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RTD-1958 Spalding PDF
RTD-1958 Spalding PDF
RTD-1958 Spalding PDF
D. B. SPALDING
Imperial College of Science and Technology, London
If the tracer is not prevented from diffusing upstream of the injector plane, the mean residence-
time exceeds the above by an amount equal to the effective longitudinal diffusion coefficient in
the inlet pipe, divided by the square of the velocity in that pipe.
R&sum&L’auteur montre que le temps de contact moyen d’un traceur introduit dans un
fluide incompressible de complexite arbitraire, lors de l’ecoulement permanent, est &gal au
rapport du volume du recipient compris entre les plans d’entree et de sortie et de la vitesse
d’ecoulement volumique, ir condition d’empecher la diffusion en amont du plan d’injection.
Les vitesses et coefficients effect& de diffusion peuvent varier avec la position, mais ne varient
pas en for&ion de la concentration ou du temps.
Si le traceur diffuse en amont du plan d’injection, la dur6e de contact est superieure B celle
d&rite precedemment dune quantite &gale au coefficient effectif de diffusion longitudinale dans
la tubulure d’entree divise par Is car& de la vitesse dans ce tube.
Wenn der Indikator von der Injektionsstelle stromaufwiirts diffundieren kann, wird die
mittlere Verweilzeit gr6sser als die oben angegebene, und zwar urn einen Betrag gleich dem
effektiven Liingsdiffusionskoeffizienten im Eintrittsrohr, geteilt durch das Quadrat der Gesch-
windigkeit in diesem Rohr.
74
A note on mean residence-times in steady flows of arbitrarycomplexity
m
Integrating the equation from 8 = o to
V - - ,2 0 = co, (3) becomes
m m
1
c m -co=V(DV c&?)-V(q cd@ (4)
& s s
0 0
s
0
c2 de pulses) of tracer is injected, the concentration is
uniform throughout the vessel.
75
D. B. SPALDING
Theorem 2
s s
00 co
s
cc
a9dc = [6’ c]; - c dB = 0 - I. (9) irrespective of the flow pattern in the vessel.
s
B=O 0 There may even be regions of recirculation in
the vessel where the streamlines are closed.
N.B. (In order that the symbols within the
Changes in flow pattern will introduce changes
square bracket shall represent zero at the upper
in the shape of the curve of Fig. 2, but we have
limit, c must fall off more rapidly than l/8. It
not had to make any assumption about this shape,
always does so ; for otherwise I would not be
being concerned only with the position of the
finite).
centroid of the area beneath it.
Putting, for convenience,
co 4. THE CASE OF A PERMEABLE INLET
J E c&‘dB, (10) PLANE
s
0 We now carry out the corresponding analysis
for the case in which the “sieve ” is absent
equation (8) now becomes
from the inlet duct, so that tracer material is
V(DVJ) - V(qJ) +I = 0 (11) free to diffuse upstream.
Now J1, if we take for clarity a plane just where x = distance along the inlet duct in the
upstream of 1, is evidently zero. Therefore stream direction.
The solution of this equation, with the boundary
vJ,=IV (13) conditions I = S/v at x = xi (inlet plane), and
I = 0 at x = - co (far upstream), is
Reverting to the earlier notation, this can be
written as x1 < x : I = (S/v) exp [v (8 - q)/D,A,] (17)
A note on mean residence-times in steady flows of arbitrary complexity
This means that I falls off exponentially in an This is Theorem 3. The second term may be
upstream direction. interpreted as a correction to the “ simple
formula,” necessary because some of the tracer
material lengthens its residence-time by diffusing
Determination of Q, : Theorem 3 upstream before being swept downstream.
The previous analyses leading to (11) is still Alternatively D,A12/v could be treated as a
valid; the solution for J, will be seen to differ correction which must be added to the vessel
however. For ease of physical understanding, we volume V to account for the permeability of the
will continue to regard I as a heat input term ; inlet plane.
no rigour is lost thereby. 5. DISCUSSION
The total “ heat input rate ” now contains
The result contained in equation (20) may be
two terms, one for the vessel as before, namely
regarded as a generalisation to flows of arbitrary
SV/v, and another for the inlet duct. The latter
PI complexity of a result reported recently by
must be written as I A, dx. Introducing LEVENSPIEL and SMITH [2], for the case of
I constant-area flow with a uniform diffusion
equation (17), valid inmthis region, we have : coefficient.
Xl However, the suggestion of these authors
321
that, in complex flows, an average value of
I A, dx = (SAX/v) exp [V(8 - xl)/D,A,) dx
diffusion coefficient should be used in the
s s
-CO -a’ residence-time correction, appears to be ill-
= S D,A,2/v2 founded : it is the diffusion coefficient in the
(18)
inlet pipe which matters. This will often be
The solution of (11) is therefore much smaller than the average.
It also appears that the time-correction
z,J, = S V/-J + SD, At/v2 (19) increases as the square of the intake area. This
means that the effect of an impermeable injector
Introducing the original notation as before,
plane can always be obtained by reducing the
a new expression for the mean residence-time is
cross-section .of the inlet duct in proportion to
obtained, namely
the other dimensions of the vessel. In many
V D,A: practical cases therefore the correction will be
em=-+7 entirely negligible.
V
6. REFERENCES
[l] DANCKWERTS P. V. Chem. Engng. Sci. 1957 2 1.
[2] LEVENSPIEL 0. and SMITH W. K. Chem. Engng. Sei. 1957 6 227;
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