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Objective:
Investigate the relationship between volume and pressure of a gas constant temperature.
Key Concepts:
The relationship between the volume and pressure of gases at constant
temperature was first stated by Robert Boyle during the 16th century. He
performed an experiment where in he trapped a fixed amount of air in the J -
tube, he changed the pressure and controlled the temperature and then, he
observed its effect to the volume of air inside the J-tube. He found out as
the pressure is increased, the volume decreases. He finally concluded that
the volume of a fixed amount of gas is inversely proportional to its pressure
at constant temperature.
Robert Boyle (1627 – 1691)
Gas particles have very weak intermolecular force of attraction; hence they move as far as possible from each
other. They have tendency to occupy all the spaces they are contained in.
In the smaller space the particles suffer collisions This relationship is known as Boyle’s Law.
with the walls of the container shows that it measures
the pressure exerted by the gas.
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Boyle's Law is important when using a syringe. When fully depressed, the syringe is at a neutral state with no air
in the cylinder. When the plunger is pulled back, you are increasing the volume in the container and thus reducing
the pressure. They are inversely proportional and one must decrease while the other increases. The liquid draws
up into the syringe because it balances the pressure, making it equal to the pressure outside of the syringe.
The given proportion above is read as: The volume of a gas is inversely proportional to its pressure, if
temperature and amount of gas are held constant.
In the proportion above, change the proportionality sign (α) with the equal sign (=) to make it an equation.
k
Thus, V = or k = VP ; The product of Pressure and Volume is constant.
P
Sample Data on Volume – Pressure relationship Volume – Pressure Graph
8.0
Trial Volume Pressure VxP .
Pressure (atm)
Formulas:
Initial condition (When unknown) Final condition (When unknown)
V1P1 = V2P2 V1P1 = V2P2
V1 V1 V2 V2
P1 = V2P2 P2 = V1P1
V1 V2
V1 = V2P2 P2 = V1P1
V2 P2
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Pressure units and their equivalents:
1 atmosphere (atm) = 760 millimeters of mercury (mmHg)
1 atm = 76 cm Hg
1 atm = 760 Torricelli (Torr)
1 atm = 101325 Pascal (Pa)
1 atm = 14.6956 Pound per square inch (Psi)
Volume units and their equivalents:
1 mL = 1cm3 1L = 1dm3 1m3 = 1000
Sample Problem:
A gas occupies 1.56 L at 1.00 atm. What will be the volume of this gas if the pressure becomes 3.00
atm?
Initial Condition Final Condition
V1 = 1.56 L P1 = 1.00 atm
V2 =? P2 = 3.00 atm
Apply Boyle’s Law Equation and Substitute the given values to the equation:
V1P1 = V2 P2
V2 =
P2
(1.56 L) (1.00 atm)
=
3.00 atm
V2 = 0.52 L
As the volume decreases, pressure increases (V inversely proportional P)
Directions:
A. Plot the points on a graph with the pressure at the y – axis and volume at the x – axis. Use the data found on
the table. Connect all points and answer the given questions below.
Pressure - Volume Graph
Volume Pressure 15.0
(mL) (mmHg)
12.0
25 3.0
Pressure (mmHg)
20 6.0 9.0
15 9.0
6.0
10 12. 0
3.0
5 15.0
0
5 10 15 20 25 30
B. Directions: Read and understand the given problem below. Write the given to the table and solve the
unknown.
4.0 L of a gas are under pressure of 3.0 atmosphere (atm). Find out what will happen to the volume of
the gas at a pressure of 2.7 atm if the temperature remains constant. Support your answer with
computation.
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Initial Condition Final Condition
Formula: Solution:
Write the relationship between volume and
_____________
pressure of a gas.
_____________________________________
Objective:
Investigate the relationship between volume and temperature of a gas at constant pressure.
Activity No.: 2 Title: Relationship between Volume and Temperature Day: 2 -3
Key Concepts:
Where:
V = volume and
T = temperature expressed in Kelvin
Removing the proportionality symbol (α) and using equality sign (=)
The equation will be as follows:
V = kT or k= V
T
Thus, in a direct proportion, the quotient of the variable is constant.
If you are going to consider the initial and final conditions, you will arrive at the following equations:
V1 V2 = k
=k and
T1 T2
Where:
V1 is the initial volume
T1 is the initial temperature
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V2 is the final volume
T2 is the final temperature
40
Volume mL
35
30
15
0
50 100 150
Temperature (K)
The volume is directly proportional to temperature.
Equation:
V1 = V2
T1 T2
The formulas:
Initial Condition (When unknown) Final condition (when unknown)
V1T2 = V2T1 V1T2 = V2T1
T2 T2 T1 T1
V1 = V2T1 V2 V1T2
T2 =
T1
V1T2 VT V1T2 = V2T1
= 2 1
V2 V2 V1 V1
T1 = V1T2 T2 = V2T1
V2 V1
Sample Problem:
A gas occupies 900.0 mL at a temperature of 27.0 °C. What is the volume at 132.0 °C?
V1 = V2
T1 T2
VT
V2 = 1 2
T1
Volume (mL)
Temperature (K)
Questions:
1. Describe the line in the graph.
______________________________________
2. What is the relationship between volume and temperature of gases at constant temperature?
_________________________________________________________________________
3. When temperature increases, volume ____________________ .
4. When volume decreases, temperature ____________________ .
C. Directions: Read and solve the given problem below. Write the given to the table and show the
complete solution.
The temperature inside my refrigerator is about 4.00 0C. If I place a balloon in my fridge that initially
has a temperature of 22.00 0C and a volume of 0.50 L, what will be the volume of the balloon when it
is fully cooled by my refrigerator?
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Write the relationship between volume and
Solution:
temperature of a gas.
__________________________________________
Objective: Explains volume – pressure and volume - temperature relationships using the kinetic molecular theory.
Key Concepts:
a. Gases are composed of molecules. The distances from one molecule to another molecule are
far greater than the molecules’ dimensions. These molecules can be considered as spherical
bodies which possess negligible mass and volume.
Molecules of Gases
b. Gas molecules are always in constant random motion and they frequently collide with one
another and with the walls of the container. Collision among molecules are perfectly elastic,
that is, energy may transfer from one molecule to molecule as the result of collision but the
total energy of all molecules in the system remains the same or constant.
The Kinetic Molecular Theory (KMT) explains the properties of gases and describes the behavior of gases.
Boyle's law is easily explained by the kinetic molecular theory. Gases can be compressed because most of
the volume of a gas is empty space. If we compress a gas without changing its temperature, the average kinetic
energy of the gas particles stays the same. There is no change in the speed with which the particles move, but the
container is smaller. Thus, the particles travel from one end of the container to the other in a shorter period of time.
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This means that they hit the walls more often. Any increase in the frequency of collisions with the walls must lead
to an increase in the pressure of the gas. Thus, the pressure of a gas becomes larger as the volume of the gas
becomes smaller.
Gas molecules are constant and
random motion.
Gas pressure is the result of
molecules colliding with the walls of
the container.
Decreasing the volume increases the
pressure since there will be higher rate
of collisions in the reduced volume.
Increasing the volume, decreases the More collisions less collisions
pressure since there will be lower rate
of collisions. www.google.com/search?q=Air+filled+balloon+in+ice+and+hot+water&tbm
In Charles’ Law, If the temperature of a gas is increased, a constant pressure may be maintained only if the
volume occupied by the gas increases. This will result in greater average distances traveled by the molecules to
reach the container walls, as well as increased wall surface area. These conditions will decrease the both the
frequency of molecule-wall collisions and the number of collisions per unit area, the combined effects of which
balance the effect of increased collision forces due to the greater kinetic energy at the higher temperature.
Directions: Choose from the word/s given inside the box to complete the sentence below. You can choose the
word twice. Write your answer on the blank provided.
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Activity 3
1. molecules
2. temperature
3. kinetic energy
4.lower rate
5. decreases
6. pressure
7. constant
8. decreases
9. low temperature
10. increases
Activity 2
Activity 1.
A. A.
Plotting points on the graph (Rubric based)
1. Straight
2. Directly proportional
3. Increases
4. Decreases
1. Not a straight line, curve
2. Increases
B. answer V2 = 0.53 L 3. inversely proportional
B. Answer to the problem:
The volume of a gas is directly proportional to V2 = 4.44 L
temperature
The volume of a gas is inversely proportional
to pressure
Answer key in Science 10 Quarter 3 – Week 1
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