PROBLEMA 1

0
0 500
f(x) = − 0.00126
(𝑃_𝑡−𝑃_∞)/(𝑃_(0−) 𝑃_∞ )
ln(𝑃_𝑡−𝑃_∞)/(𝑃_(0−) 𝑃_∞ ) R² = 0.9799588
T/s [cis]/moldm -3 𝑃_𝑡−𝑃_∞
-0.5

ln [(Pt-P)/(P0-P)]
0 0.01679 0.00904 1 0
400 0.01406 0.00631 0.69800885 -0.3595235 -1
1000 0.01102 0.00327 0.36172566 -1.01686919
1600 0.00892 0.00117 0.12942478 -2.04465543 -1.5
P¥ 2100 0.00775
P0-P¥ 0.00904 -2
425.6°C
-2.5

ሾ𝐴ሿ− ሾ𝐴ሿ∞ 𝑃𝑡 − 𝑃∞
𝑛 = 𝑙𝑛 = −ሺ𝐾1 + 𝐾−1 ሻ𝑡 0
ሾ𝐴ሿ0 − ሾ𝐴ሿ∞ 𝑃0 − 𝑃∞ 0 f(x)500 1000 150
= − 0.0005235
-0.2 R² = 0.9998508541
𝐾_𝑒𝑞=𝐾_1/𝐾_(−1) =[𝑡𝑟𝑎𝑛𝑠]/[𝑐𝑖𝑠] =𝟐.𝟕𝟗 𝐾_𝑒𝑞=𝐾_1/𝐾_(−1)
-0.4
-0.6

ln [(Pt-P)/(P0-P)]
m = Kobs= 0.0013s-1 = -0.8
K1+K-1 -1
𝐾_1=2.79𝐾_(−1) -1.2

0.0013=2.79𝐾_(−1) 〖 +𝐾 〗 _(−1)= 〖 3.79𝐾 〗 _(−1) -1.4

𝐾_1=
-1.6 7.75𝑋10^(−
0.0013= 〖 3.79𝐾 〗 _(−1)
-1.8
𝐾_(−1)=4.525𝑋10^(−
-2
 0
0 500 1000
f(x) = − 0.00126961985366065 1500 2000
x + 0.0969528620104083 2500
R² = 0.979958864177441
-0.5
ln [(Pt-P)/(P0-P)]

-1

-1.5

-2

-2.5
T/s

0
0 f(x)500 1000 1500Column F x 3000Linear
2000 2500
= − 0.000523544215075663 3500(Column
4000 F)
-0.2
R² = 0.999850854110287
𝐾_𝑒𝑞=𝐾_1/𝐾_(−1)
-0.4
tiempo

-0.6
ln [(Pt-P)/(P0-P)]

-0.8
-1 m=Kobs=0.0005s-1 =K1 +K-1
-1.2
-1.4

𝐾_1=
-1.6 7.75𝑋10^(−5) 𝑠^(−1) 𝐾_𝑒𝑞=𝐾_1/𝐾_(−1) =9.53
-1.8
𝐾_(−1)=4.525𝑋10^(−4) 𝑠^(−1)
-2 𝐾_1=9.53𝐾_(−1)
0.0005=9.53𝐾_(−1) 〖 +𝐾 〗 _(−1)= 〖 10.53𝐾 〗 _(−1)