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VGB PowerTech 3 l 2018 Flue gas flow rate calculation for mass emissions reporting

Flue gas flow rate calculation for


mass emissions reporting.
Part 1: The pathway from DIN 1942, to EN 12952-15,
to EN-ISO 16911-1
Frans Blank, David Graham and Henrik Harnevie

Kurzfassung Introduction (the lower heating value), typically the


case for gaseous and liquid fuels:
Rauchgas-Volumen-Berechnung für die Operators of combustion plant need to
Thermal Input (MJth/s) = Fuel Flow
Emissions-Berichterstattung know the flue gas flow rate to calculate the
(m3/s or kg/s) * NCV (MJth/m3 or MJ/kg)
Teil 1: Von DIN 1942 zu EN 12952-15 mass release of pollutant emissions. For
zu EN-ISO 16911-1 many standard fuels, the calculation of flue or the electrical/thermal output of the
gas flow rate gives reliable results, with a plant and the thermal efficiency, typically
Betreiber von Feuerungsanlagen müssen den defined uncertainty, using relatively simple the case for solid fuels:
Rauchgasdurchsatz ihrer Anlagen bestimmen,
procedures. The calculated dry flue gas
um Massenströme von Emissionen berechnen Thermal Input (MJth/s) = Energy Output
zu können. Für viele Standardbrennstoffe lie- volume is combined with emission concen-
trations that are reported on a dry basis. (MJout/s) ÷ Thermal Efficiency
fert die Berechnung des Rauchgasdurchsatzes (MJout/MJth)
zuverlässige Ergebnisse mit definierter Unsi- When concentrations are also measured on
cherheit und mit einem relativ einfachen Ver- a dry basis, as is often the case for large EN-ISO 16911-1 now defines reference Fuel
fahren. Das berechnete trockene Rauchgasvolu- combustion plants, this avoids the meas- Factors for fossil fuels in m3/MJth at 0 % O2,
men wird mit Emissionskonzentrationen kom- urement of water vapour and hence an ad- dry, 273.15 K, 101.325 kPa. These factors
biniert, die dann auf Basis trockener Mas- ditional uncertainty. are then corrected to the required reference
senströme gemeldet werden. Werden Konzent-
This publication is the first (VGB Research oxygen condition. There is little variation
rationen zudem auf Basis trockener Massen-
ströme gemessen, wie es bei Großfeuerungsan- Project No. 338) of a series of three VGB Re- between these specified Fuel Factors since
lagen häufig der Fall ist, vermeidet dies die an- search projects on “Flue gas flow rate calcu- there is a close correlation between the en-
sonsten erforderliche Messung von Wasser- lation for mass emissions reporting”. The ergy content of the fuel and the released
dampf und damit eine zusätzliche Unsicherheit. other two will appear within a year in this volume of combustion products. That is,
Diese Publikation ist die erste (VGB-For- journal, having the following sub-titles: only the combustible material within the
schungsprojekt Nr. 338) aus einer Reihe von –– Part 2: Verifying flue gas flow rate calcu- fuel has both a heating value and produces
drei zu VGB-Forschungsprojekten mit dem Titel lation, by means of stack testing and data gaseous combustion products. The combus-
„Berechnung des Rauchgasdurchsatzes für die evaluation, to EN-ISO 16911:2013 (VGB tible material within the fuel is principally
Berichterstattung über Massenemissionen“. Die Research Project No. 379). Carbon (C) and Hydrogen (H) and the small
beiden folgenden erscheinen innerhalb eines variation between Fuel Factors is caused by
Jahres in dieser Zeitschrift mit denfolgenden –– Part 3: Plant performance assessment
using the Large Combustion Plant and E- differences in the C:H ratio when moving
VGB PowerTech - All rights reserved - Alle Rechte vorbehalten - © 2017

Untertiteln:
PRTR databases (VGB Research Project through the range of fossil fuels from natu-
Teil 2: Überprüfung der Rauchgasdurchflussbe- ral gas to coal. The historic development of
rechnung mittels Schornsteinprüfung und Da- No. 400).
the range of Fuel Factors given in EN-
tenauswertung nach EN-ISO 16911:2013 The authors wish to thank the VGB Re- ISO 16911-1 is described below within the
(VGB-Forschungsprojekt Nr. 379) search Foundation for their financial con- context of the VGB Research Project 338.
Teil 3: Bewertung der Anlagenleistung mit Hilfe tributions, the members of the VGB Techni-
der Datenbanken Großfeuerungsanlage und E- cal Group “Emissions Monitoring”, who As already mentioned, the Fuel Factor, ‘S’,
PRTR (VGB-Forschungsprojekt Nr. 400) l formed the project oversight committee, specified in m3/MJth at 0 % O2, dry, defines
and especially Mr. Volker Hamacher (sec- the amount of flue gas released per unit of
retary of the group at the time) for his con- input energy. ‘S’ varies somewhat depend-
tinuous enthusiasm for our work. ing on the type of fuel, net calorific value,
moisture and ash content. Initially, within
Authors Motivation and our VGB Research Project, it appeared that
there were no clear references to interna-
M.Sc. Frans Blank historicalcontext tional standards available for the Fuel Fac-
Consultant
DNV GL – Energy Flue gas flow rate is calculated from the tor. For example, the Fuel Factors applied in
Arnhem, The Netherlands plant net Thermal Input (MWth) and a the Netherlands came from DIN 1942:1979,
M.Sc. David Graham Fuel Factor which defines the volume of the standard for acceptance tests [1]. The
Technical Consultant Gas Turbines dry stack gas produced from a unit of use- Fuel Factor was calculated from the com-
Uniper Technologies Ltd. ful thermal input (m3/MJth): bustion formulas in that standard.
Nottingham, United Kingdom
The revised DIN 1942:1994 standard [2]
M.Sc. Henrik Harnevie Flue Gas Flow Rate (m3/s) = Thermal
provided formulas for direct calculation of
Senior Research Engineer; Input (MJth/s) * Fuel Factor (m3/MJth)
Process & Chemistry
the flue gas flow rate. However, the Nether-
Vattenfall Asset Development In turn, the Thermal Input is calculated lands and many other European countries
Stenungsund, Sweden from either the rate of fuel consumption continued to use their own historic Fuel
and the net calorific value (NCV) of the fuel Factors.

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59
Flue gas flow rate calculation for mass emissions reporting VGB PowerTech 3 l 2018

In 2003, the DIN 1942 standard was super- EN-ISO standard. Flow calculation can dry at 273.15 K, 101.325 kPa, from the as-
seded by the European standard EN 12952- therefore be used as a reference method, received fuel composition based on an ulti-
15:2003 [3]. That standard describes the under certain circumstances [6]. So, even- mate analysis:
same basic principles relating to plant per- tually, versions of the DIN equations have
VGod = 8.8930 γC + 20.9724 γH +
formance assessment and provides empiri- become a reference method in the interna-
3.3190 γS – 2.6424 γO + 0.7997 γN
cal formulas for flue gas flow rate calcula- tional standard for the determination of
(m3/kg)  [1]
tion that are similar to the latest DIN stand- flue gas flow rate.
ard. However, this is not at all apparent Whilst the calculation approach is fully de- (Formula 8.3-60 on page 42 of
from the title: ‘Water-tube boilers and aux- fined in the reference methods standard, EN 12952-15 and Formula E.3 of
iliary installations – Part 15: Acceptance the more common application is for con- EN-ISO 16911-1)
tests’; the relevant formulas are summa- tinuous flow calculation. In that case, the where γ is the mass fraction of an individu-
rised in the closing Annex of that standard standard EN-ISO 16911-2:2013: Automat- al fuel component in the supplied fuel (as
(pages 85-86). ed Measuring Systems needs to be applied received) and C, H, S, O and N are the ele-
In 2010 the second version of the VGB/EU- [7]. This permits a calculation approach to ments carbon, hydrogen, sulphur, oxygen,
RELECTRIC guidance document for mass be used for continuous flow monitoring and nitrogen, respectively.
emissions reporting was released [4]. For provided that it is verified using manual ref-
flue gas flow calculation, this guidance erence methods, i.e., by stack testing. Al- Coal and biomass
document contains a few fixed factors, though the calculation must be initially
with reference to a 1997 International En- verified and then checked annually, ‘cali- For solid fuels the empirical relation pro-
ergy Agency handbook. For lignite or bio- bration factors’ derived from the stack test- vided in EN 12952-15 is a good approxima-
mass no dedicated calculation formulas ing results must not be applied to the calcu- tion for a wide range of solid fuels.
were provided. At that time, neither the lation.
DIN nor EN standard formulas had been as- VGod = -0.06018 (1 – γAsh – γH2O) +
The performance of the manual reference 0.25437 (H(N) + 2.4425 γH2O)
sessed by the authors of the guidance doc- methods, and their use in the verification
ument. (m3/kg)  [2]
of calculated flue gas flow rate, will be con-
Meanwhile, for many years, there had been sidered in Part 2 of this series (VGB Re- (Formula A.5N on page 85 of
a NOx-fee system in Sweden. For reporting search Project No. 379). EN 12952-15)
the annual NOx mass emission, the flue gas On a regular basis, the flue gas volume for- Where γAsh and γH2O are the mass fraction
volume needs to be accurately known. The mulas are also used for emission perfor- of ash and water and H(N) is the net calo-
use of biomass, with a fuel water content up mance benchmarking. When the annual rific value of the as-received fuel.
to 60 percent and low heating values, is energy consumption is available, the cor- In the project report, which is publicly
common in Sweden. Most plants weigh fuel responding flue gas volume can be calcu- available at the VGB web site, the emphasis
samples and check for major variations in lated easily. Combining this with the an- of the validation was on hard coal and bio-
the moisture content used for the stack gas nual energy output, the annual concentra- mass. Two participants had extensive coal
flow and the annual average. The wetter the tion can be estimated. In Part 3 of this and biomass databases. Vattenfall per-
fuel, the higher the Fuel Factor, since more series the results of VGB Research Project formed their tests on 163 fuels from the
fuel needs to be combusted simply in order No. 400: “Performance assessment using ECN Phyllis database for biomass and
to evaporate the water that is supplied with the Large Combustion Plant and E-PRTR waste, also including lignite, peat, and
that fuel. The Fuel Factor therefore increas- databases” will be published. plastics. F i g u r e 1 and F i g u r e 2 show
es by about 20 %, in relative terms, as the
the calculated Fuel Factors with formula
fuel moisture content increases from 20 to
Fuel Factor calculation formulas [1] and formula [2], respectively. The lat-
60 % as described later (Ta b l e 3 ). It was
therefore apparent that biomass fuels need- and validation results ter procedure gives almost identical results
for nearly all dry solid fuels. A further very
ed to be incorporated into the VGB Re-
VGB PowerTech - All rights reserved - Alle Rechte vorbehalten - © 2017

For solid and liquid fuels, EN 12952-15 de- interesting result is that it also does not
search Project in addition to fossil fuels.
fines a method to determine the mass spe- matter if the heating value is measured or
It should be noted that the uncertainty of cific Fuel Factor, VGod, in m3/kg at 0 % O2 calculated.
the flue gas flow rate also depends on the
uncertainty of the thermal input. For solid
fuels, the thermal input is usually deter- 0.350
mined indirectly – from the plant output
and the thermal efficiency. In this case, the
uncertainty needs to be determined on a
case-by-case basis, at least for a given plant 0.300
type and calculation approach. In many
cases, the Fuel Factor uncertainty then
Fuel factor in m3/MJth

only has a small share in the total flue gas


flow rate uncertainty.
0.250
The authors completed the VGB Research
project 338 “Determination of Flue Gas
Flow” in January 2012 [5]. In the mean-
time, the EN-ISO 16911-1:2013 standard FF
FF
analysis
analysis
(bark)
(char from food industry)
FF
FF
milne
milne
(bark)
(char from food industry)
0.200
for flow manual reference methods was FF analysis (industrial sludge) FF milne (industrial sludge)
FF analysis (brown coal) FF milne (brown coal)
under development [6]. As a direct conse- FF analysis (municipal waste) FF milne (municipal waste)
quence of the technical assessments con- FF analysis (peat) FF milne (peat)
FF analysis (recovered wood) FF milne (recovered wood)
ducted within VGB Research Project 338, FF analysis (straws and grass) FF milne (straws and grass)
FF analysis (untreated wood) FF milne (untreated wood)
which demonstrated the ease of applicabil- 0.150
ity of the calculation methods and their
low uncertainty, the project results were Fig. 1. F uel factor for 163 fuels using formula 1 with measured (analysis) and calculated (milne)
incorporated as a normative Annex E in the net calorific value.

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VGB PowerTech 3 l 2018 Flue gas flow rate calculation for mass emissions reporting

The NSE correction (Ta b l e 2 ) is derived


0.270 from the Annex of EN 12952-15 formulas
[2], [3] and [4]:
S = a / e (N) + b
0.260 where e (N) is the Net Specific Energy of the
as received fuel in MJ/kg (=H(N)).
Fuel factor in m3/MJth

For gaseous fuels, it may be more conveni-


ent to employ the volumetric Net Specific
0.250 Energy (MJ/m3 at 0 °C) in which case a =
0.2 and b = 0.234. This approach is not
FF analysis (bark) FF milne (bark) suitable for low specific energy fuel gases
FF analysis (char from food industry) FF milne (char from food industry)
FF analysis (industrial sludge) FF milne (industrial sludge)
for which the Fuel Factor shall be deter-
FF analysis (brown coal) FF milne (brown coal) mined from the gas composition according
0.240 FF analysis (municipal waste) FF milne (municipal waste)
FF analysis (peat) FF milne (peat)
to EN 12952-15 Section 8.
FF analysis (recovered wood) FF milne (recovered wood) For liquid fuels, this approach is suitable
FF analysis (straws and grass) FF milne (straws and grass)
FF analysis (untreated wood) FF milne (untreated wood) only for light petroleum fractions. Other
liquid fuels should be assessed using the
0.230 measured composition and heating value.
For solid fuels, the mass fractions of ash
Fig. 2. F uel factor for 163 fuels using formula 2 with measured (analysis) and calculated (milne)
net calorific value. and moisture in the as-received fuel need
to be taken into account using the dry,
ash free, fuel mass fraction, γF, where: γF =
The same conclusions were drawn for both Fuel Factors in 1 – γAsh – γH2O
hard coal and biomass fuels. It is generally
ISO 16911-1:2013 and their
better to base a flue gas flow calculation on Fixed Fuel Factors for wet biomass were de-
net calorific value, rather than fuel compo- calculated uncertainty rived in accordance with EN 12952-15 as
sition. For bituminous and sub-bituminous shown in Ta b l e 3 . The uncertainty re-
In the VGB project a set of fixed Fuel
coal the EN formula also showed very good lates to a moisture content variation of
Factors for commercially traded fuels,
agreement with the US EPA factors that ±10 % in each case, e.g., a moisture con-
and their associated uncertainties, was es-
were originally based on Gross Calorific tent of 30 % mass fraction covering a range
tablished and incorporated into the EN-
Values. In the VGB report [5] there is a de- of moisture contents from 20 % to 40 %.
ISO 16911-1 standard as shown in Ta -
tailed explanation of how to then use the The uncertainty increases nonlinearly at
b l e 1.
Fuel Factor to calculate flue gas flow rate high moisture contents.
when the total thermal input is calculated A wider range of fuels may be considered,
from the energy output and thermal effi- and a lower uncertainty can be achieved, Conclusions
ciency of the plant. by applying a correction for the NCV of the
as-received fuel. “As-received” indicates The calculation of flue gas flow rate, for the
Gas and oil fuel that the fuel heating value is reported on purpose of mass emissions reporting, gives
the basis that all moisture and ash-forming reliable results, with a defined uncertainty,
For liquid fuels, the empirical calcula- minerals are present. Note that the NCV is using relatively simple procedures. The
tion of the mass specific Fuel Factor is given referred to as the Net Specific Energy flue gas flow rate calculations within the
as: (NSE) in the standard. However, uncer- German standard DIN 1942:1994 had his-
VGod = 1.76435 + 0.20060 H(N) (m3/kg) tainties for these alternative approaches torically been used by many countries and
VGB PowerTech - All rights reserved - Alle Rechte vorbehalten - © 2017

 [3] are not pre-defined and need to be speci- individual companies for these purposes.
fied by the plant operator. The present VGB validation study demon-
(Formula A.10N on page 86 of
EN 12952-15) Tab. 1. Fossil fuel factors (Table E.1 of EN-ISO 16911-1).
In the validation, it showed very good Fuel type
Fuel Factor
agreement with calculation from compo- S Natural gas Gas oil Fuel oil Hard coal
sition and close agreement with US
EPA calculation. There was a distinct dif- m3/MJ at 0 % O2 dry
0.240 0.244 0.248 0.256
273,15 K & 101,325 kPa
ference in the fuel factor from Gas oil and
Fuel oil. Urel,95%, % ±0.7 ±1.0 ±1.0 ±2.0

For gaseous fuels, the empirical relation


provided in EN 12952-15 is applicable to a Tab. 2. NSE correction factors (Table E.3 of EN-ISO 16911-1).
wide range of natural gas compositions
Fuel type
and process fuel gases (but not low calo- Parameter
rific value fuel gas): Gas Liquid Solid

VGod = 0.64972 + 0.22553 H(N) (m /kg) 3 a 0.64972 1.76435 -0.06018 γF


 [4] b 0.22553 0.20060 0.25437 (1+ 2.4425 γH2O / e(N))

(Formula A.15N on page 86 of


EN 12952-15) Tab. 3. Biomass fuel factors (Table E.2 of EN-ISO 16911-1).

This formula was validated with an exact Fuel moisture (% mass fraction) 20 30 40 50 60
calculation from a molar combustion bal-
Fuel factor, S, m3/MJ at 0 % O2 dry 0.260 0.267 0.276 0.290 0.314
ance which was also used to verify a volu-
metric equation for the flue gas volume Uncertainty, Urel,95%, %
2.8 3.6 5.0 7.7 13.9
(±10 % mass fraction moisture)
(described below).

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61
Flue gas flow rate calculation for mass emissions reporting VGB PowerTech 3 l 2018

strates the low calculation uncertainty gaseous, liquid and solid fuels. Conse- [3] EN 12952-15:2003 Water-tube boilers and
that can be achieved when deriving Fuel quently, flue gas flow rate calculation was auxiliary installations – Part 15: Acceptance
Factors from the net calorific value of the approved for continuous monitoring, un- tests.
fuel. A range of fixed Fuel Factors, with de- der Part 2 of the same standard, subject to [4] VGB/EURELECTRIC, 2010: European Wide
fined uncertainties, was developed for verification using manual reference meth- Sector Specific Calculation Method for Report-
ing to the European Pollutant Release and
commercially traded fossil fuels and wet ods which is the subject of our next paper. Transfer Register – 2nd Edition.
biomass. More detailed estimation meth- The calculation approach can therefore
[5] David Graham, Henrik Harnevie, Rob van
ods, based on the net calorific value and/or continue to provide a cost effective and ac- Beek and Frans Blank, Validated methods for
the fuel composition were also derived us- curate means of continuously monitoring flue gas flow rate calculation with reference to
ing formulas given in EN 12952-15:2003 the flue gas volume flow rate. EN 12952-15, KEMA, 2012.
(the successor to DIN 1942). [6] EN-ISO 16911-1: 2013 Stationary source
In 2013, the VGB project results were suc- References emissions – Manual and automatic determi-
nation of velocity and volume flow rate in
cessfully incorporated into Annex E of EN- [1] DIN 1942: 1979 Abnahmeversuche an Damp- ducts – Part 1: Manual reference method.
ISO 16911 ”Manual and automatic deter- ferzeugern (VDI – Dampferzeugerregeln). [7] EN-ISO 16911-2: 2013 Stationary source
mination of velocity and volume flow rate [2] DIN 1942: 1994 Acceptance test code for emissions – Manual and automatic determina-
in ducts – Part 1: Manual reference meth- steam generators (VDI-rules for steam genera- tion of velocity and volume flow rate in ducts –
od” and this is applicable to a wide range of tors). Part 2: Automated measuring systems. l

VGB-Standard

Preservation of Steam andGas Turbo-Generator Sets


(2nd edition)
Edition 2017 – VGB-S-036-00-2017-04-EN
VGB-Standard
DIN A4, 42 Pa­ges, Pri­ce for VGB mem­bers* € 190.–, for non mem­bers € 280.–, + VAT, ship­ping and hand­ling Preservation of Steam and
DIN A4, 42 Seiten, Preis für VGB-Mit­glie­der* € 190,–, für Nicht­mit­glie­der € 280,–, + Ver­sand­kos­ten und MwSt. Gas Turbo-Generator Sets

The present VGB-Standard covers all aspects of preservation. This standard provides operators, manufactur- 2nd Edition

ers and planners with a basic framework on how and to what extent the steam turbines, gas turbines and
generators are to be treated.
The editorial team has decided to take the steam turbine and the generator from the VGB-R 116 “Pres-
ervation of Power Plants” (republished as VGB-S-116-00-2016-04-EN “Preservation of Power Plants”), VGB-S-036-00-2017-04-EN

to add a section on the gas turbine and to publish both together in this revised VGB standard “VGB-
S-036-00-2017-04”.
This VGB-Standard can be used analogously to protect other plant components in the power plant against
corrosion. It is prepared to the best of our professional knowledge, but does not claim to be complete.
By its very nature, this VGB-Standard is a recommendation and therefore cannot replace the expertise of the
users.
In principle, however, in addition to the recommendations and measures for protecting the assets by preser-
vation as described below, the manufacturer’s instructions and the specifications from the operating manuals
must also be observed.

* Access for eBooks (PDF files) is included in the membership fees for Ordinary Members of VGB PowerTech e.V.

VGB PowerTech Service GmbH Deilbachtal 173 | 45257 Essen | P.O. Box 10 39 32 | Germany
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Verlag technisch-wissenschaftlicher Schriften Fon: +49 201 8128-200 | Fax: +49 201 8128-302 | E-Mail: mark@vgb.org | www.vgb.org/shop

VGB-Standard

Recommendations for the Inspection and Overhaul


of Steam Turbines (formerly VGB-R 121e)
Ausgabe/edition 2016 – VGB-S-121-00-2016-04-EN
DIN A4, 90 Pa­ges, Pri­ce for VGB mem­bers* € 150.–, for non mem­bers € 210.–, + VAT, ship­ping and hand­ling VGB-Standard
DIN A4, 90 Seiten, Preis für VGB-Mit­glie­der* € 150,–, für Nicht­mit­glie­der € 210,–, + Ver­sand­kos­ten und MwSt. Monitoring, limiting
and protection devices
Monitoring, limiting and protection devices must satisfy stringent requirements in order to afford safe on gas turbine systems
and reliable operation of gas turbine units.
The VGB Technical Group “Gas Turbines” considered it necessary to revise the “Guidelines for Supervision,
Limiting and Protection Devices on Gas Turbine Systems” whose second, revised edition had been published
in 1993. The present revision was aimed at considering the present state of the art and the current codes of
practice and ISO and VDMA standards. This Standard applies to stationary gas turbines (single-shaft and VGB-S-121-00-2016-04-EN

multi-shaft turbines) used to drive generators and other machinery.

* Access for eBooks (PDF files) is included in the membership fees for Ordinary Members of VGB PowerTech e.V.
VGB PowerTech e.V. Te l : +49 201 8128 – 200
Deilbachtal 173 Fax: +49 201 8128 – 302

VGB PowerTech Service GmbH


45257 Essen | Germany www.vgb.org | mark@vgb.org

Deilbachtal 173 | 45257 Essen | P.O. Box 10 39 32 | Germany


Verlag technisch-wissenschaftlicher Schriften Fon: +49 201 8128-200 | Fax: +49 201 8128-302 | E-Mail: mark@vgb.org | www.vgb.org/shop

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International Journal for Electricity and Heat Generation

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