25.0 0.1252 3.2189 -2.0778
43.5 0.1980 3.7728 -1.6195
71.4 0.2986 4.2683 -1.2087
100.0 0.3850 4.6052 -0.9545
158.9 0.5441 5.0683 -0.6086
227.5 0.7020 5.4272 -0.3538
304.2 0.8430 5.7177 -0.1708
387.0 1.0100 5.9584 0.0100
468.0 1.1380 6.1485 0.1293
569.0 1.2880 6.3439 0.2531
677.8 1.4340 6.5189 0.3605
775.0 1.5620 6.6529 0.4460
 Freundlich
1.0000
0.5000
f(x) = 0.762561755924718 x − 4.54472530879739
0.0000 R² = 0.994983396818853

-0.5000
-1.0000
-1.5000
-2.0000
-2.5000
-3.0000
-3.5000
2.0000 2.5000 3.0000 3.5000 4.0000 4.5000 5.0000 5.5000 6.0000 6.5000 7.0000

m=0.7626
b=−4.5447
q=K =exp ( b )=0.010623
1
=0.7626
n
0.7626 2
q=0.010623 P R =0.995

Langmuir:

qm K P
q=
1+ KP
1
=
1 1
+ ( )
1
q q m K P qm

y=mx+b
1
m=
qm K

1
b=
qm
 X Y
P, TORR q/mmol/g 1/P 1/q
11.1 0.0564 0.09009 17.73050
25.0 0.1252 0.04000 7.98722
43.5 0.1980 0.02299 5.05051
71.4 0.2986 0.01401 3.34896
100.0 0.3850 0.01000 2.59740
158.9 0.5441 0.00629 1.83790
227.5 0.7020 0.00440 1.42450
304.2 0.8430 0.00329 1.18624
387.0 1.0100 0.00258 0.99010
468.0 1.1380 0.00214 0.87873
569.0 1.2880 0.00176 0.77640
677.8 1.4340 0.00148 0.69735
775.0 1.5620 0.00129 0.64020

Langmuir
20.00000

18.00000
f(x) = 190.863947610441 x + 0.531934485781402
16.00000 R² = 0.999436466007818

14.00000

12.00000

10.00000

8.00000

6.00000

4.00000

2.00000

0.00000
0.00000 0.01000 0.02000 0.03000 0.04000 0.05000 0.06000 0.07000 0.08000 0.09000 0.10000

m=190 . 8 6
b=0 .5 319
q m=1.88005

K=0.002787
 1.88005∗0.002787 P 2
q= R =0.9994
1+ 0.002787 P
Exp Freundlich Langmuir
P, torr q/mmol/g qCalc qCalc
11.1 0.0564 0.06659 0.05641
25.0 0.1252 0.12369 0.12245
43.5 0.1980 0.18870 0.20327
71.4 0.2986 0.27535 0.31201
100.0 0.3850 0.35601 0.40975
158.9 0.5441 0.50680 0.57702
227.5 0.7020 0.66634 0.72948
304.2 0.8430 0.83161 0.86258
387.0 1.0100 0.99919 0.97554
468.0 1.1380 1.15502 1.06415
569.0 1.2880 1.34063 1.15296
677.8 1.4340 1.53200 1.22928
775.0 1.5620 1.69685 1.28506

1.4000

1.2000

1.0000

0.8000
Exp
Freundlich
0.6000 Langmuir

0.4000

0.2000

0.0000
0.0 50.0 100.0 150.0 200.0 250.0 300.0 350.0 400.0 450.0 500.0

El mejor modelo que se ajusta a los datos experimentales es la isoterma de Langmuir.