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Material Specification ES-X63131: Title
Material Specification ES-X63131: Title
Material Specification ES-X63131: Title
SPEC NO.
MATERIAL SPECIFICATION ES-X63131
Contents
Page
1. Scope ··············································· 3
2. Classification ······································ 3
3. Definition ··········································· 3
4. Requirements ····································· 4
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SPEC. NO 3/22
ES-X63131
1. Scope
This specification is applied to the quality of paint film on rigid thermoplastic parts.
Remark: Normative references and specifications are shown in applying SPECs and
standard list ( Page 21 ).
2. Classification
The paint films are classified into four groups according to their applications, and identified as
the suffix PD-0, PD-1, PD-2 or PD-3 as shown in Table 1.
Table 1
Symbol Application
PD-0 Paint film for high temperature part
Paint film for interior part
PD-1 Paint film for standard temperature part
PD-2 Matte paint film
Paint film for exterior part
PD-3 Standard paint film
Remark: Symbol “M” such as PD-0M shall be added to the part required high wear resistance,
and it shall be indicated in the drawing.
Examples: Ash tray, knob, wheel cap, etc.
M : Symbol “H” such as PD-0H shall be added to the part required sunscreen cream
resistance , and it shall be indicated in the drawing.
Examples: Door switch panel, Paddle shift, etc.
3. Definition
3.1 Paint film for interior part
The paint film on plastic product that can be seen directly from the seated position.
(1) Paint film for high temperature part
Paint film on part that is subject to direct sunshine through window glass and reach a
high temperature, such as upper surface of instrument panel, door trim, and rear shelf.
(2) Paint film for standard temperature part
Paint film other than (1) above.
4. Requirements
4.1 General requirements
Unless otherwise specified, the paint film composition and thickness for PD-2 and PD-3
shall conform to Table 2.
Table 2
N Basecoat Basecoat
Color Primer Clearcoat
(Color or First) (Mica or second)
2 coat solid color
12 µm or more
2 coat metallic 5 µm or more (1) - 25 µm or more
P (10 µm or more)(4)
or pearl color
N 15 µm or more (2) 15 µm or more 25 µm or more
3 coat pearl color 15 µm or more 12 µm or more
P 5 µm or more (1) 25 µm or more
(10 µm or more) (7 µm or more)(4)
(4)
2 coat
Hiding
3 coat 18 µm or less(5) 5.5
N power
4 coat
Appearance: Appearance:
No excessive color No excessive color
: 26
difference as compared :0 5 difference as compared
5
with color sample. 17 1 with color sample.
2 coat 5 /
/0 Color difference with color
Color tone 3 coat 19 5.6
N 20 sample:
pearl i
t Angle 45°; 2.5 or less
a
n
g Angle 25°; 5.0 or less
I
o (or Angle 15°; 8.0 or less,
i
R In case of using CM-512m2)
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SPEC. NO 5/22
ES-X63131
Table 3 (Continued)
Requirement Test
Item
PD-0 PD-1 PD-2 PD-3 method
These colors have priority to
visual evaluation, and color
difference should be
reference.
3 coat
Appearance: No excessive
Color tone metallic - 5.6
color difference as compared
N 4 coat
with color master.
Color difference with color
master:
Angle 45°; 4.0 or less
Angle 25°; 6.0 or less
2 coat Shall be equal or
Gloss 3 coat superior to the standard 88 or more 5.7
4 coat sample.
L value:
35 or less
Part -
S value:
(6) 50 or less
5.8
WS value L value:
Flat 7 or less
-
panel S value:
37 or less
Adhesion Classification 2 or better 5.9
Pencil hardness(7) B or harder HB or harder 5.10
Tack free resistance Rating 4 or better 5.11
Appearance: No peeling or crack of the paint film.
Impact resistance 5.12
Adhesion: Classification 2 or better
Plane
No exposure of substrate.
abrasion
Curved
Wear surface No exposure of substrate.
5.13
resistance abrasion
M Sunscreen
cream No exposure of substrate.
resistance 6
:25
Appearance: Rating 1 or better:0
Heat cycle resistance 15 5.14
Color difference: 2.0/or17 less
(8) 05
/
Gloss retention 19: 90 % or more
Humidity resistance 20
Adhesion: Classification 2 or better
5.15
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SPEC. NO 6/22
ES-X63131
Table 3 (Continued)
Appearance:
Rating 1 or better
Color difference:
2.0 or less
Water resistance - 5.16
Gloss retention (8):
90 % or more
Adhesion: Classification 2
or better
Appearance: Rating 1 or better
Chemical resistance 5.17
Color difference: 2.0 or less
Appearance:
Rating 1 or better
Acid resistance - 5.18
Color difference:
2.0 or less
Alkali resistance - Rating 1 or better 5.19
Appearance: Rating 1 or better
Color difference: 2.0 or less
Heat resistance 5.20
Gloss retention (8): 90 % or more
Adhesion: Classification 2 or better
No excessive
discoloration, color
Urethane resistance - 5.21
transfer to a gauze, or
dissolving of the paint film.
Appearance: Appearance:
Rating 1 or better Rating 1 or better
Color difference: Color difference:
[For Blue and Red] [For Blue and Red]
4.5 or less 3.5 or less
[Except Blue and Red] [Except Blue and Red]
3.0 or less 2.0 or less
Accelerated (8)
Gloss retention : Gloss retention (8):
weathering 5.22
90 % or more 90 % or more
resistance
Adhesion: Classification 2 Adhesion: Classification 2
or better or better
Cycle test: No crack of the
paint film.
Wear resistance:
No exposure of
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SPEC. NO 7/22
ES-X63131
Table 3 (Continued)
Requirement Test
Item
PD-0 PD-1 PD-2 PD-3 method
Appearance:
Rating 1 or better
Color difference:
[For Blue and Red]
4.5 or less
[Except Blue and Red]
Weather resistance - 3.0 or less 5.23
Gloss retention (8):
90 % or more
Adhesion: Classification 2
or better
Cycle test: No crack of the
paint film
Note (5) Hiding power of specific color can be the following value if workability in the
N
production line is acceptable.
Metallic color :30 µm or more
Solid color: 40 µm or more
O The second basecoat of pearl color, 4 coat and 3coat metallic color is not specified
the hiding power
(6) This requirement is applied to a spoiler only.
N (7) The specific color shown in Table 4 depends on this table.
(8) If the paint film is matte coating, this item shall be omitted.
Table 4
Color number Requirement Test
N (Color name) PD-0 PD-1 PD-2 PD-3 method
CMP10062 (RED(P)) - B or harder 5.10
5. Test methods
5.1 Standard condition of test room
The test shall be conducted in a state of 23±2°C and 50±5 % relative humidity (hereinafter
called “room temperature”), free from direct sunshine, and nearly free of gases, dust, vapor,
and air circulation.
5.4 Appearance
Visually evaluate the appearance of paint film under a specified lighting.
Inspection method: Test specimen shall be viewed from distance 250 - 300 mm by
eyesight 0.8 min.
Lighting: Scattering daylight
The ray of light coming from northern window to the location 1,000 mm above
floor, free of direct sunshine, during the time from 3 hours after sunrise to 3
hours before sunset.
Illumination: Illumination should be 500 lx min. to the effective plane uniformly.
5.7 Gloss
Shall conform to ISO 2813 or JIS K 5600-4-7.
When the paint film has directionality, measure from the right-angled direction each other
by the same position, and average those.
If the completed part has grain, use the flat surface plate that is painted by the same
material and process as the completed part.
Measurement angle of the light: 60°
Number of measurement: 5 times
Report: the average value of 5 measurements
Front
Fig. 1
5.9 Adhesion
Shall conform to ISO 2409 or JIS K 5600-5-6.
The width of parallel lines: 2 mm
Adhesive tape: [Width] 24mm
[Adhesive strength] 2.94 N/10mm min.
and the cratering of paint film by pressure is not the object. Remove the carbon
powders by using an eraser so as not to flaw the paint film at the tested portion,
and observe at right angles with the rubbing direction from an angle of
45 degrees to the paint film surface visually and take the flaw discriminable as
the "rubbing flaw".
Fig. 2
Table 5
Rating Evaluation standard
5 Texture trace not at all noticeable
4 Texture trace barely noticeable but hardly conspicuous
3 A little but clearly noticeable
2 Texture trace excessive
1 Texture trace very excessive and ugly
Table 7
Canvas (friction belt) stroke 120 mm
Friction rate 30 cycles/minute
Material Normal canvas JIS #10 (11) or equivalent
Friction belt
Width 20 × 20 mm
Weight 1,000±1 g
Except PD-3: 1,000
Number of rubbing cycle
PD-3 : 10,000
Test stand
Test specimen
Fig. 3
Test specimen
M
Canvas (Friction cloth)
Weight
Fig. 4
Table 8
Canvas (friction belt) stroke 200 mm
Abrasion speed 60 cycles/minute
Test weight 500±1 g
Material Normal canvas JIS #10 (8) or equivalent
Friction belt
Width 40 mm
Table 9
Classification Symbol Solution Test cycle
PD-0
PD-1
Dry - 500
PD-2
PD-3
PD-0
Man-made sweat (12) Canvas shall be 100
PD-1
immersed in solution
Unleaded gasoline 50
for 30 seconds.
Wet Water 100
PD-2
Apply 2 g of wax
PD-3 Mitsubishi genuine
uniformly to friction 25
clean wax
surface of canvas.
: 26
5
Note (12) Man-made sweat shall be consisted:0of 8 g of sodium di-phosphate 12
5
hydrate, 8 g of sodium chloride,178 1g of acetic acid, and 1 liter of deionized
/
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water. 9/ 1
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SPEC. NO 13/22
ES-X63131
Table 10
Symbol Detail of 1 cycle Number of cycle
PD-0
Shall conform to Section 4.12.1 in ES-X83239. 3
PD-1
PD-2 Shall conform to Section 3.3, 3.4, or 3.5 in
5
PD-3 ES-X83244.
Table 11
Symbol Test temperature Test humidity Test time
PD-0
168 hours
PD-1 95 % R.H.
50±2°C
PD-2 or more
240 hours
PD-3
Table 12
Water Test temperature Test time
Distilled water or ionized water 40±2°C 240 hours
Table 13
Symbol Test method
PD-0 Shall conform to Section 4.16 in ES-X83239.
PD-1 Only glass cleaner and neutral detergent shall be used.
Table 14
Chemical Concentration Test temperature Test time
Sulfuric acid 5 wt % 50±2°C 3 hours
Table 15
Concentratio Volume Test Test
Chemical Container
n of droplet temperature time
Sulfuric acid 20 wt % 0.2 ml 80±2°C 1 hour Note (9)
Note (9) Stainless container with a lid shall be used. Drop some of water as
shown in Fig. 5 to prevent the evaporation of Sulfuric acid.
Water
Sulfuric acid,
or Hydrochloric acid
Fig. 5
Table 17
Volume Test Test
Chemical Concentration
of droplet temperature time
Sodium hydroxide 0.1 N 0.2 ml 55±2°C 4 hours
Table 18
Symbol Test temperature Test time
PD-0
Shall conform to Section 4.12.3 in ES-X83239.
PD-1
300 hours
PD-2
80±2°C
PD-3
Table 19
Symbol Radiant exposure
PD-0 126 MJ/m2 (300 to 400 nm)
PD-1 84 MJ/m2 (300 to 400 nm)
Table 20
Symbol Test time
PD-0 500 hours
PD-1 300 hours
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SPEC. NO 18/22
ES-X63131
Table 22
Exposure district Exposure angle Exposure period
The area in Florida, USA, or
Okinawa, Japan, where the
5 degree toward south 24 months
annual ultraviolet irradiation
is more than 250MJ / m2.
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SPEC. NO 20/22
ES-X63131
6. Report
Supplier shall submit a specification confirmation test report which proves that the material
satisfies all the items required in this specification to the Purchasing Department, affected
Designing/Engineering Department, and/or Material Engineering Department prior to the start
of mass production delivery. In addition to the above mentioned, the supplier shall also submit
to the affected Designing/Engineering Department its own test report of the specification
(test results, not nominal values), the processing conditions, the material designation, and trial
production parts or materials for MMC evaluation.
7. Designation in drawing
This specification shall be designated in drawings as follows.
Material
Paint film - For rigid thermoplastic parts
ES-X63131 PD-0 #N
8. Supplier‘s responsibility
Prior to making any change in the properties, composition, construction, color, or processing
of the material originally approved under this specification, whether or not such changes affect
the material‘s ability to meet the specification requirements, the supplier shall notify affected
Designing/Engineering Department of the proposed changes through the Purchasing
Department and obtain written approval.
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ES-X63131 21/22
TEXTILES - TESTS FOR COLOUR FASTNESS - PART B06 : COLOUR FASTNESS AND
ISO105-B06 04 AGEING TO ARTIFICIAL LIGHT AT HIGH TEMPERATURES :
PAINTS AND VARNISHES - ARTIFICIAL WEATHERING AND EXPOSURE TO
ISO11341 04 ARTIFICIAL RADIATION - EXPOSURE TO FILTERED XENON-ARC RADIA
NUMBER CL NAME
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