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(Term symbol)
Johnson Naat
Atom sederhana serupa helium yang mengandung 2 e dan inti
dengan muatan +ze (H-, He, Li+...)
Jika inti dianggap terpateri pada titik asal sistem koordinat maka
posisi kedua elektron dapat dicirikan dengan 6 koordinat
Setiap e 3 koordinat, maka Persamaan Scrodingernya adalah:
Penyelesaian atom Hidrogen tidak dapat diterapkan pada atom
polielektron, sekalipun pada atom poliatom sederhana seperti
helium (1 inti dan 2 e gaya tolak antar elektron tdk dpt
dipecahkan secara eksak
Adanya hal tersebut makan menimbulkan pendekatan dalam
mengevaluasi nilai energi sistem dan fungsi gelombang, diantaranya:
1. Teori gangguan (Schrodinger),
2. Pendekatan medan Swapanggah (self consistent field, SCF) dari
Hartree-Fock
3. Metode Variasi
Term symbol
Term Symbol
• Term simbol digunakan untuk melambangkan keadaan kuantum
dan tingkat energi yang berbeda untuk sistem banyak elektron yang
dengan konfigurasi elektron yang sama
• L= bilangan kuantum momentum sudut orbital total
• S= bilangan kuantum spin total
• J= bilangan kuantum sudut total
Faktor multiplisitas: suatu keadaan atom dengan L dan S tertentu
terdiri dari sekelompok energi relatif sangat berdekatan satu sama lain.
Spectroscopic Description of
Ground Electronic States – Term Symbols
Term Symbol Form: 2S+1{L}
J
2S+1 – multiplicity
L – resultant angular momentum quantum number
J – total angular momentum quantum number
C – 1s22s22p2
Step 5: Use Hund’s Rules to determine the relative energies of all possible states.
1. The highest multiplicity term within a configuration is of lowest energy.
2. For terms of the same multiplicity, the highest L value has the lowest
energy (D < P < S).
3. For subshells that are less than half-filled, the minimum J-value state is of
lower energy than higher J-value states.
4. For subshells that are more than half-filled, the state of maximum J-value
is the lowest energy.
Based on these rules, the ground electronic configuration for carbon has the
following energy order: 3P0 < 3P1 < 3P2 < 1D2 < 1S0
Microstates for p2 arranged by
Msand ML
MS
1 0 -1
+2 x
+1 x xx x
ML 0 x xxx x
-1 x xx x
-2 x
See L = 2 and S = 0 term
MS
1 0 -1
+2 x
+1 x xx x
ML 0 x x xx x
-1 x xx x
-2 x
L = 1, S = 1 term
MS
1 0 -1
+2 x
+1 x xx x
ML 0 x xxx x
-1 x xx x
-2 x
L = 0, S = 0 term
MS
1 0 -1
+2 x
+1 x xx x
ML 0 x xxx x
-1 x xx x
-2 x
assigning terms from microstates
• have several groups of related microstates
• #microstates = (2L +1)(2S+1)
• L = 2, S = 0 (5 microstates) (D term)
• L = 1, S = 1 (9 microstates) (P term)
• L = 0, S = 0(1 microstate) (S term)
• L= 0 1 2 3 4 5
• notation S P D F G H (then by alphabet, omitting
J)
Are you getting the concept?
Write the ground state term symbol for fluorine.