Acta mater. Vol. 45, No. 7, pp.

2789-2799,1997
~ 1997Acta Metallurgic Inc.
Pergamon Publishedby ElsevierScienceLtd
@ PII: S1359-6454(96)00379-5 Printed in Great Britain.All rights reserved
1359-6454/97 $17.00+ 0.00

NITROGEN STRENGTHENING OF A MARTENSITIC

STEEL: RELATION BETWEEN MICROSTRUCTURE AND
MECHANICAL BEHAVIOUR
C. FRANCE’, H. KL~CKER2, J. LE COZE2 and A. FRACZKIEWICZ2
‘Centre de RecherchesAscometal et Unimetal, 57360Amnevilleand 2Ecoledes Mines de Saint-Etienne,
158Cours Fauriel, 42023Saint-Etienne, Cedex 2, France

(Received 30 November 1995; accepted 28 Oclober 1996)

Abstract—Foursyntheticmartensitic steelscontaining differentnitrogen levelswere prepared by powder

techniqueand HIP. The base compositionof the four alloyscorrespondsto H13steelexceptfor the carbon
content. The nitrogen contents of the differentspecimensare, respectively,0.2, 0.5, 1.0and 1.5wtO/o.The
flow stresses and Young’s moduli of the four alloys were determined between room temperature and
600°C.The volume fractions of micron-sizeand manometric second-phaseparticles were determined as
a function of the total nitrogen content. The mechanicaland microstructural analyses showthat nitrogen
strengthening of martensitic tool steel is suitably described by Orowan’s mechanism. G 1997 Acta
Metallurgic Inc.

R&um&Quatre nuances d’un acier martensitique revenu contenant different taux d’azote ont et6
preparees par la technique des poudres et HIP. La composition de base des quatre alliages correspond
a celle de l’acier H13 except6pour le carbone. Les taux d’azote respectifs sent de 0.2, 0.5, 1.0 et 1.50/.
(massique). Les limites d’elasticity et modules de Young des quatre alliages ont &t&mesures entre
l’ambianteet 600°C.Les fractions volumiquesde precipit6smicrom6triqueset de pr~cipit~snanom~triques
ont W detennin~esen fonction du taux total d’azote. L’analysemecanique et microstructurale montre
que le durcissement par I’azote d’un acier martensitique revenu peut i%red4crit par le m+chanisme
d’Orowan.

Zusammenfassung-Vierverschiedene martensitische Stahle mit verschiedenen Stickstoffgehaltensind

durch Pudertechnikund HIP hergestelltworden. Die Basiskompositionder vier Legierungenstimmt fur
alle Elemente ausser Kohlenstoffmit der des H13-Stahl iiberein. Die Stickstoffgehaltesind 0.2, 0.5, 1.0
und 1.5Gew.O/O. Die Fliessgrenzeund das Elastizitatsmodulder vier Stahllegierungenwurden zwischen
Raumtemperatur und 600”Cbestimmt. Die Volmnengehalteder mikrometrischen und nanometrischen
Teilchen sind in Funktion des Stickstoffgehaltsbestimmt worden. Diese mechanischenund
mikrostrukturellen
Untersuchungen
zeigen,classdieStickstotl%artung
einesmartensitischen
Stahlsdurch
den MechanismsvonOrowanbeschriebenwerdenkann.

1. INTRODUCTION geneousmaterials are reported in the literature. The

During forging operations a die is submitted to best known are vibration techniques [3], bending
severe thermomechanical stresses: the temperature coupled with observation under a microscope[4]and
varies between 300 and 600”C,the strain rate locally measurement of residual strains by an X-ray
reaches 10-’ s-’ and friction causesconsiderablewear ‘ technique. These techniques give interesting results
of the die. Nitrogen strengthening of the die induces when applied to bimaterialsbut are rather difficultto
a sharp improvement of the theological parameters adapt to materials exhibiting a continuousvariation
within a surface layer of 20&300~m. Figure l(a) of mechanical parameters.
shows the well-known variation of nitrogen and The present work is concerned with the relation
carbon contents with the surface layer of a H13 steel between the mechanical behaviour (flow stress,
after salt-bath nitriding at 570”C [1]. The nitrogen Young’s modulus) and the local nitrogen content.
content decreases continuously from a maximum of Nitrogen strengthening was intensively studied in
about 2 wtO/O at the surface to the bulk initial value. ix-ironand in austenitic steels at low temperature by
Precipitation of nitrides causes diffusion of the Byrnes et al. [5]. In tempered martensitic tool
carbon atoms into the matrix [2]. steels, nitrogen strengthening has been much less
The variation of carbon and nitrogen contents explored [6].
within the surface layer gives rise to a continuous Four tempered martensitic homogeneous tool
variation of the theological parameters. Figure l(b) steels with different nitrogen contents were studied.
[1] shows the variation of microhardness within the Particular attention was paid to strengthening
surface layer. Many testing techniques for hetero- mechanisms by second phase particles.
2789
2790 FRANCE et al.: NITROGEN STRENGTHENING OF STEEL

- (a) 2. MATERIALSAND TESTINGTECHNIQUES

‘lTt ON
+C I 2.1. Synthetic materials

Four synthetic martensitic steels with different

nitrogen contents wereprepared by powdertechnique
and HIP. The powder particles were smaller than
500ym. The base composition of the four alloys is
givenin Table 1.This compositioncorrespondsto the
H13 steel except for the carbon content, which is
0.1 wt% instead of 0.4 wt%. The carbon of 0.1 wt%
was selected to simulate the carbon content of
0.1 wt% in a nitrided H13 steel as shownin Fig. l(a).
The nitrogen contents of the different specimensare,
respectively,0.2, 0.5, 1.0 and 1.5wtO/O.
-1-q \ In common practice, the H13-steelis heat treated
-o 100 200 300 for 30 min at 990”Cand tempered at 530°Cfor 4 h,
then at 600”Cfor 2 h 30min. After heat treatment the
grain size is 8 pm. In our experiments, the synthetic
alloys were heat treated and tempered to produce a
microstructure similar to that of the industrial
material.
The heat treatments were optimized on the
1.5wt% N alloy. All the synthetic materials were
heat treated at 11OO”Cfor 10min and tempered at
500”C for 2 h. Figure 2 shows micrographs of the
four synthetic alloys with tempered martensite
structures. Comparing Figs 2(a) and 2(d) showsthat,
when the nitrogen content increases, the structure
becomes more and more equiaxed (ferrite with
carbides). The grain sizes in the synthetic materials
(Table 2) are larger than in a H13 steel. SEM analysis
of the synthetic materials (Fig. 10) reveals micron-
ized precipitates (VC, CrN) which are not present in
the industrial material. Nevertheless,the microhard-
nesses of the three alloys with the highest nitrogen
400”~ contents (0.5, 1.0 and 1.5wtO/i) are in good
o 100 200 300 agreementwith the microhardnessin the surfacelayer
of the salt-bath treated H13 steel [Fig. l(b)]. In fact,
Fig. 3 shows a good correspondence between the
Fig. 1. (a) Variation of nitrogen and carbon contents within microhardness of the three synthetic materials and
the surface layer of a salt-bath treated H13 steel. (b)
Variation of microhardness within the surface layer of a the surface layer of the industrial alloy with the same
salt-bath treated H13 steel. nitrogen content. However,the microhardness of the
0.2 wt% N alloy is lower than the value at the same
nitrogen content in the surfacelayer. At this nitrogen
content an accumulation of carbides is observed in
the surface [2].
Table 1. The base composition of the four
alloys 2.2. Testing techniques
AlloywtyoN 2.2.1. Young’smodulus. Cylindrical specimens of
Com~osition 1.5 1.0 0.5 0.2 the four steelswith length 20 mm-gaugeand diameter
N 1.53 1.00 0.55 0.18 15mm were deformed elastically between room
c 0.09 0.095 0.104 0.100 temperature and 600”C. The deformation was
Mn 0.53 0.50 0.40 0.41 measured by strain gauges.
Si 0.99 0.98 0.935 0.94 2.2.2. Flow stress. Compression tests were per-
Ni 0.07 0.07 0.084 0.09
Cr 5.49 5.49 5.19 5.25 formed on cylindricalspecimenswith a gauge length
Mo 1.23 1.23 1.22 1.25 of 10mm and a diameter of 10mm at different
v 1.07 1.05 0.94 0.955 crosshead speeds (0.2, 2.0, 20, 50mm/min). The
s 0.007 0.006 0.009 0.010 displacements were measured by two inductive
P 0.009 0.009 0.010 0.010
displacement transducers.
 FRANCE et al.: NITROGEN S

Fig. 2. Micrographs of the four syntheticmaterials w

0.2wt% N; (b) 0.5wt~oN; (C’

For both test series (Young’s modulus and flow

stress) the temperature, measured by a thermocouple
welded onto the specimens, was held to within 1°
throughout each test. The specimenswere heated in
a vertical infra-red radiation furnace.
2.2.3. Hardness.The variation of Vickershardness
with temperature was measured on the 1.5 and
1.0wt% N alloys. The test temperature was
measured by a thermocouplefixedonto the specimen.
The heating rate was 12°C/min. A 10kg load was
applied for 12s.

Table 2. The grain sizes of the

synthetic materials
Number
of grains Grain size 400 [
wt% N analysed (pm) 0.0 0,5 1.0 1.5
1.5 50 7.3 wtOAN
1.0 50 8.0 Fig. 3. Microhardness of synthetic materials and the value
0.5 30 11.6
corresponding to the same nitrogen content in the surface
0.2 25 16.0 layer.
2792 FRANCE et al.: NITROGEN STRENGTHENING OF STEEL

2000 M+b)

>
)

%000 wWN
-— )
0 1.5
+ 1.0
● ().5
● 0.2
500 I I I I
100 I I

0 200 400 0 200 600

T(”C) T(°C)
(c) 1)
800

● 600

o 1.5
0 l.fJ &=400
+ 0,5
● f).z
200 IY$!%N
01.5
+ 1.0
0 I I

o 200 400 600

o 200 400 600 T(”C)
T(”C)
Fig. 4. (a) Variation of flowstress vs temperature for the four nitrogen contents. (b) Variation of Young’s
modulus vs test temperature for the four nitrogen contents. (c) Variation of normalized flow stress
IJW)/E(~ vs test temperature. (d) Variation of hardness vs test temperature for the 1.0and 1.5wtO/O N
alloy.

7.5

0 15
+ 1.0
● 0.5
● 02
6.5 I i 1 I

1,0 1,5 2,0 2.5 3.0 3.5

1000/T (K-j

Fig. 5. log(rr,)vs l/T for the four nitrogen contents.

 FRANCE et al.: NITROGEN STRENGTHENING OF STEEL 2793

(a)
250~

I m450
0550
0500
I
I X600
100
o 1 2
Wt%(N)

2000}’) 1
2tPc
200”C
300°c
MOec
450”C
500”C
1000 550°c

600°c
321 21i * Fea
1
500 L + CrN-
o 1 2 31!+..., VN-vc
wt% (N) , ....
11
i
0“-. :’
u
112
Fig. 8. (a) TEM photograph of the non-deformed
1.5wt% N alloy. (b) Diffraction pattern corresponding to
Fig. 8(a).

variation of flow stress CTY

with temperature is shown
for the four differentalloys.The nitrogen strengthen-
ing decreases with increasing test temperature. At
room temperature the flow stress of the 1.5wtO/O N
alloy is 640MPa higher than the flow stress of the
0.2 wt% N alloy, whereas at 600”C the four steels
have rather similar flow stresses. Figure 4(b) shows
that the Young’smodulus variesmore or lesslinearly
between room temperature and 600”C. Figure 4(c)
shows that the variation of normalized flow stress
uY(7’)/E(T)is small between room temperature and
400°C.Above 450°Ca steep decreaseof flowstress is
observed. Figure 4(d) shows that the variation of
2794 FRANCE et al.: NITROGEN STRENGTHENING OF STEEL

110
● Fea

112
Q 4

0;;
111
,?**”--””

. ...+:
b’

111
Fig. 9. (a) TEM photograph ofthenon-deformed
+ CrN-VN-VC

0.2wt%N alloy.(b)DiffractionPatterncorresponding
to Fig.9(a).
 FRANCE eCal.: NITROGEN STRENGTHENING OF STEEL 2795

Table 3. Classification of the micron-size second-phase

particles as a function of the mean radius R = (a+ b)/2
D(pm)
wtO/oN 0.125 0.25 0.5 0.75 1 1.25 1.5 Total
0.2 0.08 0.55 0.37 0.04 1.05
0.5 0.06 1.16 0.63 0.18 0.02 2.05
1 1.52 1.53 0.31 0.20 0.01 3.57
1.5 0.59 2.94 1.16 0.71 0.22 0.03 5.65

Table 4. Lattice parameters and formation energies of the

different meci~itates
Lattice parameters AG(500”C)
Precipitates (rim) (kJ/mol of N or C)
VN 0.4139 – 115
CrN 0.4169 – 53
Vc 0.4131+.4166 –92
Cr,zC< 1.066 –72

Fig. 10.SEM micrographsof the four alloys.

 2796 FRANCE et al.: NITROGEN STRENGTHENING OF STEEL

~ (a) - (b)
0.2w-MN 0.5 WI??N

■ ■1 1 1
0.0 0.5 1.0 1.5
0.5 1.0 1.5 d(y)
d(p)

~ (c)
l.oWl%N 1.5 Wt%N

0.0 0.5 1.0 1.5 0.0

-L L 0.5
&

1.0 1.5
d (p) d(v)

Fig. ll(a-d). Histogramsof micron-sizedsecond-phaseparticlesin the fouralloys.

variation of log(oY)with l/T is consistent with a nitrogen strerigthening is less efficient. Figure 6(b)
non-linear viscoplasticbehaviour shows the flow stress vs the total nitrogen content c.
(wt%) at different temperatures between 20 and
a,= ki?’’’exp(mkT)T). (1)
600°C.The curves fit best to a power law UY= k C!2,
The strain rate sensitivitym is about 0.01in the high but the 0.2 value obtained is smaller than the 0.5
temperature range and close to zero in the low obtained in classical low-temperature (no cross slip)
temperature range. Hereafter the deformation mech- strengthening models [5]. In order to clarify the
anism in the low temperature range will be studied in relationship between the microstructure and the flow
more detail. stress,the volumefractions of microscopic(JJ and of
3.1.2. Injkmce of total nitrogencontent on Young’s nanometric (J) precipitates were determined.
modulus and jlow stress. Figure 6(a) shows the
3.2. Microstructure
variation of Young’s modulus vs total nitrogen
content. Young’s modulus increases linearly with The microstructure of the synthetic alloys were
nitrogen content up to 1wtO/’.Above 1wt% N the analysedin order to determinethe volumefractions of

—
 FRANCE et al.: NITROGEN STRENGTHENING OF STEEL 2797
12
P
10
t / total

()~
o 1 2 Fig. 14. TEM photograph of deformed 0.2 wt% N alloy
showingOrowan loops.
Wt%(N)
Fig. 12.Variation of the different volumefractions vs total
nitrogen content. (arrow B on Fig. 7) are observed. The radius of the
semi-coherentprecipitatesis a fewnanometers. At the
micron-sizedand nanometric second-phaseparticles. interfaceof martensite laths CrZSC6, CrN, VN and VC
The volumefractions of nanometric precipitatesin the incoherent precipitates are observed.
four synthetic alloys were determined in order to Figure 8 shows a TEM photograph and the
clarify the hardening mechanism and the variation of corresponding diffraction pattern of the 1.5wtO/O N
flow stress with total nitrogen content. alloy. Figure 8(a) shows a micron-sizedCrN particle
It was not possibleto determinethe volumefraction (grey) and nanometer-sizeprecipitates (black spots).
of the nanometric precipitates from the TEM The micron-sizeprecipitate is incoherent whereas the
photographs. Figure 7 shows a TEM photograph of small nanometer-size particles are semi-coherent.
the non-deformed 1.5wt% N alloy. Electron diffrac- Figure 8(b) shows the diffraction pattern and one
tion and dark-fieldillumination were used to identify orientation relation between the Feetmatrix and the
the second-phase particles. Semi-coherentand inco- CrN–VN–VCparticles.The orientation relation is not
herent CrN, VN, VC and CrJ,C, second-phase perfect, because each particle is a cluster of several
particles are present. The CrZ,C6precipitates were CrN–VN–VCprecipitates.Figure 9(a)showsthe dark
easilyidentifiedby electrondiffraction.The diffraction fieldimage of the nanometer-sizeprecipitates insidea
patterns of CrN, VN and VC are very close and no martensite lath of the 0.2 wt% N alloy (white spots)
distinction was made between these particles. and Fig. 9(b) gives the corresponding diffraction
Intergranular and transgranular precipitation is pattern. The orientation relation between the
observed. Inside the martensite laths semi-coherent precipitates and the Feixmatrix is quite simple. The
CrN, VN and VC single precipitates (arrow A on clusteringof the precipitates is less important than in
Fig. 7) and clusters of the same type of precipitates Fig. 8.
As it was not possible to determine the volume
fraction of the nanometric precipitates from the TEM
photographs, the volume fraction of nanometric
second-phaseparticles was estimated as follows:

&
. the volumefraction of micron-sizesecondphase
200”C
particles~, was measured by SEM;
300”C . the volume fraction of nanometer-sizedprecipi-
400”C tates (~,) was determined as the difference
4 ●
450”C between the calculated total volume fraction of
500”C precipitates and the volume fraction ~,.

~5’OOc

/-’---- ’OOOc Table 6. Increment in flow stress, radius of

nanometric precipitates and distance betweenthe
500 Orowan looIJsfor the four synthetic alloys
0.1 (),2 ( wtO/oN 0.2 0.5 1.0 1.5
in
f A~.,P(MPa) 738 978 1168 1288
Fig. 13. Flow stress vs square root of volume fraction of 1 (rim) 20.6 15.5 13.0 11.8
nanometric second-phaseparticles.
r (rim) 1.6 1.5 1.6 1.6

.—.—
- ———
2798 FRANCE et al.: NITROGEN STRENGTHENING OF STEEL
3.2.1. Total volume fraction of second phase
particles. Table 4 gives the formation enthalpies of
the different precipitates [8]. The lowest formation
enthalpy corresponds to the VN precipitates. The
critical radii for precipitation (Table 4) are calculated
with the surface ener@es given in Table 4. The
smallest radius corresponds to VN and CrN
precipitates. Assuming that the precipitates with the
lowest critical radius appear first, the total volume
fraction of precipitates is calculated by the following
assumptions:
● all the nitrogen atoms are bonded either to Cr
or to V to giveCrN and VN in the ratio [Cr]/M;
● the carbon atoms form Cr,,C, and VC with the
remaining Cr and V in the ratio [Cr]/M;
. the carbon not used to form CrZ,C6or VC forms
MoC;
● [Cr]and M are the number of atoms of Cr and
V per unit volume.
3.2.2. Micron-sized second-phaseparticles. The
distribution of micron-sized second-phase particles
( >0.1 pm) was ascertained on the SEM. Figures
IO(a-d) show typical micrographs of each steel. The
size distribution of second-phase particles was
determined from four differentmicrographs for each
steel. The micron-sizedprecipitates (black and white
spots on Fig. 10)were assumed to be spheroidal with
axes a and b (measured in the observed section).The
precipitates were analysed by a micro-probe (under
10kv) on the SEM and by dark-fieldillumination on
the TEM. There are essentially micron-sized CrN,
VN, VC and CrZjCCprecipitates. Table 5 gives a
classification of the micron-size second-phase par-
ticlesas a function of the mean diameter D = (a+ b).
The corresponding histograms are shown in Figs
1l(a-d). The maximum D value varies from 0.75 pm
for the 0.2 wt% N alloy to 1.5~m for the 1.5wt% N
alloy. The scatter of the particle-size distribution
increases with increasing nitrogen content. The total
volumefraction of micron-sizedprecipitatesincreases
rapidly with total nitrogen content as is shown in
Fig. 12.
3.2.3. Nanometric second-phase particles. The
volume fraction of nanometric precipitates (fv) is
determined as the differencebetweenthe total volume
fraction of precipitates (calculated previously) and
the measured volume fraction fp of micron-sized
second-phase particles.
Figure 12 shows the variation of the different
volume fractions of precipitates vs total nitrogen
content. The volume fraction of micron-sized
second-phaseparticles (f~) increasesmuch more with
total nitrogen content than the volume fraction of
nanometric precipitates (fq). In the 0.2 wtO/O
N alloy,
L equals 1.0vol.% andfi 1.87VOIV.,whereas in the
1.5wt% N alloy, f, equals fi(5.7 VOI%).Thus, the
volume fraction of nanometric particles grows very
slowly with the total nitrogen content. A deviation
from linearity is observed beyond 1wt% N.
4. DISCUSSION
4.1. Variationofjlow stresswith temperatureand total
nitrogen conlent
At low temperatures (<400°C), the variation of
normalized flow stress with temperature is small for
all nitrogen contents [Fig. 4(a)]. This behaviour is
typical of dispersion hardening (by carbides and
nitrides) [9] and dislocation glide controlled defor-
mation. For all strengthening mechanisms based on
dislocation glide,the flowstressis proportional to the
square root of the volume fraction of strengthening
particles. Thus a proportionality between the flow
stress and the square root of nitrogen content might
be expected here [10]. The slow variation of flow
stress with the total nitrogen content (o}= k Cfiz)
instead of (crY = k C{s) can be explained by the
microstructural analysis. Figure 13 shows the flow
stress vsf705.At low temperatures (< 300”C)the flow
stress varieslinearly withf?os.In viewof theseresults,
only the nanometric particles are expected to
strengthen the material. Nitrogen increases very
slowlywhen the total nitrogen content increases,and
nitrogen strengthening is less efficient than below
1 wtYo N.
4.2. Deformationmechanism
The TEM investigations have shown that nano-
metric particles are semi-coherent with the matrix
(Figs 8 and 9). Figure 14 shows a TEM photograph
of a 0.2 wt% N specimenplastically deformed up to
O.lYO.Dislocation loops around nanometer size
precipitates are observed (arrows A). The distance
betweenthe dislocation loops is about 30 nm, Table 6
gives the values of the measured increment in flow
stress A7.,Pas a function of the nitrogen content for
the four steels at room temperature. Assuming an
Orowan strengtheningmechanism, the characteristic
distance 1 between the dislocation loops is given
classicallyby the following formula [6]:
a=~ (2)
exp
where AZ,.P,G and b are, respectively,the measured
increment in flow, the matrix shear modulus at the
temperature under consideration and the matrix
Burgers’ vector. The corresponding values of A are
given in Table 6. Good agreement with the
experimental value of about 30 nm is observed. The
mean radius of the strengthening second-phase
particles is related to the volume fraction f, and the
distance between dislocation loops by [6]:
L
r=1.25(27r/3fq)’/’” (3)
The corresponding values in Table 6 are in good
agreement with the radii observed on the micro-
graphs. Thus, strengthening is due to the Orowan
mechanism on the small nanometric second-phase
particles. In the martensitic steel here observed, the
 FRANCE et al.: NITROGEN STRENGTHENING OF STEEL
semi-coherent precipitates are not sheared. The
hardening due to the micrometric precipitates is
negligible[7].
5. CONCLUSIONS
The nitrogen strengthening of a tempered marten-
sitic tool steel has been studied between 20 and
600°C.Syntheticalloys representative of the different
zones of a nitrided layer were prepared. The studies
of these materials have given:
. The relation between theological parameters
and total nitrogen content. Nitrogen strengthen-
ing of the H13 steel is most efficient below
1 wt’YoN.
● The temperature dependenceof flow stress, The
existenceof two distinct temperature ranges has
been shown. In the low temperature range,
deformation is controlled by dislocation glide.
Nitrogen strengthening of H13 steel is very
efficientat temperatures less than 400°C.Above
400°C, when deformation is controlled by
climb, the strengthening is much less efficient.
. The relation betweenflowstressand microstruc-
ture. The flow stress varies linearly with the
square root of nanometer-sizedparticle volume
fractions. The strengthening is controlled by
Orowan’smechanism. The semi-coherent pre-
cipitates are not sheared. To quantify the
strengthening, the nanometric second-phase
particle volume fraction was determined as a
function of the total nitrogen content.
. The relation between the microstructure and
total nitrogen content. The volume fraction of
micron-size second-phase particles increases
2799
faster than the volume fraction of nanometric
precipitates when the total nitrogen content
increases.This result‘explainswhy the strength-
ening is more efficient at low nitrogen levels.
Moreover the micron-size second-phase par-
ticles will cause damage when the die is
submitted to plastic strains. So, a compromise
can be found at the 1wtO/O N alloys between
increasing the volume fraction of nanometric
precipitates and limiting the volume fraction of
micron-sizedprecipitates.
Acknowledgements—This workwas supportedby a grant
from the A.N.R.T. (France)Number 286/92and from
ASCOMETALResearch and Development Division
(France).
REFERENCES
1. France,C.,Th&sede l’Ecoledes Minesde Saint-Etienne,
1996.
2. Leroy, C., Thise de l’Ecoledes Mines de Nancy, 1983.
3. Mihara, T. and Obata, M., Experimental Mechanics,
1992, March, 30.
4. Nix, W. D. Metal Trans., 1989,20A, 2217.
5. Byrnes,M. L. G., Grujicic, M. and Owen, W. S., Acta
metall., 37B, 1853.
6. Simcoe,C. R., Nehrenberg,A. E., Biss,V. and Coldren,
A. P., Trans. Am. Soc. Melals 61, 835.
7. Martin,J. W., Micromechanisms in Particle-hardened
Alloys, ed. J. Wilson. Cambridge University Press,
Cambridge,1980.
8. Smithhells, C. J., Metal Reference Book IV, Vol. 2,
Butterworths, London, 1967.
9. Nicholson, R. B., in Proc. of Conf. on the Effec~
of Second-phase Particles on the Mechanical Properties
of Steel. The Iron and Steel Institute, London,
1971.
10. Chilton, J. M. and Kelly, P. M., Acta metall., 1968, 16,
637.