Dechroming Salt - B - 3.4 - Engl

EU-Material Safety Data Sheet
According to Regulation (EC) No 1907/2006 (REACH)

Page: 1/11
Printing date: 26.07.2023 Reviewed on: 26.07.2023
Version: 3.4
Trade name: Dechroming Salt
1. Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
REACH Registration Number:

This product is a mixture. REACH Registration Numbers of the dangerous compounds see
section 3.
1.2 Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses:
Product for dechroming of rotogravure cylinder
1.3. Details of the supplier of the safety data sheet

Manufacturer/Supplier:
Graphische Technik und Handel Heimann GmbH
Pferdekamp 9
59075 Hamm Telephone-No.: +492381/97216-0 Fax: -2
Germany e-mail: info@heimann-hamm.de
Responsible Department:
Abteilung Druckchemie
1.4 Emergency telephone number:

Giftinformationszentrale Göttingen; Tel.-No.: +49551/19240
2. Hazards identification
2.1 Classification of the substance or mixture
Classification (Regulation (EC) No. 1272/2008)
Acute Tox. 4 H302
Skin Corr., 1B H314
STOT SE3 H335
Aquatic Acute 1 H400
Aquatic Chronic 1 H410
2.2 Label elements

Labelling (Regulation (EC) No. 1272/2008:
Hazard pictograms:
Signal word:
Danger
Hazard-determining components of labelling:
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Version: 3.4
Zinc chloride
Hazard statements:
H302 Harmful if swallowed.
H314 Causes severe skin burns and eye damage.
H335 May cause respiratory irritation.
H410 Very toxic to aquatic life with long lasting effects.
Precautionary statements:
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P301 + P330 + P331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
P303 + P361 + P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated
clothing. Rinse skin with water/shower.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P310 Immediately call a POISON CENTER or doctor/physician.
2.3 Other hazards
Results of PBT and vPvB assessment
PBT: Not applicable.
vPvB: Not applicable.
3. Composition/information on ingredients
3.1 Substances:
Not applicable.
3.2 Mixtures:
Mixture of the following components with additional harmless compounds.
Hazardous components (Regulation (EC) No. 1272/2008)
CAS-No. EC-No./ REACH Name Concen- Index-No. Classification

Registration- tration
No.
7646-85-7 231-592-0 / Zinc chloride 25 – 75% 030-003-00-2 Skin Corr. 1B, H314
01-2119472431- Aqu. acute 1, H400
44 Aqu. chron. 1, H410
Acute Tox. 4, H302
STOT SE3, H335
For the full text of the H-Statements in this section, see section 16.
4. First aid measures

4.1 Description of first aid measures:
General information:
Remove contaminated clothing immediately. When symptoms persist or in all cases of doubt
seek medical advice.
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Following inhalation:
Supply fresh air; consult doctor.
Following skin contact:
Remove contaminated clothing. Wash skin thoroughly with soap and water or use recognised
skin cleanser. Consult a doctor.
Following eye contact:
Rinse out with clean, fresh water for at least 10 minutes, holding the eyelids apart. Remove
contact lenses. Immediately call in ophthalmologist.
Following ingestion:
Rinse out mouth and give to drink a lot of water, avoid vomiting (risk of perforation). Call a
physician immediately. Do not attempt to neutralise. Never give to drink liquids if the injured
person is unconscious or has cramps.
Self-protection of the first aider:
It may be dangerous for a first-aid person to perform a mouth-to-mouth resuscitation. Wash
contaminated clothing thoroughly with water before removing or wearing gloves.
4.2 Most important symptoms and effects, both acute and delayed:
Irritation and corrosion, bronchitis, Cough, Shortness of breath, diarrhoe, nausea, vomiting,
cardiovascular disorders, collapse, metallic taste. Risk of blindness!
4.3 Indication of immediate medical attention and special treatment needed:

Treat symptomatically.
5. Fire-fighting measures
5.1 Extinguishing media:
Suitable extinguishing media:
Carbon dioxide CO2, dry powder, water spray, alcohol resistant foam.
Unsuitable extinguishing media: water jet.
5.2 Special hazards arising from the substance or mixture:

Not combustible. Ambient fire may liberate hazardous vapours (Zinc oxide, Hydrogen chloride
gas).
5.3 Advice for firefighters

Special protective equipment for firefighters:
In the event of fire, wear self-contained breathing apparatus. Prevent skin contact by keeping a
safe distance or wearing suitable protective clothing.
Further information:
Prevent fire extinguishing water from contaminating surface water or the ground water system.
Cool closed containers exposed to fire with water spray. Suppress (knock down)
dust/gases/vapours/mists with a water spray jet.
6. Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures
Advise for non-emergency personnel:
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Do not breathe dust, vapours, aerosols. Avoid substance contact. Ensure adequate ventilation.
Evacuate the danger area, observe emergency procedures, consult an expert.
Advice for emergency responders:
Protective equipment see section 8.
6.2 Environmental precautions:
Do not empty into drains. If the Product contaminates rivers and lakes or sewages inform
respective authorities.
6.3 Methods and materials for containing and cleaning up:

Observe possible material restrictions (see section 7.2 and 10.5). Take up dry and place in a
container for disposal according to local regulations. Clean preferably affected area with water.
Avoid generation of dust. Ensure adequate ventilation.
6.4. Reference to other sections: Indications about waste treatment see section 13.
7. Handling and storage

7.1 Precautions for safe handling
Precautions:
Avoid contact with eyes, skin and clothing. Avoid inhalation of dusts. Wear protective equipment
according section 8. Avoid release into the environment and let not reach groundwater, waters
or the canalization. Ventilate the working area and use an exhaust ventilation. Store the
substance only in the original container. Keep container tightly closed.
Advice on protection against fire and explosion:
No information available.
Advice for general hygiene at the workplace:

Smoking, eating and drinking should be prohibited in application area. Wash the hands before
taking a break and after end of work. Remove contaminated clothes.
7.2 Conditions for safe storage, including any incompatibilities:

Resistant materials are glass and plastic (PE, PP). Store in accordance with the particular
national regulations concerning storage water endangering substances. Keep container tightly
closed in a dry well-ventilated place. Store at +5 - +25°C. Do not store together with
incompatibility substances (see section 10) or food and beverages. Keep locked up.
7.3 Specific end uses

Apart from the uses mentioned in section 1.2 no other specific uses are stipulated.
8. Exposure controls/personal protection

8.1 Control parameters
Components with workplace control parameters:
Contains no substances with occupational exposure limit values.
Additional information:
Numerical data - if specified - are taken from the valid national list (Germany)
Recommended monitoring procedures:
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Methods for measurement of the workplace atmosphere have to correspond to the requirements
of norms DIN EN 482 and DIN EN 689.
Derived No Effect Level (DNEL):
Zinc chloride:
Worker DNEL, longterm, systemic effects, inhalation: 1 mg/m³
Predicted No Effect Concentration (PNEC):
No data available.
8.2 Exposure controls:

Appropriate engineering controls:
Technical measures and appropriate working operations should have given priority over the use
of personal protective equipment (see section 7.1). Ensure good ventilation. This can be
achieved by local exhaust or general exhaust air.
Appropriate assessment methods for verifying the effectiveness of the protective measures
taken include metrological and non-metrological investigative methods such as those described
in the Technical Rules for Hazardous Substances (TRGS) 402 and BS EN 14042 "Workplace
Areas, Guidance for the Implementation and Application of Procedures for Assessing Exposure
to Chemical and Biological Agents.".
Individual protection measures:
Protective clothing needs to be selected specifically for the workplace, depending on
concentrations and quantities of the hazardous substances handled. The chemical resistance of
the protective equipment should be enquired at the respective supplier.
Hygiene measures:
The product must be kept away from drinks, food and fodder. Remove contaminated clothing
immediately and wash before reuse. Wash the hands before taking a break and after end of
work. Avoid contact with the eyes and the skin. Do not eat, drink or smoke during work with the
product. Do not breathe in dust.
Personal protective equipment:
Eye/face protection:
Use safety goggles with side protection according to EN166: 2001.
* Hand protection:
For prolonged or repeated contact use chemical-resistant protective gloves (EN 374) (made of
nitrile or butyl rubber; thickness 0,3 mm; permeation time > 480 min).
Other protective equipment:
Wear protective clothing if skin contact can occur for this product. Working clothes must not
consist of textiles, which show a dangerous melting behaviour in case of fire.
* Respiratory protection:
Required when dust/vapours/aerosols are generated (filter A2B2E2K2-P3). Observe the wearing
time limit and the rules for the use of breathing apparatus (BGR 190).
Environmental exposure controls:
Do not empty into drains.
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9. Physical and chemical properties
9.1 Information on basic physical and chemical properties
Form: solid
Colour: white
Odour: odourless
Odour threshhold: no information available
pH: approx. 5 (100 g/l at 20°C)
Melting point : no information available
Boiling point/boiling range: no information available
Flash point: not applicable
Evaporation rate: no information available
Flammability (solid, gas): the product is not flammable
Lower explosion limit: not applicable
Upper explosion limit: not applicable
Vapour pressure: no information available
Relative vapour density: no information available
Relative density: no information available
Water solubility: soluble (20°C)
Partition coefficient n-octanol/water: no information available
Autoignition temperature: not applicable
Decomposition temperature: not determined
Viscosity, dynamic: not determined
Explosive properties: not applicable
Oxidizing properties: no information available
9.2 Other data
Bulk density: not determined
Ignition temperature: not combustible
10. Stability and reactivity

10.1 Reactivity
Corrosive in combination with water.
10.2. Chemical stability

The product is chemically stable under ambient conditions (room temperature). At high
temperatures and contact with water formation of hydrogen chloride.
10.3 Possibility of hazardous reactions

Exothermic reaction with (concentrated) alkalis, concentrated sulfuric acid and nitric acid (risk of
splashing), Strong oxidizing agents.
10.4 Conditions to avoid

Strong heating. Exposure to moisture: the product is hygroscopic.
10.5 Incompatible materials

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Alkalis, strong acids, base metals.
10.6 Hazardous decomposition products

In strong heating zinc oxide / hydrogen chloride is released.
11. Toxicological information

11.1 Information on toxicological effects
Acute oral toxicity:
LD50 (rat): 350 mg/kg (zinc chloride); RTECS
Symptoms: If ingested, severe burns of the mouth and throat, as well as a danger of perforation
of the oesophagus and the stomach.
Acute inhalation toxicity:
LCL0 (rat): 2 mg/kg, 10 min (zinc chloride); IUCLID
Symptoms: burns of mucous membranes, cough, shortness of breath. Possible damages:
damage of respiratory tract.
Acute dermal toxicity:
Skin corrosion/irritation:
Causes burns.
Eye damage/irritation:
Causes serious eye damage. Risk of blindness!
Sensitization to the respiratory tract/skin:
No sensitization effects known.
Gentoxicity in vitro:
No gentoxicity effects known.
Mutagenicity:
No mutagenicity effects known.
Carcinogenicity:
No carcinogenic effects known.
Reproductive toxicity:
No reproductive toxicity effects known.
Teratogenicity:
No teratogenicity effects known.
Specific target organ toxicity – single exposure:
May cause respiratory irritation.
Specific target organ toxicity – repeated exposure:
The substance or mixture is not classified as specific target organ toxicant, repeated exposure.
Aspiration hazard:
No aspiration toxicity classification.
* 11.2 Further information

Endocrine disrupting properties
The substance/mixture does not contain components considered to have endocrine disrupting
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Properties according to REACH Article 57(f) or Commission Delegated regulation (EU)
2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.
Systemic effects:
After uptake: metallic taste, drop in blood pressure, lachycardia, cardiovascular disorders,
diarrhea, circulatory collapse, disturbed electrolyte balance.
Causes impaired function of kidney.
Further information:
Handle in accordance with good industrial hygiene and safety practice.
12. Ecological information

12.1 Toxicity
Toxicity to fish:
LC50 (Danio rerio, zebra fish): 38 mg/l, 96 h
(IUCLID; Zinc chloride)
Toxicity to daphnia and other aquatic invertebrates:
EC50 (Daphnia magna; water flea): 0,33 mg/l, 48h
(IUCLID, Zinc chloride)
Toxicity to algae:
Toxicity to bacteria:
12.2 Persistence and degradability

12.3 Bioaccumulative potential

12.4 Mobility in soil

12.5 Results of PBT and vPvB assessment

PBT/vPvB assessment not available as chemical safety assessment not required/not
conducted.
* 12.6 Endocrine disrupting properties

The substance/mixture does not contain components considered to have endocrine disrupting
Properties according to REACH Article 57(f) or Commission Delegated regulation (EU)
2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.
* 12.7 Other adverse effects

Additional ecological information:
Do not let untreated reach waters, waste water (canalization) and soil. A harmful effect on water
living beings cannot be excluded. After neutralization, heavy metal precipitation and filtration,
the relatively small doing effect of resulted salts is only available. The toxic effect for fishes and
bacteria begins below pH-value = 6 and/or above pH-value = 9.
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General references:
The product is water endangering. Let not reach groundwater, waters or the canalization.
Discharge to the environment must be avoided.
13. Disposal considerations

Waste treatment methods:
Waste material must be disposed of in accordance with the Directive on waste 2008/98/EC as
well as other national and local regulations. Leave chemicals in original containers. No mixing
with other waste. Handle uncleaned containers like the product itself.
EWC-Code: 110105 (valid for the solution)
Uncleaned packaging:
Not orderly emptied containers and product residues are hazardous waste. Disposal must be
made according to official regulations.
EWC-Code 150110 (Packaging containing residues of hazardous substances or contaminated
by hazardous substances).
Cleaned packaging:
Only emptied and cleaned packaging are to let for recycling.
Recommended cleaning agent: water, if necessary with cleaning agent.
14. Transport information

Land transport: ADR/RID
14.1 UN Number 2331
14.2 UN proper shipping name: ZINC CHLORIDE, ANHYDROUS, MIXTURE
14.3 Transport hazard class(es) 8
14.4 Packing group III
14.5 Environmental hazards yes
14.6 Special precautions for user
Tunnel code: E
Air transport: ICAO-TI and IATA-DGR
14.1 UN Number 2331
14.5 Environmental hazards yes
Packing Instructions: 860
Sea transport: IMDG
14.1 UN Number 2331
14.5 Environmental hazards yes (Marine Pollutant)
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EmS: F-A, S-B
Segregation Group: 1, Acids
7, Heavy metals and their salts (including
their organometallic compounds)
14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not relevant
15. Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or
Mixture:
EC regulations:
Major accident hazard Legislation (96/82/EC):
Dangerous for the environment
9a
Quantity 1: 100 t
Quantity 2: 200 t
Occupational restrictions:
Take note of Dir 94/33/EC on the protection of young people and Dir 92/85/EEC for pregnant
women at work.
Substances of very high concern (SVHC):
This product does not contain substances of very high concern according to Regulation (EC) No.
1907/2006 (REACH), Article 57 above the respective regulatory concentration limit of ≥ 0.1%
(w/w).
Information according to 1999/13/EC about limitation of emissions of volatile organic
compounds (VOC-guideline):
The product contains no VOC.
Regulation (EC) No. 842/2006 on certain fluorinated greenhouse gases:
Does not apply.
Regulation (EC) No 1005/2009 on substances that deplete the ozone layer:
Does not apply.
National legislation:
Water pollutant class: WGK 3
15.2 Chemical safety assessment:

For this product a chemical safety assessment was not carried out.
16. Other information
16.1 Indication of changes:

Details marked with a * have been changed in regards to the former safety data sheet.
16.2 Abbreviations and acronyms:

Used abbreviations and acronyms can be looked up at www.wikipedia.org.
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16.3 Key literature references and sources for data:
Regulations:
REACH Regulation (EC) No 1907/2006, as last amended by Regulation (EU) 2017/1000
CLP Regulation (EC) No 1272/2008, as last amended by Regulation (EU) 2017/776
Regulation (EC) No 1907/2006, as last amended by Regulation (EU) 2015/830
Internet:
1http://www.baua.de
2http://publikationen.dguv.de
3http://dguv.de/ifa/stoffdatenbank
4http://www.gischem.de
5http://echa.europa.eu/en/candidate-list-table
16.4 Classification for mixtures and used evaluation method according to regulation (EC)
1207/2008 [CLP]:
See section 2.1 (classification). The product is classified and labelled according to the CLP
regulation.
16.5 Relevant H- and EUH-phrases (number and full text):

H302 Harmful if swallowed.
H314 Causes severe skin burns and eye damage.
H335 May cause respiratory irritation.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
16.6 Training advice:

Provide adequate information, instruction and training for the operators.
16.7 Additional information:

The information of this MSDS is based on the present state of our knowledge and on current
EU and national laws. The users working conditions are beyond our knowledge and control. It is
always the responsibility of the user to take all necessary steps in order to fulfil the demands
laid down in the local rules and legislation. The information in this MSDS is meant as a
description of safety requirements of our product; it is not to be considered as a guarantee of
the product´s properties. The information in this Safety Data Sheet is required pursuant to the
EC-directive 1907/2006/EC.
Department issuing data specification sheet:
Department of printing chemistry
Person to turn to:
Mr. Dr. Dittmar

Dechroming Salt - B - 3.4 - Engl

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EU-Material Safety Data Sheet

According to Regulation (EC) No 1907/2006 (REACH)

REACH Registration Number:

1.3. Details of the supplier of the safety data sheet

1.4 Emergency telephone number:

2.2 Label elements

CAS-No. EC-No./ REACH Name Concen- Index-No. Classification

4. First aid measures

4.3 Indication of immediate medical attention and special treatment needed:

5.2 Special hazards arising from the substance or mixture:

5.3 Advice for firefighters

6. Accidental release measures

6.3 Methods and materials for containing and cleaning up:

7. Handling and storage

Advice for general hygiene at the workplace:

7.2 Conditions for safe storage, including any incompatibilities:

7.3 Specific end uses

8. Exposure controls/personal protection

8.2 Exposure controls:

10. Stability and reactivity

10.2. Chemical stability

10.3 Possibility of hazardous reactions

10.4 Conditions to avoid

10.5 Incompatible materials

10.6 Hazardous decomposition products

11. Toxicological information

* 11.2 Further information

12. Ecological information

12.2 Persistence and degradability

12.3 Bioaccumulative potential

12.4 Mobility in soil

12.5 Results of PBT and vPvB assessment

* 12.6 Endocrine disrupting properties

* 12.7 Other adverse effects

13. Disposal considerations

14. Transport information

15. Regulatory information

15.2 Chemical safety assessment:

16. Other information

16.1 Indication of changes:

16.2 Abbreviations and acronyms:

16.5 Relevant H- and EUH-phrases (number and full text):

16.6 Training advice:

16.7 Additional information:

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