Beruflich Dokumente
Kultur Dokumente
Organische Verbindungen Und Ihre Reaktionswege
Organische Verbindungen Und Ihre Reaktionswege
An cdg 9nefZadg
90
Z E E E E E E
E B B B E ) E1 E B B B E
E E E E
91
Z PdZjshnmrfkdhbgtmf9 BG2H ) NG“ BG2NG ) H“
a CZr Gxcpnwhchnm fpdhes Zkr mtbkdnoghkdr Sdhkbgdm Zm: chd ;afZmfrfptood hrs cZr Hnchchnm- Dr
gZmcdks rhbg Zkrn tl dhmd mtbkdnoghkd Rtarshstshnm- CZ rhbg eöp dhmdm PdZjshnmrZakZte mZbg RM0
dhm ophlßpdr BZpanjZshnm ahkcdm lörrsd+ udpkßtes chd PdZjsnm mZbg cdl RM1,LdbgZmhrltr9
“
E
E E
E N ) E B „ E N B „ E N B E ) „
E E
E
E
PdZjshnmrrbgphssd9
.- Mtbkdnoghkdp ;mfphee cdr Excpnwhchnmr7
N
N
BE2 B ) N E BE2 B N B 1 E3
N B 1 E3 N E
N N
BE2 B ) B 1 E3 N BE2 B ) B 1 E3 N E
N E N
93
Z PdZjshnm unm BxbkngdwZm lhs Apnl tmsdp Khbgsdhmektrr pZchjZkhrbgd Rtarshstshnm(9
E E
E E E E
E B E E B E
B B Khbgs B B
E E ) Ap 1 E Ap ) EAp
B B B B
E B E E B E
E E E E
E E
0 Dkdldmsd Bgdlhd Nadorsted LOV — Dpmrs Ikdss UdpkZf FlaG+ RstssfZps 1.04
5 N of Z m h r b g d Sd o a h m c t m f d m t m c h g od O d Z i s h n m r u d f d
PdZjshnmrldbgZmhrltr9
OnkZphrhdptmf tmc gdsdpnkxshrbgd RoZkstmf cdr Ap1+Lnkdiäkr: Ahkctmf cdr Apnlnmhtlhnmr7
E E E
E E E E E E
E B E E B E E B E
B B B B ) “ B B
E ) Ap Ap E Ap Ap E Ap ) Ap
B B B B B B
E B E E B E E B E
E E E
E E E
PdZjshnmrldbgZmhrltr9
Ehmvdhrd3
©gmkhbg vhd adh cdp Rtarshstshnm dhmdp Gxcpnwxfptood vhpc Ztbg ghdp ytmßbgrs cZr RZtdprsnee,
Zsnl cdr Dsgdplnkdjökr opnsnmhdps+ rncZrr Zkr ;afZmfrfptood dhm OpnoZmnklnkdjök zunpfdahkcds„
vhpc- MZbg cdp Opnsnmhdptmf dpenkfs cdp mtbkdnoghkd ;mfphee cdr Hnchchnmr Zm dhmdl cdl N,;snl
admZbgaZpsdm B,;snl+ cZr dhmd onrhshud SdhkkZctmf spßfs- CZ dhmd Fptood Zm dhmdl ophlßpdm
IngkdmrsneeZsnl rtarshsthdps vhpc+ kßtes chd PdZjshnm mZbg cdl RM1,LdbgZmhrltr Za-
1 Dkdldmsd Bgdlhd Nadorsted LOV — Dpmrs Ikdss UdpkZf FlaG+ RstssfZps 1.04
5 N of Z m h r b g d Sd o a h m c t m f d m t m c h g od O d Z i s h n m r u d f d
B2G6NG ) G2N) ) H“ B 2G 6H ) 1 G 1N
95 Hm cdp dprsdm Rsted nwhchdps lZm chd Gßkesd cdr ophlßpdm ;kjngnkr lhs Itoedpnwhc ytp BZpanm,
rßtpd9
BtN BtN
P – BG1NG P – BGN P – BNNG
PdZjshnmrsxo9 NwhcZshnmrpdZjshnm
Ehmvdhr3 Chd NwhcZshnmryZgk cdr IngkdmrsneeZsnlr vhpc unm “Ä ;kjngnk( öadp Ä ;kcdgxc( Zte ÄÄÄ
BZpanmrßtpd( dpgägs-
Hm cdp yvdhsdm Rsted udpdrsdps lZm chd BZpanmrßtpd lhs cdp Zmcdpdm Gßkesd cdr ophlßpdm
;kjngnkr9
G 2N )
P – BNNG ) P – BG1NG P – BNNBG1 – P ) G1N
Ehmvdhrd3
Chd dprsd PdZjshnmrrsted vhpc hl Rbgökdpatbg hm IZo- 1-03 adgZmcdks-
CZ hm cdp ;tefZadmrsdkktmf mZbg dhmdl Adhohdk fdepZfs vhpc+ vhpc hm cdp jnmjpdsdm Kärtmf cdp
Pdrs P dprdsys+ y- A- ctpbg BG2- C- g-+ cdp ophlßpd ;kjngnk jZmm y- A- DsgZmnk rdhm-(
Vdmm DsgZmnk Zkr Adhrohdk fdvßgks vhpc+ jZmm chd dprsd Rsted Ztbg dhmd dmyxlZshrbgd NwhcZshnm
lhs DrrhfrßtpdaZjsdphdm rdhm-
96
Z CZ cZr FZr ApnlvZrrdp dmseßpas+ hrs dr udpltskhbg dhm ;kjdm- CdlmZbg hrs dhmd Dkhlhmhdptmfr,
pdZjshnm ZafdkZtedm tmc Opnodm dmsrsZmcdm9
E BE2 E BE2 N
E B B E ) N E B B ) E E ) Ap
E E
E Ap
a Adh cdp PdZjshnm unm Opnodm lhs ApnlvZrrdp jämmdm chd enkfdmcdm PdZjshnmdm ZakZtedm: dr
gZmcdks rhbg hm Zkkdm Eßkkdm tl dkdjspnoghkd ;cchshnmrpdZjshnmdm9
E BE2 E BE2
B B ) Ap 1 E B B E
E E
Ap Ap
E BE2 E BE2
B B ) Ap 1 ) 1 E1N E B B E ) Ap “ ) E 2N )
E E Ap N E
E BE2 E BE2
B B ) Ap 1 ) 1 E1N E B B E ) Ap “ ) E 2N )
E E E N Ap
2 Dkdldmsd Bgdlhd Nadorsted LOV — Dpmrs Ikdss UdpkZf FlaG+ RstssfZps 1.04
5 N of Z m h r b g d Sd o a h m c t m f d m t m c h g od O d Z i s h n m r u d f d
97
Z Gdprsdkktmfrläfkhbgjdhsdm eöp BgknpdsgZm9
;tr dhmdl ;kjZm DsgZm(9 BG2 – BG2 ) Bk1 BG2 – BG1 – Bk ) GBk
98
E BE2 E E E E
E
B E N B BE2 N B BE2
E N ) E
E B E E B E E B E
E BE2
E E E E
B
) E B
N OpnoZm+1+nk
B
E
E E E E E
E
E B BE2 E B BE2 E B BE2
E N ) E
B E N B E N B E
E E E E E E
OpnoZm+.+nk
;kr GZtosopnctjs ahkcds rhbg OpnoZm,1,nk+ hm fdphmfdm ;msdhkdm OpnoZm,0,nk- Adfpömctmf9 Adh cdp
Ahkctmf unm OpnoZm,1,nk dmrsdgs Zkr Wvhrbgdmopnctjs dhm rdjtmcßpdr BZpanjZshnm- Chdrdr gZs
Ztefptmc cdr )H,Deedjsr cdp ;kjxkfptoodm dhmd fdphmfdpd KZctmfrchbgsd Zl B,;snl tmc hrs cZgdp
rsZahkdp Zkr cZr ophlßpd BZpanjZshnm+ cZr ytp Ahkctmf unm OpnoZm,0,nk eögps-
90.
Z Dsgdm pdZfhdps lhs dhmdp vßrrphfdm Kärtmf unm Apnl tmc IZkhtlapnlhc
unpgZmcdmd Sdhkbgdm rhmc B1G3 + G1N+ Ap1 + Ap“ tmc I)(9
3 Dkdldmsd Bgdlhd Nadorsted LOV — Dpmrs Ikdss UdpkZf FlaG+ RstssfZps 1.04
5 N of Z m h r b g d Sd o a h m c t m f d m t m c h g od O d Z i s h n m r u d f d
a Dsgdm pdZfhdps lhs dhmdp vßrrphfdm Kärtmf unm Apnl tmc MZsphtlbgknphc unpgZmcdmd Sdhkbgdm
rhmc B1G3 + G1N+ Ap1 + Bk“ tmc MZ)(9
Ehmvdhr3 Hl dprsdm PdZjshnmrrbgphss ahkcds rhbg dhm Apnlnmhtlhnm- CdrgZka dmsgZksdm Zkkd chpdjs
Ztr Dsgdm dmsrsdgdmcdm PdZjshnmropnctjsd lhmcdrsdmr dhm ApnlZsnl- CZr Apnlnmhtlhnm jZmm
cZmm unm cdm udprbghdcdmdm mtbkdnoghkdm Sdhkbgdm Zmfdfpheedm vdpcdm-
900
Z CZ dr rhbg tl dhmd dkdjspnoghkd ;cchshnm gZmcdks+ hrs chd PdZjshnmrfdrbgvhmchfjdhs tlrn
fpäÜdp+ id fpäÜdp chd mdfZshud KZctmfrchbgsd Zm cdp B B,Cnoodkahmctmf hrs- Chd adhcdm Ldsgxk,
fptoodm hl 1+2,Chldsgxkats,1,dm dpgägdm Ztefptmc hgpdr )H,Deedjsr chd KZctmfrchbgsd Zm cdp
B B,Cnoodkahmctmf- Chd adhcdm BgknpZsnld hl 0+1,Chbgknpdsgdm udpphmfdpm Ztefptmc hgpdr
“H,Deedjsr chd KZctmfrchbgsd Zm cdp B B,Cnoodkahmctmf-
a Chd Cnoodkahmctmf yvhrbgdm cdm adhcdm IngkdmrsneeZsnldm eögps yt dhmdp ;mgßtetmf unm
Dkdjspnmdm yvhrbgdm cdm adhcdm ;snljdpmdm- Dhm dkdjspnoghkdr Sdhkbgdm dhm Sdhkbgdm lhs dhmdp
onrhshudm KZctmf ncdp SdhkkZctmf( vhpc cZunm Zmfdynfdm+ dhm mtbkdnoghkdr Sdhkbgdm vhpc Zte,
fptmc cdp fkdhbgmZlhfdm KZctmfdm ZafdrsnÜdm-
901
Z CZr adhl BpZbjdm fdahkcdsd FZrfdlhrbg+ cZr Ztr tmfdrßsshfsdm Udpahmctmfdm lhs uhdp
IngkdmrsneeZsnldm adrsdgs+ mdmms lZm B3,Rbgmhss- Rdhmd GZtosadrsZmcsdhkd rhmc AtsZ,0+2,chdm
tmc chd Atsdm,Hrnldpd Ats,0,dm+ :(,Ats,1,dm+ W(,Ats,1,dm tmc Hrnatsdm 1,Ldsgxkopnodm(-
4 Dkdldmsd Bgdlhd Nadorsted LOV — Dpmrs Ikdss UdpkZf FlaG+ RstssfZps 1.04
5 N of Z m h r b g d Sd o a h m c t m f d m t m c h g od O d Z i s h n m r u d f d
PdZjshnmrfkdhbgtmf9
E BE2
E BE2 N ;cchshnm
B B ) E B B BE2
E E Ckhlhmhdptmf
E BE2 E N E
Hrnatsdm 1+LdsgxkopnoZm+1+nk
1 Sde3 Øadp chd Ahkctmf unm LSAD ncdp DSAD tmc cdpdm ZmrbgkhdÜdmcdp RoZkstmf- RsZss VZrrdp
adhl 0- Vdf( udpvdmcds lZm LdsgZmnk ncdp DsgZmnk- Chd PdZjshnmdm rhmc ZmZknf9
E BE2
E BE2 N ;cchshnm
B B ) E B B BE2
E BE2 Ckhlhmhdptmf
E BE2 E N BE2
Hrnatsdm LSAC
E BE2
E BE2 N ;cchshnm
B B ) E B B BE2
E B1E3 Ckhlhmhdptmf
E BE2 E N B1E3
Hrnatsdm CSAC
902
Z Dr ehmcds dhmd mtbkdnoghkd Rtarshstshnm rsZss- PdZjshnmrldbgZmhrltr9
a Chd Rtarshstshnm cdp Gxcpnwxfptood hrs mtp läfkhbg+ vdmm chdrd opnsnmhdps hrs rhdgd PdZjshnmr,
ldbgZmhrltr hm Z( (- UnpZtrrdsytmf cZeöp hrs+ cZrr chd PdZjshnm hm rZtpdp Kärtmf rsZssehmcds-
MZsphtlbgknphckärtmf hrs idcnbg mdtspZk- MZbg WtrZsy unm udpc- Rbgvdedkrßtpd dmsgßks chd
MZsphtlbgknphckärtmf Ztbg Nwnmhtlhnmdm+ rncZrr chd PdZjshnm ZakZtedm jZmm-
903
03)0 Z BpZbjdm unm CdbZm Zkr Adhrohdk(9
BG2 – BG1 – BG1 – BG1 – BG1 – BG1 – BG1 – BG1 – BG1 – BG2
5 Dkdldmsd Bgdlhd Nadorsted LOV — Dpmrs Ikdss UdpkZf FlaG+ RstssfZps 1.04
5 N of Z m h r b g d Sd o a h m c t m f d m t m c h g od O d Z i s h n m r u d f d
PdZjshnmrsxo9 DkhlhmhdptmfrpdZjshnm
a FkdhbgfdvhbgsrpdZjshnm9
E E E E
E B B E B B ) E Bk
E Bk
Bk Bk
BgknpvZrrdprsnee
Chpdjsbgknphdptmf Nwxbgknphdptmf
0+1,ChbgknpdsgZm 0+1,ChbgknpdsgZm
Sgdplnkxrd
Uhmxkbgknphc BgknpvZrrdprsnee
OnkxldphrZshnm
Onkxuhmxkbgknphc OUB(
Cdp adh cdp Sgdplnkxrd unm 0+1,ChbgknpdsgZm dmsrsdgdmcd BgknpvZrrdprsnee vhpc adh cdp Nwx,
bgknphdptmf unm Dsgdm vhdcdp dhmfdrdsys tmc udpapZtbgs- CZlhs vhpc dhmd noshlZkd Mtsytmf cdr
Pngrsneer Bgknp tmc cdr Wvhrbgdmopnctjsr BgknpvZrrdprsnee dppdhbgs-
6 Dkdldmsd Bgdlhd Nadorsted LOV — Dpmrs Ikdss UdpkZf FlaG+ RstssfZps 1.04
5 N of Z m h r b g d Sd o a h m c t m f d m t m c h g od O d Z i s h n m r u d f d
03)2
Z PZchjZkhrbgd OnkxldphrZshnm unm Uhmxkbgknphc yt OUB9
Adhrohdk7
B N N B 1 B N
N N N
AdmynxkpZchiZk
E Bk E Bk Bk E Bk E E Bk E Bk Bk E Bk E
P B B B B ) B B B B P P B B B B B B B B P
E E E E E E E E E E E E E E E E
m m
Idssdmudpyvdhftmf MdadmpdZishnm(7
E B E E B E
E Bk E Bk
Bk B E Bk B E
P B B ) P B B E )
E B E B E
E E E E
Bk B E Bk B E
7 Dkdldmsd Bgdlhd Nadorsted LOV — Dpmrs Ikdss UdpkZf FlaG+ RstssfZps 1.04
5 N of Z m h r b g d Sd o a h m c t m f d m t m c h g od O d Z i s h n m r u d f d
2 HdssdmZaaotbg3 PdZfhdpdm yvdh PZchjZkd lhsdhmZmcdp+ hrs chd PdZjshnmrjdssd addmcds tmc rnlhs
chd Ahkctmf dhmdr Onkxldplnkdjökr Zafdrbgknrrdm-
Hdssdmudowvdhetme3 CZr adh chdrdp MdadmpdZjshnm fdahkcdsd PZchjZk jZmm vhd adh 1- lhs dhmdl
Lnmnldplnkdjök pdZfhdpdm-
a Adh cdp dmdpfdshrbgdm Udpvdpstmf Udpapdmmtmf( unm OUB dmsrsdgs BgknpvZrrdprsnee+ cdp rsZpj
jnppnchdpdmc Zte chd ;mkZfdmsdhkd vhpjs tmc Ztr Tlvdksrbgtsy,Fpömcdm Ztr cdl PZtbgfZr
ZtrfdvZrbgdm vdpcdm ltrr- ;tÜdpcdl dmsrsdgdm cZadh gnbgfheshfd tmc bZmbdpnfdmd Chnwhmd-
Ehmvdhr3 Hm cdp öakhbgdpvdhrd adh LökkudpapdmmtmfrZmkZfdm ctpbgfdeögpsdm PZtbgfZrvßrbgd
lhs BZkbhtlgxcpnwhc eögps BgknpvZrrdprsnee ytp Ahkctmf unm cdpydhs mhbgs udpvdpsaZpdl BZkbhtl,
bgknphc-
8 Dkdldmsd Bgdlhd Nadorsted LOV — Dpmrs Ikdss UdpkZf FlaG+ RstssfZps 1.04